• Bulletin of the Korean Chemical Society
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• 제21권11호
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• pp.1085-1089
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• 2000

The effect of 2-hydroxyacetophenone-aroyl hydrazone derivatives on the inhibition of copper corrosion in 3N nitric acid solution at 303 K was investigated by galvanostatic polarization and thermometric techniques. A significant decrease in the cor rosion rate of copper was observed in the presence of the investigated compounds. The corrosion rate was found to depend on the nature and concentrations of the inhibitors. The degree of surface coverage of the adsorbed inhibitors is determined from polarization measurements, and it was found that the results obey the Frumkin adsorption isotherm. The inhibitors acted as mixed-type inhibitors, but the cathode is more polarized. The relative inhibitive efficiency of these compounds has been explained on the basis of structure dependent electron donor properties of the inhibitors and the nature of the metal-inhibitor interaction at the surface. Also, some thermodynamic data for the adsorption process ( ΔGa* and f ) are calculated and discussed.

• 한국환경복원기술학회지
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• 제6권1호
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• pp.28-33
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• 2003

In this study, we observed air temperature to make clear that land coverage condition and stand form has a certain relationship to air temperature during the night in various green space. And with revolution analysis, we interpreted relationship of air temperature distribution in the green space, The way of analysis is this land coverage rate and air temperature, of number of tree volume of tree air temperature. With this experimental result, we can propose green plan, which is taking into consideration lower effect of air temperature. In this result, lower zone is formed in forest and water area, higher zone is formed in paved surface and barren ground. but this gap is a little. arbor+subarbor area, in the point of water area surrounded stand is formed relative lower air temperature. As a result to make up efficiency lower air temperature area, it is needed to make water area which has surrounded forest, and it is needed to make stand form lower air temperature 2~3 layer forest. In order of arbor, subarbor, shrub, the lower air temperature is more effect.

• Journal of Periodontal and Implant Science
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• 제30권3호
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• pp.651-661
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• 2000

A mucogingival grafting procedure has been developed to cover denuded root surface. The subepithelial connective tissue graft technique is very predictable and allows for a good esthetic results and minimum patient discomfort on the palate. However, in areas where there is a lack of vestibular depth and keratinized attached tissue, the presence of frena or heavy muscle attachment, covering the connective tissue graft with a mucosal flap is very difficult. The purpose of this study is to evaluate an alternative technique of root coverage using the free connective tissue graft. The results were as follows: 1. Probing depths didn't seem to vary significantly from the preoperative to postoperative period. 2. The amount of keratinized tissue showed an increase of $5.9{\pm}0.97mm$ from the preoperative level. 3. Total clinical exposed root coverage increase 72.2% compare with preoperative level. 4. The shrinkage from gingival margin is $4.2{\pm}1.15mm$ and the mean shrinkage rate is 40.1%. 5. The depth of the vestibule increased with the average distance from cementoenamel junction to mucogingival junction being $7.4{\pm}1.65mm$.

• 아시안잔디학회지
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• 제15권4호
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• pp.181-186
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• 2001

본 연구는 토지피복현황과 수림형태 등이 다양한 도시녹지를 대상으로 기온저감효과와의 관련성을 파악한 결과 아래와 같은 효과가 실증되었다. 그 결과를 바탕으로 녹지 내의 토지피복현황과 기온분포, 토지피복비율 및 녹적량과 기온 저감효과와의 관련성을 회귀분석 등에 의해 해석하였다. 그 결과, 포장면과 나지 주변에서는 고온역이, 수림지와 수면 주변에서는 저온역이 형성되었다. 특히, 교목＋소교목층으로 피복되어 있는 구역과 수림으로 둘러싸인 수면, 소하천 주변에는 상대적으로 낮은 기온이었다. 또한, 저온을 형성하는 메커니즘은 토지피복비율(수림지, 초지, 수면)등이고, 그 토지피복의 종류와 비율에 따라 기온저감효과가 서로 달랐다. 더욱이 녹정량과 기온과의 관계는 부의 상관을 나타냈고, 그 효과는 교목, 소교목, 관목의 순이다.

• 대한금속재료학회지
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• 제46권5호
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• pp.296-303
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• 2008

Hydrogen permeation through dense palladium-based membranes has attracted the attention of many scientists largely due to their unmatched potential as hydrogen-selective membranes for membrane reactor applications. Although it is well known that the permeation mechanism of hydrogen through Pd involves various processes such as dissociative adsorption, transitions to and from the bulk Pd, diffusion within Pd, and recombinative desorption, it is still unclear which process mainly limits hydrogen permeation at a given temperature and hydrogen partial pressure. In this study, we report an all-electron density-functional theory study of hydrogen permeation through Pd membrane (using VASP code). Especially, we focus on the variation of the energy barrier of the penetration process from the surface to the bulk with hydrogen coverage, which means the large reduction of the fracture stress in the brittle crack propagation considering Griffith's criterion. It is also found that the penetration energy barrier from the surface to the bulk largely decreases so that it almost vanishes at the coverage 1.25, which means that the penetration process cannot be the rate determining process.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.79-79
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• 2012

A high temperature and a low temperature plasma process technologies were developed and demonstrated for synthesis, hybrid formation, surface treatment and CVD engineering of nano powder. RF thermal plasma is used for synthesis of spherical nano particles in a diameter ranged from 10 nm to 100 nm. A variety of nano particules such as Si, Ni, has been synthesized. The diameter of the nano-particles can be controlled by RF plasma power, pressure, gas flow rate and raw material feed rate. A modified RF thermal plasma also produces nano hybrid materials with graphene. Hemispherical nano-materials such as Ag, Ni, Si, SiO2, Al2O3, size ranged from 30 to 100 nm, has been grown on graphene nanoplatelet surface. The coverage ranged from 0.1 to 0.7 has been achieved uniformly over the graphene surface. Low temperature AC plasma is developed for surface modification of nano-powder. In order to have a three dimensional and lengthy plasma treatment, a spiral type of reactor has been developed. A similar plasma reactor has been modfied for nano plasma CVD process. The reactor can be heated with halogen lamp.

• 한국태양에너지학회 논문집
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• 제29권6호
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• pp.81-87
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• 2009

The purpose of this study is to evaluate of the outdoor thermal environment by building scale and block type as variable factors. In this study, 18 cases of office in central business district that have different condition are compared about their surface temperature, HIP(Heat Island Potential), and MRT(Mean Radiant Temperature). They are simulated with 3-dimension numerical simulation software named Hoyano-model. The output results contain visualized distribution chart and numerical data. The results of evaluation are as follows. (1)The surface temperature of the building becomes higher as building coverage ratio is higher but floor area ratio is lower. In same conditions, unified block type is maximum $3.2^{\circ}C$ higher than divided block type. (2)HIP shows different daily pattern as block type. During daytime, divided block type is much higher than unified block type but after sunset, it is changed. (3)MRT shows different distribution pattern as sunlight moves expecially at noon. (4)As the results of this study, cases that have high floor area ratio condition show lower surface temperature by tendency to stay low indoor temperature in office building and big rate of windows on building surface.

• 대한원격탐사학회지
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• 제27권6호
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• pp.653-662
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• 2011

Land surface temperature (LST) is a one of the key variables of land surface which can be estimated from geostationary meteorological satellite. In this study, we have developed the three sets of LST retrieval algorithm from MTSAT-2 data through the radiative transfer simulations under various atmospheric profiles (TIGR data), satellite zenith angle, spectral emissivity, and surface lapse rate conditions using MODTRAN 4. The three LST algorithms are daytime, nighttime and total LST algorithms. The weighting method based on the solar zenith angle is developed for the consistent retrieval of LST at the early morning and evening time. The spectral emissivity of two thermal infrared channels is estimated by using vegetation coverage method with land cover map and 15-day normalized vegetation index data. In general, the three LST algorithms well estimated the LST without regard to the satellite zenith angle, water vapour amount, and surface lapse rate. However, the daytime LST algorithm shows a large bias especially for the warm LST (> 300 K) at day time conditions. The night LST algorithm shows a relatively large error for the LST (260 ~ 280K) at the night time conditions. The sensitivity analysis showed that the performance of weighting method is clearly improved regardless of the impacting conditions although the improvements of the weighted LST compared to the total LST are quite different according to the atmospheric and surface lapse rate conditions. The validation results of daytime (nighttime) LST with MODIS LST showed that the correlation coefficients, bias and RMSE are about 0.62~0.93 (0.44~0.83), -1.47~1.53 (-1.80~0.17), and 2.25~4.77 (2.15~4.27), respectively. However, the performance of daytime/nighttime LST algorithms is slightly degraded compared to that of the total LST algorithm.

• 한국진공학회지
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• 제1권1호
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• pp.1-10
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• 1992

Three chemical precleaning methods-degreasing, electropolishing and acidic etching-suitable for stainless steel vacuum chamber have been studied and compared. The techniques used in evaluating and comparing the three treatments include Auger analysis and the measurement of the outgassing rate. The obtained outgassing rates (N2 equivalent) are 1.1 $\times$ 10-10torr l/s cm2 and 3.9 $\times$ 10-11torr l/s cm2 for degreasing electropolishing, and etching method, respectively, after 48 hours from the initial pumpdown at room temperature. A simple model is introduced to analyze the pumpdown curve. Some surface parameters, such as surface coverage, mean residence time, and desorption energy, are calculated from corresponding equations derived from this model.

• 한국신뢰성학회지:신뢰성응용연구
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• 제17권2호
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• pp.122-128
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• 2017

Purpose: To investigate the corrosion inhibition effect of the natural spearmint oil extracted from Mentha Spicata plants on 304 stainless steel in different concentrations of hydrochloric acid. Method: The anti-corrosive effect has been investigated in 0.5m, 1m and 2m HCl using weight loss test and electrochemical polarization method as a function of inhibitor concentration and immersion time in strong chloride environment. The surface morphology was analysed by scanning electron microscopy (SEM). Results: The corrosion rate of steel decreased and inhibition efficiency increased with the increase in inhibitor concentration. Microscopic evaluation revealed significant corrosion in the specimens immersed in uninhibited conditions. Potentiodynamic polarization test results showed an increase in corrosion potential (Ecorr) and decrease in corrosion current (icorr) value with increasing concentration of inhibitor. Conclusions: Immersion of steel in higher concentration of inhibitor resulted in greater surface coverage value and hence lesser number of surface corrosion sites/pores were formed; thus lowering the corrosion rate.