• Asian Journal of Atmospheric Environment
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• v.12 no.1
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• pp.47-58
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• 2018

The aim of this work is to investigate the effect of atmospheric stability on near-field pollutant dispersion from rooftop emissions of a single cubic building using computational fluid dynamics (CFD). This paper used the shear stress transport (here after SST) k-${\omega}$ model for predicting the flow and pollutant dispersion around an isolated cubic building. CFD simulations were performed with two emission rates and six atmospheric stability conditions. The results of the simulations were compared with the data from wind tunnel experiments and the result of simulations obtained by previous studies in neutral atmospheric condition. The results indicate that the reattachment length on the roof ($X_R$) obtained by computations show good agreement with the experimental results. However, the reattachment length of the rooftop of the building ($X_F$) is greatly overestimated compared to the findings of wind tunnel test. The result also shows that the general distribution of dimensionless concentration given by SST k-${\omega}$ at the side and leeward wall surfaces is similar to that of the experiment. In unstable conditions, the length of the rooftop cavity was decreased. In stable conditions, the horizontal velocity in the lower part around the building was increased and the vertical velocity around the building was decreased. Stratification increased the horizontal cavity length and width near surface and unstable stratification decreased the horizontal cavity length and width near surface. Maintained stability increases the lateral spread of the plume on the leeward surface. The concentration levels close to the ground's surface under stable conditions were higher than under unstable and neutral conditions.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.62-68
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• 2004

To comply with stringent exhaust emission standards, it is necessary to reserch on some better quality of automotive fuels. Sulfur in fuels is sulfur compound by DOC and then it caused to the increase of PM on the surface of the catalyst. This research is focused on diesel emission characteristics and poisoning effect on Diesel Oxidation Catalyst when Ultra Low Sulfur Diesel(ULSD) and biodiesel are applied simultaneously. The biodiesel is used to improve viscosity of fuel specially in fuel injection system of engine since the introduction of ULSD may degrade viscosity in the process of desulfurization. Furthermore, this study may provide some basic data for the design of emissions reduction technology.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.146-151
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• 2004

The characteristics of combustion and emission of biodiesel fuel were investigated in a single cylinder DI diesel engine equipped with a common rail injection system. For investigating the effect of bio diesels, the experiments were conducted at various mixing ratio and engine operation conditions. Experimental results show that combustion pressure increased with the increase of mixing ratio and injection pressure. The HC and CO emissions are decreased and NOx emission is increased as the mixing ratio of biodiesels increases at 100MPa injection pressure. However the results of the emissions are shown the contrary to the results at 50MPa of injection pressure due to larger droplets of biodiesel sprays.

• Journal of Environmental Science International
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• v.13 no.9
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• pp.845-853
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• 2004

Recently many countries agreed to reduce emissions of greenhouse gases into the atmosphere or at least to keep them at the current level at the Kyoto Protocol. Carbon dioxide has been proven to be 80% of greenhouse gases, contributing to the increase of the earth's surface temperature. It is reported that half of the $CO_2$ emissions are produced by industry and power plants using fossil fuels. In this article, we review and analysis domestic and abroad R & D policy trends relating to UN framework convention on climate change(UNFCCC).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.5
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• pp.659-669
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• 1997

The effects of exhaust gas recirculation on diesel engine combustion and soot/NOx emissions are numerically studied. The primary and secondary atomization is modelled using the wave instability breakup model. Autoignition of a diesel spray is modelled using the Shell ignition model. Soot formation is kinetically controlled and soot oxidation is represented by a model which account for surface chemistry. The NOx formation is based on the extended Zeldovich NOx model. Effects of injection timing and concentration of $O_{2}$ and CO$_{2}$ on the pollutant formation and the combustion process are discussed in detail.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.413-413
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• 2023

Wetlands are a critical component of the global carbon cycle and are essential in mitigating climate change. Accurately quantifying wetland carbon emissions is crucial for understanding and predicting the impact of wetlands on the global carbon budget. The uncertainty quantifying carbon in wetlands may comes from the ecosystem's hydrological, biochemical, and microbiological variability. The Community Land Model is a sophisticated and flexible land surface model that offers several configuration options such as energy and water fluxes, vegetation dynamics, and biogeochemical cycling, necessitating careful consideration for the alternative configurations before model implementation to develop a practical model framework. We conducted a systematic literature review, analyzing the alternatives, focusing on the carbon stock pools configurations and the parameters with significant sensitivity for carbon quantification in wetlands. In addition, we evaluated the feasibility and availability of in situ observation data necessary for validating the different alternatives. This analysis identified the most suitable option for our study site, the Binbong Wetland, in Korea.

• Environmental Engineering Research
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• v.24 no.1
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• pp.159-172
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• 2019

To investigate the influence of pollution events on the chemical composition and formation processes of aerosol particles, 24-h integrated size-segregated particulate matter (PM) was collected during the fall season at an urban site of Gwangju, Korea and was used to determine the concentrations of mass, water-soluble organic carbon (WSOC) and ionic species. Furthermore, black carbon (BC) concentrations were observed with an aethalometer. The entire sampling period was classified into four periods, i.e., typical, pollution event I, pollution event II, and an Asian dust event. Stable meteorological conditions (e.g., low wind speed, high surface pressure, and high relative humidity) observed during the two pollution events led to accumulation of aerosol particles and increased formation of secondary organic and inorganic aerosol species, thus causing $PM_{2.5}$ increase. Furthermore, these stable conditions resulted in the predominant condensation or droplet mode size distributions of PM, WSOC, $NO_3{^-}$, and $SO{_4}^{2-}$. However, difference in the accumulation mode size distributions of secondary water-soluble species between pollution events I and II could be attributed to the difference in transport pathways of air masses from high-pollution regions and the formation processes for the secondary chemical species. The average absorption ${\AA}ngstr{\ddot{o}}m$ exponent ($AAE_{370-950}$) for 370-950 nm wavelengths > 1.0 indicates that the BC particles from traffic emissions were likely mixed with light absorbing brown carbon (BrC) from biomass burning (BB) emissions. It was found that light absorption by BrC in the near UV range was affected by both secondary organic aerosol and BB emissions. Overall, the pollution events observed during fall at the study site can be due to the synergy of unfavorable meteorological conditions, enhanced secondary formation, local emissions, and long-range transportation of air masses from upwind polluted areas.

• Journal of Climate Change Research
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• v.7 no.2
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• pp.103-110
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• 2016

In this study, we researched the characteristics of $CH_4$ and $N_2O$ emission of the wastewater treatment (WWT) process in the dairy industry. For flux measurements at the air-water interface, a floating dynamic flow-through chamber was used above the water surface. $CH_4$ and $N_2O$ concentration from the WWT process was measured by NDIR (Non-Dispersive Infrared) Analyser. In the study, $CH_4$ and $N_2O$ fluxes results showed a distinct difference for each WWT process. 60% of the GHG emissions which was the highest percentage were from the equalization tank. Reactor tank was second with 27% of the total emissions from the WWT. Aeration tank was third with 12% of the total emissions. The tendency was that the more the wastewater was treated, the less GHGs were emitted. $CH_4$ and $N_2O$ showed the same tendency. This indicates that the concentrations and properties of wastewater could affect the tendency.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.119-119
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• 2010

We report strong exciton transition and exciton-phonon couplings in photoluminescence (PL) of ZnO thin films grown on MgO/sapphire (buffer/substrate) by plasma-assisted molecular beam epitaxy. The PL spectra at 10 K showed the intensity of the dominant emission, donor-bound exciton transition of front surface (top surface, the latter part in growth) is found to be about 100 times higher than that of back surface (in-depth bottom area, the initial part), while the room temperature PL spectra showed dominant contributions from the free exciton emissions and phonon-replicas of free excitons for front surface and back surface, respectively, It could be attributed to the strong contributions of exciton-phonon coupling. Time resolved PL spectra reveal that the life time of exciton recombination from the front surface are longer than those from back surface. This is most probably due to the fact that reduction of non-radiative recombination in the front surface. This investigation indicates that the existence of native defects or trap centers which can be reduced by the proper initial condition in growth and the exciton-phonon interaction couplings play an important role in optical properties and crystal quality of ZnO thin films.

• Atmosphere
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• v.25 no.4
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• pp.639-657
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• 2015

There is an increasing need to improve the air quality over South Korea to protect public health from local and remote anthropogenic pollutant emissions that are in an increasing trend. Here, we evaluate the performance of the WRF-Chem (Weather Research and Forecasting-Chemistry) model in simulating near-surface air quality of major Korean cities, and investigate the impacts of time-varying chemical initial and lateral boundary conditions (IC/BCs) on the air quality simulation using a chemical downscaling technique. The model domain was configured over the East Asian region and anthropogenic MICS-Asia 2010 emissions and biogenic MEGAN-2 emissions were applied with RACM gaseous chemistry and MADE/SORGAM aerosol mechanism. Two simulations were conducted for a 30-days period on April 2010 with chemical IC/BCs from the WRF-Chem default chemical species profiles ('WRF experiment') and the MOZART-4 (Model for OZone And Related chemical Tracers version 4) ('WRF_MOZART experiment'), respectively. The WRF_MOZART experiment has showed a better performance to predict near-surface CO, $NO_2$, $SO_2$, and $O_3$ mixing ratios at 7 major Korean cities than the WRF experiment, showing lower mean bias error (MBE) and higher index of agreement (IOA). The quantitative impacts of the chemical IC/BCs have depended on atmospheric residence time of the pollutants as well as the relative difference of chemical mixing ratios between the WRF and WRF_MOZART experiments at the lateral boundaries. Specifically, the WRF_MOZART experiment has reduced MBE in CO and O3 mixing ratios by 60~80 ppb and 5~10 ppb over South Korea than those in the WRF-Chem default simulation, while it has a marginal impact on $NO_2$ and $SO_2$ mixing ratios. Without using MOZART-4 chemical IC, the WRF simulation has required approximately 6-days chemical spin-up time for the East Asian model domain. Overall, the results indicate that realistic chemical IC/BCs are prerequisite in the WRF-Chem simulation to improve a forecast skill of local air quality over South Korea, even in case the model domain is sufficiently large to represent anthropogenic emissions from China, Japan, and South Korea.