• Title/Summary/Keyword: Surface crystal

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Reorientation of Colloidal Crystalline Domains by a Thinning Meniscus

  • Im, Sang-Hyuk;Park, O-Ok
    • Macromolecular Research
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    • v.12 no.2
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    • pp.189-194
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    • 2004
  • When water is evaporated quickly from a water-based colloidal suspension, colloidal particles protrude from the water surface, distorting it and generating lateral capillary forces between the colloidal particles. The protruded colloidal particles are then assembled into ordered colloidal crystalline domains that float on the water surface on account of their having a lower effective density than water. These colloidal crystal domains then assemble together by lateral capillary force and convective flow; the generated colloidal crystal has grain boundaries. The single domain size of the colloidal crystal could be controlled, to some extent, by changing the rate of water evaporation, but it seems very difficult to fabricate a single crystal over a large area of the water's surface without reorienting each colloidal crystal domain. To reorient such colloidal crystal domains, a glass plate was dipped into the colloidal suspension at a tilted angle because the meniscus (airwaterglass plate interface) is pinned and thinned by further water evaporation. The thinning meniscus generated a shear force and reoriented the colloidal crystalline domains into a single domain.

Effect of Crystal Shape on the Grain Growth during Liquid Phase Sintering of Ceramics

  • Jo, Wook;Hwang, Nong-Moon;Kim, Doh-Yeon
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.728-733
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    • 2006
  • The equilibrium or growth shape of ceramic materials is classified largely into two categories according to the thermodynamic conditions imposed. One is a polyhedral shape where the surface free energy is anisotropic, and the other a spherical shape where the surface free energy is isotropic. In the case of grains with a polyhedral shape of anisotropic surface free energy, socalled abnormal grain growth usually takes place due to a significant energy barrier for a growth unit to be attached to the crystal surface. In the case of grains with a spherical shape of isotropic surface free energy, however, normal grain growth with a uniform size distribution takes place. In this contribution, the state-of-the-art of our current understanding of the relationship between the crystal shape and the microstructure evolution during the sintering of ceramic materials in the presence of a liquid phase was discussed.

A Defect Free Bistable C1 SSFLC Devices

  • Wang, Chenhui;Bos, Philip J.
    • Journal of Information Display
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    • v.4 no.1
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    • pp.1-8
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    • 2003
  • Recent progress in both low pretilt and high pretilt defect free C1 surface stabilized ferroelectric liquid crystal (SSFLC) devices is reviewed. First, by numerical calculation to investigate the balance between surface azimuthal anchoring energy and bulk elastic energy within the confined chevron layer geometry of C1 and C2, it is possible to achieve a zigzag free C1 state by low azimuthal anchoring alignment with a low pretilt angle. The critical azimuthal anchoring coefficient for defect free C1 state is calculated. Its relationship with elastic constant, chevron angle as well as surface topography effect are also discussed. Second, using $5^{\circ}$ oblique SiO deposition alignment method a defect free, large memory angle, high contrast ratio and bistable C1 SSFLC display, which has potential for electronic paper applications has also been developed. The electrooptical properties and bistability of this device have been investigated. Various aspects of defect control are also discussed.

Numerical modeling of defects nucleation in the liquid crystal devices with inhomogeneous surface (액정 디스플레이 소자 내에서의 불균일한 표면에 의한 결점의 발생과 모델링)

  • Lee Gi-dong;Kang Bongsoon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.8
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    • pp.1793-1798
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    • 2005
  • We model the nucleation and motion of defects in the liquid crystal display device with inhomogeneous surface by using fast Q-tensor method, which can calculate scalar order parameter S and nucleation of the defect in the liquid crystal director field. In order to model the defect, homeotropic aligned liquid crystal cell with step inhomogeneous electrode which has a height of $1{\mu}m$ is used. From the simulation, we can observe the nucleation and line of the defect from surface inhomogeneity and the experiment is performed for confirmation.

The Effect of Seed Orientation on Growth Form and Surface Morphology in Growing NYAB Crystal (NYAB 결정육성시 종자정의 방향이 성장외형 및 표면형상에 미치는 영향)

  • 정선태;최덕용
    • Korean Journal of Crystallography
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    • v.5 no.2
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    • pp.93-99
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    • 1994
  • Growth form and surface morphology of NYAB single crystal grown by TSSG technique using a K2O/3MoOS/0.5B203 flux was investigated. In the crystal grown from <100> or <120> seed, prismatic and (101) faces were well developed with different size each other. (001) face was also developed in the crystal grown from <001> seed. While growth hillocks were observed on the prismatic face of the crystal grown from <100> seed, surface striations parallel to neighbor (101) faces were formed on that face of the crystal grown from <001> seed. The (101) faces were grown by two dimensional nucleation growth. (001) face which was developed at slow growth velocity of [001] direction was grown by screw dislocation Anisotropy of growth velocity as to seed orientation affected on crystal morphology and surface morphology.

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The Variation of Radiative Equilibrium Temperatures with the Ice Crystal Habits and Sizes in Cirrus Clouds (권운 내 빙정의 종류와 크기에 따른 복사 평형 온도 변화)

  • Jee, Joon-Bum;Lee, Won-Hak;Lee, Kyu-Tae
    • Atmosphere
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    • v.20 no.4
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    • pp.427-436
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    • 2010
  • The single-scattering optical properties of ice crystals in cirrus clouds by the aircraft measurement data were investigated, and the radiative equilibrium temperatures and radiative fluxes were calculated and analyzed by radiative convective model with the variations of ice crystal habits and sizes in cirrus clouds. The homogeneous cloud is assumed to be in the layer 200~260 hPa with an ice crystal content of $10gm^{-2}$ for the flux calculation. The profiles of temperature, humidity, and ozone typical of mid-latitude summer are used. The surface albedo is assumed to be 0.2 for all spectral bands and the cosine of solar zenith angles is 0.5. The result of radiative equilibrium temperature at surface was less than surface temperature of the standard atmosphere data in case of smaller effective ice crystal size and larger optical thickness. The column, aggregation and plate in 6 ice crystal habits were the most effective in positive greenhouse effect and bullet-4 was the worst in it. At the surface, the maximum difference of equilibrium temperature by 6 kinds of ice crystal habits were about 3~15 K with 30 sample aircraft measurement data.

Effect of the Molecular Structure of Rubbed Polyimide Films for Surface Liquid Crystal Alignment of Nematic Liquid Crystal (네마틱 백정의 표면 액정 배향에관한 폴리이미드막의 분자 구조의 효과)

  • 서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.232-234
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    • 1996
  • We have investigated the effect of molecular structure of polymer of rubbed polyimide (PI) films for surface liquid crystal alignment. To obtain surface alignment effect of Polymer molecular structure, we measured the polar (out of plane-tilt) anchoring strength and surface ordering of 5CB on rubbed PI surfaces. We have found that the polar anchoring strength of 5CB is depend on the polymer molecular structure of these unidirectionally rubbed PI surfaces.

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Silicon melt motion in a Czochralski crystal puller (쵸크랄스키 단결정 장치에서의 실리콘유동)

  • 이재희;이원식
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.27-40
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    • 1997
  • The heat in Czochralski method is transfered by all transport mechanisms such as convection, conduction and radiation and convection is caused by the temperature difference in the molden pool, the rotations of crystal or crucible and the difference of surface tension. This study delvelops the simulation model of Czochralski growth by using the finite difference method with fixed grids combined with new latent heat treatment model. The radiative heat transfer occured in the surfce of the system is treated by calculating the view factors among surface elements. The model shows that the flow is turbulent, therefore, turbulent modeling must be used to simulate the transport phenomena in the real system applied to 8" Si single crystal growth process. The effects of a cusp magnetic field imposed on the Czochralski silicon melt are studied by numerical analysis. The cusp magnetic field reduces the natural and forced convection due to the rotation of crystal and crucible very effectively. It is shown that the oxygen concentration distribution on the melt/crystal interface is sensitively controlled by the change of the magnetic field intensity. This provides an interesting way to tune the desired O concentration in the crystal during the crystal growing.

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Consideration on Various Conditions of Two-Dimensional Crystal Arrays for the Next Generation PET Detector

  • Tsuda, Tomoaki;Murayama, Hideo;Kawai, Hideyuki;Inadama, Naoko;Umehara, Takaya;Kasahara, Takehiro;Orita, Narimichi
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2002.09a
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    • pp.318-321
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    • 2002
  • As a part of the next generation PET project, we have developed a depth of interaction detector which is consist of three-dimensional arrays of GSO crystal elements sized 2.9mm ${\times}$ 2.9mm ${\times}$ 7.5mm. The basic structure of a detector block is 4-stages in depth, one stage is composed of 2 by 2 array of the crystal elements. The blocks are optically coupled to a position sensitive photomultiplier tube. Each crystal element can be in different conditions; rough or chemical etching for the crystal surface. The effect of the difference of crystal surface condition on the detector performance was analyzed in one-dimensional crystal array as a basic study for the three-dimensional detector by a simple model which is considered only probabilities of transmission, reflect and absorption of photons are in a crystal. As the next step, we investigated the effect of different crystal surface condition in a "U shaped detector" which is an array of stacked crystals bending at the center.

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