• Journal of Korean Society for Atmospheric Environment
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• v.15 no.E
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• pp.29-38
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• 1999

This study identified emission sources and emissions of air pollutants such as volatile organic compounds (VOCs), solvents, and acid gases produced from chemical plants. We collected air samples from various processes, reactors and facilities using VOC detectors and workers' experience. We identified chemical structures and emission concentrations of air pollutants. We analyzed total emissions of air pollutants emitted from the chemical plants. Also, we developed some emission reduction technologies based on chemical types and emission situations of the identified air pollutants. For reduction of air emissions of acid gases, we employed a method improving solubility of pollutants by reducing scrubber operation temperature, increasing surface area for effective contact of gas and liquid, and modifying or changing chemicals used in the acid scrubbers. In order to reduce air emissions of both amines and acid gases, which have had different emission sources each other but treated by one scrubber, we first could separate gas components. And then different control techniques based on components of pollutants were applied to the emission sources. That is, we first applied condensation and then acid scrubbing method using H2SO4 solution for amine treatment. However, we only used an acid scrubbing method using H2O and NaOH solution for acid gas treatment. In order to reduce air emissions of solvents such as dimethylformamide and toluene, we applied condensation and activated carbon adsorption. In order to reduce air emissions of mixture gases containing acid gases and slovents, which could not be separated in the processes, we employed a combination of various air pollution control devices. That is, the mixture gases were passed into the first condenser, the acid scrubber, the second condenser, and the activated carbon adsorption tower in sequence. In addition, for improvement of condensation efficiency of VOCs, we changed the type of the condensers attached in the reactors as a control device modification. Finally, we could successfully reduce air emissions of pollutants produced from various chenmical processes or facilities by use of proper control methods according to the types and specific emission situations of pollutants.

• Journal of Korean Vacuum Science & Technology
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• v.5 no.1
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• pp.1-6
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• 2001

We measured the simultaneous, time-resolved spectra of photon emission, electron emission, and frictional force during the abrasion single crystal MgO with a diamond stylus in vacuum. phE and EE signal can be detected with millisecond resolution during the wear of a single crystal MgO substrate with a diamond stylus. The emissions and wear behavior are strong function of surface condition, load and stylus velocity. Measurement on annealed vs as-received material show that the luminescence is primarily due to deformation, and the electron emission is primarily due to fracture. These emissions provide insight into the processes responsible for catastrophic failure of ceramics in wear applications.

• Journal of Mechanical Science and Technology
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• v.16 no.2
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• pp.270-278
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• 2002

In order to reduce the exhaust emissions of a spark ignition engine, it is important not only to improve the catalyst conversion efficiency, but also to directly reduce the engine-out exhaust emissions during a cold starting of the engine and warm up periods. The purpose of this study is to evaluate feasibility of a glow plug for an early fuel evaporator. In order to promote atomization, gasoline is injected on the glow plug with room temperature(20$\^{C}$) and high temperature(250$\^{C}$). To analyze the spray behavior characteristics, a PMAS is used to measure the SMD and the dropsize distribution of an impinging spray and a free spray. Results show that the evaporation rate of the impinging spray on the high temperature surface of the glow plug was higher than that of the free spray on the room temperature surface.

• Journal of The Korean Astronomical Society
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• v.23 no.1
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• pp.71-82
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• 1990

Theoretical calculations of the combined radiative transfer and statistical equilibrium equation including the charge-particle conservations have been earned out for a multilevel hydrogen atom in quiescent prominences. Cool and dense models show the steep changes of population and radiation field in the vicinity of the surface, while these physical quantities remain unchanged for models with temperature of 7,300K, regardless of total densities. Ionization rate of hydrogen atom related with metallic line formation varies in considerable amounts from the surface to the center of model prominences cooler than 6,300K. However, such cool models cannot release enough hydrogen line emissions to explain observed intensities. Prominence models with a temperature higher than 8,000K can yield the centrally reversed Lyman line profiles confirmed by satellite EUV observations. We find that queiscent prominence with a density between $2{\times}10^{11}$ and $10^{12}cm^{-3}$ should be in temperature range between 6,300K and 8,300K, in order to explain consistently observed H alpha, beta line emissions and $n_p/n_l$ ratio.

• Journal of Power System Engineering
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• v.9 no.4
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• pp.118-123
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• 2005

We have investigated the fabrication of Si nanoparticles and $C_{60}$ thin films by pulsed laser ablation. By atomic force microscopy(AFM), the laser-deposited $C_{60}$ thin film was verified to have surface far smoother than the surfaces of films produced by the conventional evaporation method. The Si deposited at a He atmosphere of 0.2 Torr was with about $60{\AA}$ height of the Si nanoparticles, suggesting that it was uniformly deposited. We observed visible green emissions spectra in the $Si/C_{60}$ multilayer films after laser annealing. It is considered that this green emissions is occurred from SiC particles, which is produced reaction of Si nanoparticles with $C_{60}$ by laser annealing.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.2
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• pp.225-241
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• 2007

A closed flux chamber system was used for measuring major greenhouse gas (GHG) emission from tideland and/or wetland soils in estuarine area at Saemankum, Kunsan in southwestern Korea during from months of February to June 2006. Hourly averaged GHG soil emissions were measured two to three times a day during the ebb tide hours only. Site soils were analyzed for soil parameters (temperature, pH, total organic contents, N and C contents in soil) in the laboratory. Soil GHG fluxes were calculated based on the GHG concentration rate of change measured inside a closed chamber The analysis of GHG was conducted by using a Gas Chromatography (equipped with ECD/FID) at laboratory. Changes of daily, monthly GHGs' fluxes were examined. The relationships between the GHG emissions and soil chemical contents were also scrutinized with respect to gas production and consumption mechanism in the soil. Soil pH was pH $7.47{\pm}0.49$ in average over the experimental period. Organic matter contents in sample soil was $6.64{\pm}4.98\;g/kg$, and it shows relatively lower contents than those in agricultural soils in Kunsan area. Resulting from the soil chemistry data, soil nitrogen contents seem to affect GHG emission from the tidal land surface. The tidal soil was found to be either source or sink for the major GHG during the experimental periods. The annual average of $CH_{4}\;and\;CO_{2}$ fluxes were $0.13{\pm}0.86\;mg\;m^{-2}h^{-1}\;and\;5.83{\pm}138.73\;mg\;m^{-2}h^{-1}$, respectively, which will be as a source of these gases. However, $N_{2}O$ emission showed in negative flux, and the value was $-0.02{\pm}0.66\;mg\;m^{-2}h^{-1}$, and it implies tidal land surface act as a sink of $N_{2}O$. Over the experimental period, the absolute values of gas fluxes increased with soil temperature in general. Averages of the ambient gas concentration were $86.8{\pm}6.\;ppm$ in $CO_{2},\;1.63{\pm}0.34\;ppm\;in\;CH_{4},\;and\;0.59{\pm}0.15\;ppm\;in\;N_{2}O$, respectively. Generally, under the presence of gas emission from agricultural soils, decrease of gas emission will be observed as increase in ambient gas concentration. We, however, could not found significant correlation between the ambient concentrations and their emissions over the experimental period. There was no GHG compensation points existed in tide flat soil.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.2
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• pp.203-212
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• 2001

During the growing season from June to August, 2000, the soil NO and $N_2$O fluxes were measured to elucidate characteristics of soil nitrogen emissions from different types of intensively managed agricultural soils at outskirts of Kunsan City, located in the western inland of Korea, Flux measurements were made using a closed chamber technique at two different agricultural fields; one was made from upland field, and the other from rice paddy field. The flux data from upland field were collected for both the green onion and soybean field. Concentrations of NO and $N_2$O inside a flux chamber ar 15 minute sampling interval were measured to determine their soil emissions. Either polyethylene syringes of teflon air bags were used for gas samples of $N_2$O and NO. The analysis of NO and $N_2$O was made using a chemiluminesence NO analyzer and GC-ECD, respectively no later than few hours after sample collection at laboratory. The gas fluxes were varied more than one standard deviation around their means. Relatively high soil gas emissions occurred in the aftermoon for both NO and $N_2$O. A sub-peak for $N_2$O emission was observed in the morning period, but not in the case of NO. NO emissions from rice paddy field were much less than those from upland site. It seems that water layer over the rice paddy field prevents gases from escaping from the soil surface covered with were during the irrigation and acts as a sink of these gases. The NO fluxes resulted from these field experiments were compared to those from grass soil and they were found to be much higher. Diurnal and daily variations of NO and $N_2$O emission were discussed and correlated with the effects of nitrogen fertilizer application on the increase of the level of soil nitrogen availability.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.2
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• pp.139-158
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• 2017

CMAQ (Community Multiscale Air Quality Model) simulations were carried out to estimate the potential range of contributions on surface $PM_{2.5}$ concentrations over the Seoul Metropolitan Area (SMA) with the gaseous precursors and Primary Particulate Matters(PPM) available from a recent national emissions inventory. In detail, on top of a base simulation utilizing the 2013 Clean Air Policy Supporting System (CAPSS) emission inventory, a set of Brute Force Method (BFM) simulations after reducing anthropogenic $NO_x$, $SO_2$, $NH_3$, VOCs, and PPM emissions released from area, mobile, and point sources in SMA by 50% were performed in turn. Modeling results show that zero-out contributions(ZOC) of $NH_3$ and PPM emissions from SMA are as high as $4{\sim}5{\mu}g/m^3$ over the region during the modeling period. On the contrary, ZOC of local $NO_x$ and $SO_2$ emissions to SMA $PM_{2.5}$ are less than $1{\mu}g/m^3$. Moreover, model analyses indicate that a wintertime $NO_x$ reduction at least up to 50% increases SMA $PM_{2.5}$ concentrations, probably due to increased HNO3 formation and conversion to aerosols under more abundant ozone and radical conditions after the $NO_x$ reduction. However, a nation-wide $NO_x$ reduction decreased SMA $PM_{2.5}$ concentrations even during winter, which implies that nation-wide reductions would be more effective to curtail SMA $PM_{2.5}$ concentrations than localized efforts.

• Journal of Korean Society for Atmospheric Environment
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• v.31 no.5
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• pp.430-436
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• 2015

Numerical air quality forecasting suffers from the large uncertainties of input data including emissions, boundary conditions, earth surface properties. Data assimilation has been widely used in the field of weather forecasting as a way to reduce the forecasting errors stemming from the uncertainties of input data. The present study aims at evaluating the effect of input data on the air quality forecasting results in Korea when data assimilation was invoked to generate the initial concentrations. The forecasting time was set to 36 hour and the emissions and initial conditions were chosen as tested input parameters. The air quality forecast model for Korea consisting of WRF and CMAQ was implemented for the test and the chosen test period ranged from November $2^{nd}$ to December $1^{st}$ of 2014. Halving the emission in China reduces the forecasted peak value of $PM_{10}$ and $SO_2$ in Seoul as much as 30% and 35% respectively due to the transport from China for the no-data assimilation case. As data assimilation was applied, halving the emissions in China has a negligible effect on air pollutant concentrations including $PM_{10}$ and $SO_2$ in Seoul. The emissions in Korea still maintain an effect on the forecasted air pollutant concentrations even after the data assimilation is applied. These emission sensitivity tests along with the initial condition sensitivity tests demonstrated that initial concentrations generated by data assimilation using field observation may minimize propagation of errors due to emission uncertainties in China. And the initial concentrations in China is more important than those in Korea for long-range transported air pollutants such as $PM_{10}$ and $SO_2$. And accurate estimation of the emissions in Korea are still necessary for further improvement of air quality forecasting in Korea even after the data assimilation is applied.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.2
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• pp.259-268
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• 2005

In this study, we investigated the seasonal variations in the composition and emission patterns of VOC ventilated as landfill gas (LFG) from an urban municipal landfill site during the winter (2002) and summer (2003) period. The results of our study, when examined using the major aromatic VOC components as BTEX, indicated the existence of diverse characteristics in the LFG emissions of VOC. It was found that the relative extent of benzene emission showed most significant increase in the summer season, while most species underwent notable reductions. Despite the presence of certain patterns in the seasonal emissions of BTEX, the gross picture of their emission between summer and winter was not different distinctively so that the wintertime emissions exceed their summer counterparts by about three times. The observations of moderate enhancement in wintertime LFG emissions of BTEX appeared to reflect such environmental changes in the winter season as favorable conditions for LFG ventilation with reduced surface emissions due to frozen soil layers.