• Title/Summary/Keyword: Surface fuel

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An Experimental Study on the Characteristics of Electrochemical Reactions of RDF/RPF in the Direct Carbon Fuel Cell (직접탄소 연료전지에서 RDF 및 RPF의 전기화학반응 특성에 관한 실험적 연구)

  • Ahn, Seong Yool;Rhie, Young Hoon;Eom, Seong Yong;Sung, Yeon Mo;Moon, Cheor Eon;Kang, Ki Joong;Choi, Gyung Min;Kim, Duck Jool
    • Journal of Hydrogen and New Energy
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    • v.23 no.5
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    • pp.513-520
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    • 2012
  • The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.

RADIATION SAFETY ASSESSMENT FOR KN-12 SPENT NUCLEAR FUEL TRANSPORT CASK USING MONTE CARLO SIMULATION

  • Kim, J.K.;Kim, G.H.;Shin, C.H.;Choi, H.S.
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.207-214
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    • 2001
  • The KN-12 spent nuclear fuel (SNF) transport cask is designed for transportation of up to 12 assemblies and is in standby status for being licensed in accordance with Korea Atomic Energy Act. To evaluate radiation shielding and criticality safety of the KN-12 cask, each case of study was carried out using MCNP4B Code. MCNP code is verified by performing benchmark calculation for the KSC-4 SNF cask designed in 1989. As a result of radiation safety evaluation for the KN-12 cask, calculated dose rates always satisfied the standards at the cask surface, at 2m from the surface in normal transport condition, and at 1 m from the surface in hypothetical accident condition. Maximum dose rate was always arisen on the side of the cask. For normal transport condition, photons primarily contribute to dose rate between two kinds of released sources, neutrons and photons, from spent nuclear fuel but for hypothetical accident condition, contrary case was resulted. The level of calculated dose rate was 27.8% of the limit at the cask surface, 89.3% at 2 m from the cask surface, and 25.1% at 1 m from the cask surface. For criticality analysis, keff resulting from the criticality analysis considering the condition of optimum partial flooding with fresh water is 0.89708(0.00065. The results confirm the standards recommended by all regulations on radiation safety.

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Simulation of Asymmetric Fuel Thermal Behavior Using 3D Gap Conductance Model (3 차원 간극 열전도도 모델을 이용한 핵연료봉의 열적 비대칭 거동 해석)

  • Kang, Chang Hak;Lee, Sung Uk;Yang, Dong Yol;Kim, Hyo Chan;Yang, Yong Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.3
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    • pp.249-257
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    • 2015
  • A fuel assembly consists of fuel rods composed of pellets (UO2) and a cladding tube (Zircaloy). The role of the fuel rods in the reactor is to generate heat by nuclear fission, as well as to retain fission products during operation. A simulation method using a computer program was used to evaluate the safety of the nuclear fuel rods. This computer program has been called the fuel performance code. In the analysis of a light water reactor fuel rod, the gap conductance, which depended on the distance between the pellets and cladding tube, mainly influenced the thermomechanical behavior of the fuel rod. In this work, a 3D gap element was proposed to simulate the thermo-mechanical behavior of the nuclear fuel rod, considering the gap conductance. To implement the proposed 3D gap element, a 3D thermo-mechanical module was also developed using FORTRAN90. The asymmetric characteristics of the nuclear fuel rod, such as the MPS (missing pellet surface) and eccentricity, were simulated to evaluate the proposed 3D gap element.

Determination of Properties of Ionomer Binder Using a Porous Plug Model for Preparation of Electrodes of Membrane-Electrode Assemblies for Polymer Electrolyte Fuel Cells

  • Park, Jin-Soo;Park, Seok-Hee;Park, Gu-Gon;Lee, Won-Yong;Kim, Chang-Soo;Moon, Seung-Hyeon
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.295-300
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    • 2007
  • A new characterization method using a porous plug model was proposed to determine the degree of sulfonation (DS) of ionomer binder with respect to the membrane used in membrane-electrode assemblies (MEAs) and to analyze the fraction of proton pathways through ionomer-catalyst combined electrodes in MEAs for polymer electrolyte fuel cells (PEFCs). Sulfonated poly(ether ether ketone) was prepared to use a polymeric electrolyte and laboratory-made SPEEK solution (5wt.%, DMAc based) was added to catalyst slurry to form catalyst layers. In case of the SPEEK-based MEAs in this study, DS of ionomer binder for catalyst layers should be the same or higher than that of the SPEEK membrane used in the MEAs. The porous plug model suggested that most of protons were via the ionomer binder (${\sim}92.5%$) bridging the catalyst surface to the polymeric electrolyte, compared with the pathways through the alternative between the interstitial water on the surface of ionomer binder or catalyst and the ionomer binder (${\sim}7.3%$) and through only the interstitial water on the surface of ionomer or catalyst (${\sim}0.2%$) in the electrode of the MEA comprising of the sulfonated poly(ether ether ketone) membrane and the 5wt.% SPEEK ionomer binder. As a result, it was believed that the majority of proton at both electrodeds moves through ionomer binder until reaching to electrolyte membrane. The porous plug model of the electrodes of MEAs reemphasized the importance of well-optimized structure of ionomer binder and catalyst for fuel cells.

Robotic Floor Surface Decontamination System

  • Kim, Kiho;Park, Jangjin;Myungseung Yang
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.133-134
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    • 2004
  • DUPIC (Direct Use of spent PWR fuel In CANDU) fuel cycle technology is being developed at Korea Atomic Energy Research Institute (KAERI). All the DUPIC fuel fabrication processes are remotely conducted in the completely shielded M6 hot-cell located in the Irradiated Material Examination Facility (IMEF) at KAERI. Undesirable products such as spent nuclear fuel powder debris and contaminated wastes are inevitably created during the DUPIC nuclear fuel fabrication processes.(omitted)

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Multi-layered Coating Deposited on PEMFC (Proton Exchange Membrane Fuel Cell) Bipolar Plates (고분자전해질 연료전지용 바이폴라 플레이트의 다층 코팅의 증착)

  • Yun, Young-Hoon;Chung, Hoon-Taek;Cha, In-Su;Choi, Jeong-Sik;Kim, Dong-Mook;Jung, Jin-Ho
    • Journal of the Korean Ceramic Society
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    • v.45 no.8
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    • pp.472-476
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    • 2008
  • The surface region of commercial stainless steel 304 and 316 plates has been modified through deposition of the multi-layered coatings composed of titanium film ($0.1{\mu}m$) and gold film ($1-2{\mu}m$) by an electron beam evaporation method. XRD patterns of the stainless steel plates deposited with conductive metal films showed the peaks of the external gold film and the stainless steel substrate. Surface microstructural morphologies of the stainless steel bipolar plates modified with multi-layered coatings were observed by AFM and FE-SEM images. The stainless steel plates modified with $0.1{\mu}m$ titanium film and $1{\mu}m$ gold film showed microstructure of grains of under 100 nm diameter. The external surface of the stainless steel plates deposited with $0.1{\mu}m$ titanium film and $2{\mu}m$ gold film represented somewhat grain growth of Au grains in FE-SEM image. The electrical resistance and water contact angle of the stainless steel bipolar plates modified with multi-layered coatings were examined with the thickness of the gold film.

A Study on Performance Characteristics According to the Fuel Conditions for a Fuel Pump in LPG Engine (자동차용 LPG 펌프의 연료조건에 따른 성능특성에 관한 연구)

  • Park, Cheol-Woong;Kim, Chang-Up;Choi, Kyo-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.4
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    • pp.266-274
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    • 2008
  • The need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as Liquefied Petroleum Gas(LPG) which is able to meet the limits of better emission levels without many modifications to current engine design. LPG has a high vapor pressure and lower viscosity and surface tension than diesel and gasoline fuels. These different fuel characteristics make it difficult to apply it for the conventional gasoline or diesel fuel pump directly. In this study, experiments are performed to get performance and efficiency of the fuel pump at different condition as temperature, rotating speeds, composition of fuel. The characteristics of fuel pump is affected by cavitation due to the variation of temperature and composition.

Experimental Study on the Spray Behavior of Non-Esterification Biodiesel Fuel (비에스테르화 바이오디젤유의 분무거동에 대한 실험적 연구)

  • Choi, S.H.;Oh, Y.T.
    • Journal of ILASS-Korea
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    • v.14 no.3
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    • pp.117-121
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    • 2009
  • Biodiesel fuel has different spray patterns, because viscosity and surface tension of biodiesel fuel are higher than that of diesel fuel. The diesel combustion is strongly controlled by the fuel spray behavior in combustion chamber. So, it was needed to understand the spay characteristics of non-esterification biodiesel fuel. In this study, the spray characteristics of non-esterification biodiesel fuel was investigated to confirm of an effect of WDP. The characteristics of fuel atomization was analyzed with SMD and span factor through laser diffraction particle analyzer (LDPA), and the process of spray injection was visualized through the visualization system composed of a halogen lamp and high speed camera. It was found that injection delay time and SMD of blended fuel with WDP get shoter and smaller than that of non-esterification biodiesel fuel.

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Systems Engineering Approach to the Heat Transfer Analysis of PLUS 7 Fuel Rod Using ANSYS FEM Code

  • Park, Sang-Jun;Mutembei, Mutegi Peter;Namgung, Ihn
    • Journal of the Korean Society of Systems Engineering
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    • v.13 no.1
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    • pp.33-39
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    • 2017
  • This paper describes the system engineering approach for the heat transfer analysis of plus7 fuel rod for APR1400 using, a commercial software, ANSYS. The fuel rod is composed of fuel pellets, fill gas, end caps, plenum spring and cladding. The heat is transferred from the pellet outward by conduction through the pellet, fill gas and cladding and further by convection from the cladding surface to the coolant in the flow channel. The goal of this paper is to demonstrate the temperature and heat flux change from the fuel centerline to the cladding surface when having maximum fuel centerline temperature at 100% power. This phenomenon is modelled using the ANSYS FEM code and analyzed for steady state temperature distribution across the fuel pellet and clad and the results were compared to the standard values given in APR1400 SSAR. Specifically the applicability of commercial software in the evaluation of nuclear fuel temperature distribution has been accounted. It is note that special codes have been used for fuel rod mechanical analysis which calculates interrelated effects of temperature, pressure, cladding elastic and plastic behavior, fission gas release, and fuel densification and swelling under the time-varying irradiation conditions. To satisfactorily meet this objective we apply system engineering methodologies to formulate the process and allow for verification and validation of the results acquired. The close proximity of the results obtained validated the accuracy of the FEM analysis of the 2D axisymmetric model and 3D model. This result demonstrated the validity of commercial software instead of proprietary in-house code that is more costly to develop and maintain.