• Title/Summary/Keyword: Surface color change

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Bio-functionalized Gold Nanoparticles for Surface-Plasmon- Absorption-Based Protein Detection

  • Kim, Wan-Joong;Choi, Soo-Hee;Rho, Young-S.;Yoo, Dong-Jin
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4171-4175
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    • 2011
  • Bio-functionalized gold nanoparticles (AuNPs), which bio-specifically interact with biotin-(strept)avidin, were investigated in this study. AuNPs were functionalized with a synthetically-provided biotin-linked thiol (BLT), which was synthesized by amidation of the active ester of biotin with 2-mercaptoethylamine. The BLT-attached AuNP was bio-specific for streptavidin, making it potentially useful for biosensor applications. To test the bio-specific interactions, the colors, absorption spectra and TEM images were investigated for proteins such as streptavidin, cytochrome C, myoglobin and hemoglobin. The colors and absorption spectra changed when streptavidin was added to the BLT-attached AuNP solution. However, the color and spectra did not change when the other proteins were added to the same solution. These results show that the AuNPs provided a colloidal solution with excellent stability and highly selective absorption characteristics for streptavidin as a target molecule. Proteins were also screened in order to identify a general strategy for the use of optical biosensing proteins based on AuNPs. In addition, TEM images confirmed that streptavidin led the BLT-attached AuNPs to aggregate or precipitate.

ULTRAVIOLET MICROSCOPIC STUDY ON LIGNIN DISTRIBUTION IN THE FIBER CELL WALL OF BCTMP

  • Seung-Lak YooN;Yasuo KOJIMA;Lee, Seon-Ho
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.375-380
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    • 1999
  • In order to improve the optical properties of high yield pulp, bleached chemi-thermo-mechanical pulp (BCTMP) was produced from CTMP of Betula maximowicziana Regel by two staged ozone-hydrogen peroxide bleaching. This pulp was used for the evaluation of the improvement of optical properties, chemical characteristics of lignin in fiber, and the relationship between lignin and optical properties in fiber cell wall. By hydrogen peroxide treatment, the brightness was improved, but the post color number (PC No.) was not. There was little improvement on optical properties by ozone treatment, but his could be solved by using two staged ozone-hydrogen peroxide bleaching. The hydrogen peroxide treatment did not make nay change on chemical characteristics of lignin in cell wall, but by ozone treatment, it was found that the non-aromatic conjugated structure was existed in the surface of cell wall, but this could be removed by hydrogen peroxide treatment in two staged ozone-hydrogen peroxide treatment. Therefore, the optical properties was significantly improved due to the removal of non-aromatic conjugated structure.

Effects of Concentration of ZnO Nanoparticles on Mechanical, Optical, Thermal, and Antimicrobial Properties of Gelatin/ZnO Nanocomposite Films

  • Shankar, Shiv;Teng, Xinnan;Rhim, Jong-Whan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.20 no.2
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    • pp.41-49
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    • 2014
  • This study illustrates the synthesis of gelatin based zinc oxide nanoparticle (ZnONPs) incorporated nanocomposite films using different concentrations of ZnONPs. The ZnONPs were oval in shape and the size ranged from 100- 200 nm. The nanocomposite films were characterized by UV-visible, FE-SEM, FT-IR, and XRD. The concentrations of ZnONPs greatly influenced the properties of nanocomposite films. The absorption peaks around 360 nm increased with the increasing concentrations of ZnONPs. The surface color of film did not change while transmittance at 280 nm was greatly reduced with increase in the concentration of ZnONPs. FTIR spectra showed the interaction of ZnONPs with gelatin. XRD data demonstrated the crystalline nature of ZnONPs. The thermostability, char content, water contact angle, water vapor permeability, moisture content, and elongation at break of nanocomposite films increased, whereas, tensile strength and modulus decreased with increase in the concentrations of ZnONPs. The gelatin/ZnONPs nanocomposite films showed profound antibacterial activity against both Gram-positive and Gram-negative food-borne pathogenic bacteria. The gelatin/$ZnONP^{1.5}$ nanocomposite film showed the best UV barrier and antimicrobial properties among the tested-films, which indicated a high potential for use as an active food packaging films with environmentally-friendly nature.

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Studies on the Formation of Liquid Crystal and the Stability in W/O Emulsion Systems using Beeswax and Silicone Surfactant (Beeswax와 실리콘계 계면활성제를 사용한 W/O유화계에서 액정의 형성 및 안정도에 관한 연구)

  • Choi, Moon-Jae;Lee, Young-Moo;Jin, Byung-Suk
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.279-288
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    • 2004
  • Liquid crystal (LC) system was introduced into W/O emulsion in order to enhance the stability and moisturizing effect. The LC system, composed of beeswax, surfactant, and water was formed on the surface of emulsion droplet, which was investigated through a polarized microscope. The phenomenon that the viscosity in W/O emulsion system is decreased with time, was reduced by the formation of LC with the addition of beeswax. Centrifugal separation test showed that the stability of emulsion system was increased with the addition of beeswax to 3%. The color change of vitamin C was delayed in LC emulsion systems, which indicates stabilization effect against the oxidation of vitamin C. Evaporation rate in W/O emulsion was retarded by LC, so that high moisturizing effect is expected in W/O LC system.

Aortoenteric Fistula - A Report of a Case - (대동맥장루 -1예 보고-)

  • 김성수
    • Journal of Chest Surgery
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    • v.22 no.5
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    • pp.823-828
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    • 1989
  • Aortoenteric fistula is an uncommon important complication of aortic reconstruction with a prosthetic graft. The complication often is difficult to diagnose and is associated with poor prognosis. Aortoenteric fistula could be divided into true aortoenteric fistula and paraprosthetic-enteric fistula. In case of true aortoenteric fistula, an actual communication between the gastrointestinal tract and the aortic lumen is present. So, massive gastrointestinal hemorrhage is the presenting manifestation. In paraprosthetic-enteric fistula, characterized by communication between the gastrointestinal tract and the external surface of synthetic vascular prosthesis without actual fistularization into the vascular lumen, the predominant clinical manifestation were sepsis, fever and anemia. We experienced one case of paraprosthetic-enteric fistula in a 16 years old male after abdominal aortic reconstruction with a prosthetic graft. The interval from the operation to onset of symptoms was 40 months. The initial clinical manifestation was sepsis, fever and anemia without massive gastrointestinal hemorrhage. Surgical treatment consists of complete excision of infected graft, two layers closure of jejunal wall defect and pledgets suture of aortic stump with surrounding health tissue. Anatomic revascularization was not able to be done: because of extensive retroperitoneal inflammation and extraanatomic revascularization did not performed due to adequate distal blood supply through rich collateral circulation. After operation, he complained numbness on left foot on moderate exertion and felt coldness on left leg compared with right leg but not showed skin color change. 43 days after operation, he discharged without gait disturbance except numbness on left foot on moderate exertion.

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Prepration and Properties of Blue Tungsten Oxide Nanopowders by High Energy Ball-Mill (고 에너지 볼밀을 이용한 Blue 텅스텐산화물 나노입자의 제조와 특성)

  • Kim, Myung-Jae;Lee, Kwang-Seok;Kim, Kyung-Nam
    • Korean Journal of Materials Research
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    • v.31 no.1
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    • pp.23-28
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    • 2021
  • The purpose of this study is to prepare WO3 nanopowders by high-energy milling in mixture gas (7 % H2+Ar) with various milling times (10, 30, and 60 min). The phase transformation, particle size and light absorption properties of WO3 nanopowders during reduction via high-energy milling are studied. It is found that the particle size of the WO3 decreases from about 30 ㎛ to 20 nm, and the grain size of WO3 decreases rapidly with increasing milling time. Furthermore, the surface of the particles due to the pulverization process is observed to change to an amorphous structure. UV/Vis spectrophotometry shows that WO3 powder with increasing milling times (10, 30, 60 min) effectively extends the light absorption properties to the visible region. WO3 powder changes from yellow to gray and can be seen as a phenomenon in which the progress of the color changes to blue. The characterization of WO3 is performed by high resolution X-ray diffractometry, Field emission scanning electron microscopy, Transmission electron microscopy, UV/Vis spectrophotometry and Particle size analysis.

Long-term and Real-time Monitoring System of the East/Japan Sea

  • Kim, Kuh;Kim, Yun-Bae;Park, Jong-Jin;Nam, Sung-Hyun;Park, Kyung-Ae;Chang, Kyung-Il
    • Ocean Science Journal
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    • v.40 no.1
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    • pp.25-44
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    • 2005
  • Long-term, continuous, and real-time ocean monitoring has been undertaken in order to evaluate various oceanographic phenomena and processes in the East/Japan Sea. Recent technical advances combined with our concerted efforts have allowed us to establish a real-time monitoring system and to accumulate considerable knowledge on what has been taking place in water properties, current systems, and circulation in the East Sea. We have obtained information on volume transport across the Korea Strait through cable voltage measurements and continuous temperature and salinity profile data from ARGO floats placed throughout entire East Sea since 1997. These ARGO float data have been utilized to estimate deep current, inertial kinetic energy, and changes in water mass, especially in the northern East Sea. We have also developed the East Sea Real-time Ocean Buoy (ESROB) in coastal regions and made continual improvements till it has evolved into the most up-to-date and effective monitoring system as a result of remarkable technical progress in data communication systems. Atmospheric and oceanic measurements by ESROB have contributed to the recognition of coastal wind variability, current fluctuations, and internal waves near and off the eastern coast of Korea. Long-tenn current meter moorings have been in operation since 1996 between Ulleungdo and Dokdo to monitor the interbasin deep water exchanges between the Japanese and Ulleung Basins. In addition, remotely sensed satellite data could facilitate the investigation of atmospheric and oceanic surface conditions such as sea surface temperature (SST), sea surface height, near-surface winds, oceanic color, surface roughness, and so on. These satellite data revealed surface frontal structures with a fairly good spatial resolution, seasonal cycle of SST, atmospheric wind forcing, geostrophic current anomalies, and biogeochemical processes associated with physical forcing and processes. Since the East Sea has been recognized as a natural laboratory for global oceanic changes and a clue to abrupt climate change, we aim at constructing a 4-D continuous real-time monitoring system, over a decade at least, using the most advanced techniques to understand a variety of oceanic processes in the East Sea.

Time-series Analysis of Pyroclastic Flow Deposit and Surface Temperature at Merapi Volcano in Indonesia Using Landsat TM and ETM+ (Landsat TM과 ETM+를 이용한 인도네시아 메라피 화산의 화산쇄설물 분포와 지표 온도 시계열 분석)

  • Cho, Minji;Lu, Zhong;Lee, Chang-Wook
    • Korean Journal of Remote Sensing
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    • v.29 no.5
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    • pp.443-459
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    • 2013
  • Located on Java subduction zone, Merapi volcano is an active stratovolcano with a volcanic activity cycle of 1-5 years. Merapi's eruptions were relatively small with VEI 1-3. However, the most recent eruption occurred in 2010 was quite violent with VEI 4 and 386 people were killed. In this study, we have attempted to study the characteristics of Merapi's eruptions during 18 years using optical Landsat images. We have collected a total of 55 Landsat images acquired from July 6, 1994 to September 1, 2012 to identify pyroclastic flows and their temporal changes from false color images. To extract areal extents of pyroclastic flows, we have performed supervised classification after atmospheric correction by using COST model. As a result, the extracted dimensions of pyroclastic flows are nearly identical to the CVP monthly reports. We have converted the thermal band of Landsat TM and ETM+ to the surface temperature using NASA empirical formula and calculated time-series of the mean surface temperature in the area of peak temperature surrounding the crater. The mean surface temperature around the crater repeatedly showed the tendency to rapidly rise before eruptions and cool down after eruptions. Although Landsat satellite images had some limitations due to weather conditions, these images were useful tool to observe the precursor changes in surface temperature before eruptions and map the pyroclastic flow deposits after eruptions at Merapi volcano.

CO and Soot Yields of Wood Combustibles for a Kitchen Fire Simulation (주방 화재시뮬레이션을 위한 목재 가연물의 CO 및 Soot Yields)

  • Mun, Sun-Yeo;Hwang, Cheol-Hong;Kim, Sung-Chan
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.76-84
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    • 2019
  • Experimental studies using an open cone calorimeter were conducted to provide information on the CO and soot yields of wood combustibles required for a kitchen fire simulation of PBD. A total of eight specimens were examined for medium density fiberboard (MDF) and particle board (PB), which are used widely in kitchen furniture production, depending on the water content, surface processing method, and surface color. The thermal penetration time related to the fire spread rate in the depth direction differed significantly according to the surface processing treatment method, even for a specimen of identical thickness. The CO yield ($y_{CO}$) of the MDF and PB series did not change significantly according to the combustion mode and surface treatment process in flaming mode. On the other hand, $y_{CO}$ was approximately 10 times higher in smoldering mode than in flaming mode. The soot yield ($y_{soot}$), however, varied considerably depending on the combustion mode and surface treatment process. In particular, a higher $y_{soot}$ was found in flaming mode and in the surface-treated specimens. Finally, the $y_{CO}$ and $y_{soot}$ of MDF and PB measured for the kitchen fire simulation of PBD were applied.

Changes in the Spawning Ground Environment of the Common Squid, Todarodes pacificus due to Climate Change (기후변화에 따른 살오징어(Todarodes pacificus) 산란장 환경 변화)

  • Kim, Yoon-ha;Jung, Hae Kun;Lee, Chung Il
    • Ocean and Polar Research
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    • v.40 no.3
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    • pp.127-143
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    • 2018
  • This study analyzed the influence of climate change on the spawning ground area of the common squid, Todarodes pacificus. To estimate long term changes in the area of the spawning ground of the common squid, water temperature at 50 m deep that can be inferred from sea surface temperature (SST) based on both NOAA/AVHRR (1981.07-2002.12) and MODIS/AQUA (2003.01-2009.12) ocean color data was analyzed. In addition, five climate indices, Arctic Oscillation Index (AO), Siberian High Index (SH), Aleutian Low Pressure Index (ALP), East Asia Winter Monsoon Index (EAWM) and Pacific Decadal Oscillation (PDO) which are the main indicators of climate changes in the northwestern Pacific were used to study the relationship between the magnitude of the estimated spawning ground and climate indices. The area of the estimated spawning ground was highly correlated with the total catch of common squid throughout four decades. The area of the estimated spawning ground was negatively correlated with SH and EAWM. Especially, PDO was negatively correlated with the area of the spawning ground in the northwestern Pacific (r = -0.39) and in the southern part of the East Sea (r = -0.38). There was a positive relationship between the AO and the area of the spawning ground in the northwestern Pacific (r = 0.46) as well as in the southern part of the East Sea (r = 0.32). Temporally, the area of the winter spawning ground in the southern part of the East Sea in the 1980s was smaller than those areas in the 1990s and 2000s, because the area was disconnected with the western coastal spawning ground of Japan in the 1980s, while the area had been made wider and more continuous from the Korea strait to the western coastal water of Honshu in the 1990s and 2000s.