• 한국표면공학회지
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• 제39권4호
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• pp.160-165
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• 2006

Ni-SiC composite coating layers were prepared by electroplating method and their deposition rate, codeposition of SiC, morphology, surface roughness, hardness, wear and friction properties were investigated. It was found that the deposition rate and the codeposition of SiC in the composite coating layer increased with increasing concentration of SiC in the solution only at the early stage. Both of them reached certain maxima and then decreased with increasing concentration of SiC. Rough surface was obtained with increasing codeposition of SiC, which is probably due to the agglomeration of the SiC particle in the vicinity of surface. Vickers hardness increased with increasing codeposition of SiC and heat treatment at $300^{\circ}C$ in air for 1 hour. Wear volume decreased with increasing codeposition of SiC and friction coefficient increased with increasing codeposition of SiC at the early stage, and it became almost constant. Such wear and friction behaviors are desirable for the practical application.

• 한국환경과학회지
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• 제23권3호
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• pp.399-407
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• 2014

In this study, before and after sunset carbon dioxide concentration and air temperature were observed in two points of atmosphere (lower observation point of the GL + 0.1 m, the upper observation point of GL + 1.0 m) on the foreshore at located in Suncheon Bay and their variations were analyzed. Observation was performed on the foreshore on 2~4 August 2010. Instrument (VAISALA, GMP343) was set two hours before sunset and then observation was made continuously for six hours. In three days, observed carbon dioxide concentration was 375~419 ppm, and the air temperature was in the range of $28.7{\sim}32.5^{\circ}C$. The average concentration of carbon dioxide was 388~399 ppm in the upper observation point and 386~396 ppm in the lower observation point. It was higher in the upper observation point and its fluctuations were similar in two observation points. Correlation coefficients between carbon dioxide concentration and air temperature in the upper observation point were in the range of -0.64~-0.88, and were calculated -0.65 to -0.90 in the lower observation point. For the carbon dioxide concentration, correlation coefficients between the upper part and the lower part were very high as 0.98 in three times. For the air temperature, correlation coefficients between the upper part and the lower part were very high as 0.97 and 0.99. In the same observation time, the slope of the linear regression function as carbon dioxide concentration in the lower observation point for the upper observation point was in the range of 0.97~1.01. Carbon dioxide concentration was slightly higher in the upper observation point. Because carbon dioxide in the lower observation point was closer on the surface of the foreshore and absorbed from atmosphere to the foreshore. In this study, it was showed that the vertical variation of carbon dioxide concentration was insignificant in the several meter scale of atmosphere on the surface of the foreshore.

• 대한기계학회논문집A
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• 제25권12호
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• pp.1911-1918
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• 2001

Recently the non-destructive test technique which uses the grain boundary etching characteristics owing to the variation of material structures has been proposed. However, during in-serviced GEM test there are a lot of variables such as the changes of temperature and concentration of etching solution, the roughness condition of surface polished etc.. The purpose of this paper is to investigate the influences of these test variables on GEM test results in order to establish a reliable and sensitive of GEM evaluation technique. The experiments are conducted in various solution temperatures, 10$\^{C}$, 15$\^{C}$, 20$\^{C}$, and 25$\^{C}$ and in 70% and 100% concentrations of that, and in various surface roughnesses polished by #800, #2000, and 0.3㎛ alumina powder. Through the test with variables, it is verified that the decrease of temperature and concentration of etching solution and the coarsened surface roughness by not using polishing cloth and powder induce some badly and/or greatly influences on GEM test results like grain boundary etching width(W$\_$GB) and intersecting point ratio(N$\_$i/N$\_$0/). Therefore, to get reliable and good GEM test results, it must be prepared the surface of specimen polished by polishing cloth and 0.3㎛ alumina powder and the saturated picric acid solution having 25$\^{C}$ and be maintained the constant temperature(25$\^{C}$) during GEM test.

• 한국토양비료학회지
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• 제49권1호
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• pp.81-86
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• 2016

Heavy metal pollution in agricultural fields at the abandoned metal mines has been serious problems in Korea. In order to manage heavy metal pollution in surface water and soil, numerous remediation strategies have been established. Therefore, main purpose of this research was to examine feasibility of ecological toxicity assessment for establishing management strategy in heavy metal polluted agricultural fields. Heavy metal concentration in surface water and soil was monitored along with ecotoxicity experiment with Daphnia magna and Eisenia fetida. Result showed that high toxicity was observed in heavily polluted agricultural field with heavy metals. In case of mortality of Daphnia magna (85%) and Eisenia fetida (6.7%), the highest ratio was observed when heavy metal concentration in surface and soil was high. Calculated ecotoxicity index (EI) ranged 0.06-0.30 and the highest EI was observed in heavily polluted sites among 5 abandoned metal mines. Overall, ecological toxicity assessment is necessary to evaluate heavy metal pollution in agricultural fields near at the abandoned metal mines along with chemical concentration analysis.

• 대한화장품학회지
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• 제33권1호
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• pp.7-10
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• 2007

수용성 폴리머와 계면활성제의 상호작용을 레올로지와 표면 장력을 측정하여 연구하였다. 본 연구에 사용된 폴리머는 acrylates/$C_{10-30}$ alkyl acrylate crosspolymer (AC), ammonium acryloyldimethyltaurate/VP copolymer (AV)이다. 계면활성제는 PEG-40 hydrogenated castor oil (HC), polysorbate 60 (P60)이다. HC와 P60은 AC 폴리머 주위에서 마이셀을 형성하여 점도를 증가하였다. 그러나, HC는 P60보다 보다 높은 농도 범위에서 점도 증가 거동을 보였다. 같은 농도 범위에서 계면활성제들의 표면장력을 비교해보면, 표면장력이 AC/HC의 농도 증가에 따라 증가한 반면, AC/P60의 농도증가에 대해서는 거의 증가하지 않았다. 이런 결과는 AC/HC 사이의 마이셀이 강하게 조직화된 구조를 형성하기 때문으로 추정된다.

• 환경위생공학
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• 제17권3호
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• pp.99-109
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• 2002

Charcoal $tube/CS_2$ method are more popularly used than any other in the measurement of the working environment for the exposure evaluation of organic solvent, but it is some weak points that the lower accuracy can be obtained on the polar materials and within the range of the low concentration. Thus solvent desorption method has been developed to make accuracy higher and to overcome some weak points. However, because of high price of adsorption tube for thermal desorption and the short of study on its application to the working environment, it is not popularly used in the domestic industrial hygiene fields. This dissertation aims to develop thermal desorption and adsorption tubes for measuring organic solvents in the working environment, by comparing and analyzing breakthrough condition and adsorption capacity with ACF. Specific surface area of ACF used in this study is wider than the one of AC and micropore of ACF related with adsorption has been developed, and adsorption velocity and adsorption amount are very excellent by linking a pore of surface and an inside well into micropore. 1. Result of analysis on physical characteristics of adsorbent, the specific surface area of ACF was 1.3 times higher than that of AC. Distribution ratio of micropore related to adsorption was 94% on ACF and AC. Result of SEM, micropore of the AC is opened to the surface. In contrast, ACF shows that extremely fast adsorption speed. Because of micropore are exposed on the surface and penetrate through each other. 2. Breakthrough characteristics of adsorbents was not different from slop of breakthrough curve. The effluent concentration reaches 10% of initial concentration($C_{out}/C_{in}=0.1$, break point) of ACF was 30~316min longer than that of AC. Therefore, the adsorption capacities of ACF was 1.1~4.6 times higher than that of AC. ACF can be used as a proper adsorbent for measurement of organic solvent.

• 한국재료학회지
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• 제14권6호
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• pp.407-412
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• 2004

Photo decomposition of gas phase benzene by $TiO_2$ thin films chemically deposited on alumina balls were investigated under UV irradiation. Photo decomposition rates were measured in real time during the reaction using a photo ionization detector, which ionizes C-H bonding of benzene molecules and then converts into volatile organic compounds (VOCs) concentrations. From the measuring results, the VOCs concentration increased instantly when IN irradiated because C-H bonds of benzene molecules strongly absorbed on the surface of $TiO_2$ films before the IN irradiation was destroyed by photo decomposition. After that, the VOCs concentration decreased with increasing surface area of $TiO_2$ and reaction time under the IN irradiation. At the optimal conditions for the photo decomposition of gas phase benzene, the reaction rate of the photo decomposition for high concentrations (over 60 ppm) was slow but that of relatively low concentration (under 60 ppm) was fast, due to limited surface area of $TiO_2$ thin films for the reaction. Thus, it is concluded that the photo decomposition rate was mainly affected by the surface area of $TiO_2$ or absorption reaction.

• 한국산학기술학회논문지
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• 제22권6호
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• pp.11-18
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• 2021

나노버블수는 태양광 패널 청소, 도로의 염분 제거, 기계의 정밀 부품 청소 등 다양한 세척 공정에 사용된다. 해양쓰레기 세척 시스템의 전처리에 나노버블을 적용하면 높은 세척 효율과 물 절약이 가능하다. 본 연구에서는 나노버블수의 염분 제거율을 비교하기 위해 NaCl 200,000 mg/L 용액에 목재를 침적시켜 해양쓰레기를 제작하였다. 수돗물과 나노버블수를 이용하여 노즐 종류, 오리피스 직경, 펌프 회전수 및 세척 시간에 따른 목재 표면 염분농도를 비교하였다. 목재 표면 염분농도는 세척시간이 길어질수록 감소하였다. 하지만 물 사용량을 고려한 최적의 세척 시간은 5-10초 사이였다. 노즐의 오리피스 직경이 커질수록 분사압력은 낮아지며, 세척 후 목재 표면 염분농도는 높아졌다. 이는 노즐의 오리피스 직경이 세척 시스템에서 중요한 요인임을 나타낸다. 나노버블수를 이용한 세척 후 목재 표면 염분농도는 수돗물로 세척 후 목재 표면 염분농도에 비해 부채꼴형 노즐은 2.2 %, 원형 노즐은 30.9 % 낮았다. 또한, 나노버블수를 이용한 세척 실험에서 부채꼴형 노즐을 사용하여 세척하였을 때가 원형 노즐을 사용하였을 때보다 목재 표면 염분농도가 약 9.5 mg/L 낮았다.

• 한국표면공학회지
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• 제42권5호
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• pp.197-202
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• 2009

The electrodeposition in acidic aqueous electrolyte bath of cadmium telluride on gold electrodes has been studied by electrochemical analysis. Conventional cyclic voltammetry using potentiostat is considered as a reliable method to study electrochemical behavior of electrodeposition of CdTe. In this paper, the mechanism of CdTe deposition and its cyclic voltammetry were studied with the Te ion concentration, temperature, potential, and scan rate. We also investigated surface morphologies using FESEM and atomic composition of Cd and Te using EDS. Atomic composition of Cd and Te were varied with Te ion concentration in the electrolyte.

• 산업기술연구
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• 제22권A호
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• pp.249-254
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• 2002

The surface of tube-type alumina substrate was modified with a silane coupling agent in order to modify the membrane surface with hydrophobicity. Contact angle of water drops on modified membrane was greater than $90^{\circ}$. The modified membrane was tested in pervaporation and vapor permeation for the recovery of menthol from dilute menthol/water mixture. With increasing menthol concentration in the feed at $45^{\circ}C$, permeation rate of menthol in pervaporation and vapor permeation increased from $0.039(g/m^2hr)$ to $0144(g/m^2hr)$ and from. $0.077(g/m^2hr)$ to $0.297(g/m^2hr)$ respectively. When feed concentration is 0.005(g/L) at $45^{\circ}C$, separation factor for menthol in pervaporation and vapor permeation is 20,7 and 40.5 respectively.