• Title/Summary/Keyword: Surface coating layer

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Study of COD Removal Efficiency from Synthetic Wastewater by Photocatalytic Process

  • Rojviroon, Orawan;Rojviroon, Thammasak;Sirivithayapakorn, Sanya
    • Environmental Engineering Research
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    • v.19 no.3
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    • pp.255-259
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    • 2014
  • In this research, we compared the COD removal efficiencies of titanium dioxide ($TiO_2$) thin films coated on the surfaces of borosilicate glass that prepared by three different numbers of coating layer; i) 3 layers ii) 4 layers and iii) 5 layers by sol-gel method. All of the prepared $TiO_2$ thin films consisted of pure anatase crystalline structure with grain sizes in the range 20-250 nm. The calculated optical band gaps of the $TiO_2$ thin films were 3.24. The total apparent surface area per total weight of $TiO_2$ thin films were 4.74, 3.86 and $2.79m^2g^{-1}$ for 3, 4 and 5 layers coating, respectively. The kinetics of the photodegradation reactions of COD under UVA light source were described by the Langmuir-Hinshelwood (L-H) kinetic model. The specific rates of the photodegradation of $TiO_2$ thin films at 3 layers coating was $1.40{\times}10^{-4}min^{-1}mW^{-1}$, while for the 4 layers coating and the 5 layers coating were $1.50{\times}10^{-4}$ and $4.60{\times}10^{-4}min^{-1}mW^{-1}$, respectively. The photocatalytic performance of COD degradation was higher with smaller grain size, higher surface area and narrow optical band gaps. Moreover, the numbers of coating layer on substrate also have great influence for kinetic of COD removal.

Study on the Compositional Characteristics of the PCS Coating Layer by Curing Treatment for the Protection of Graphite Mold Surface (흑연 금형 표면 보호용 PCS 코팅층의 열경화에 의한 조성비 조절 특성 연구)

  • Kim, Kyoung-Ho;Lee, Yoonjoo;Shin, Yun-Ji;Jeong, Seong-Min;Lee, Myung-Hyun;Bae, Si-Young
    • Journal of the Korean institute of surface engineering
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    • v.53 no.6
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    • pp.293-299
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    • 2020
  • The characteristics of the polycarbosilane (PCS)-based composite ceramic layer was studied by controlling the curing temperature. The stress at the interface of the graphite and SiOC composite layer was evaluated v ia finite element analysis. As a result, the tensile stress was released as the carbon ratio of the SiC decreases. In experiment, the SiOC layers were coated on the VDR graphite block by dip-coating process. It was revealed that the composition of Si and C was effectively adjusted depending on the curing temperature. As the solution-based process is employed, the surface roughness was reduced for the appropriate PCS curing temperature. Hence, it is expected that the cured SiOC layer can be utilized to reduce cracking and peeling of SiC ceramic composites on graphite mold by improving the interfacial stress and surface roughness.

Analysis of Corrosion Characteristics for TiN- and Ti/TiN-coated Stainless Steel Bipolar Plate in PEMFC (고분자전해질 연료전지에서 TiN과 Ti/TiN이 코팅된 스텐레스 강 분리판의 부식 특성)

  • Han, Choonsoo;Chae, Gil-Byung;Lee, Chang-Rae;Choi, Dae-Kyu;Shim, Joongpyo
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.118-127
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    • 2012
  • TiN or Ti/TiN was coated on stainless steel as bipolar plate in polymer electrolyte membrane fuel cells (PEMFCs) to improve their corrosion resistance and electric conductivity, and their properties were examined under fuel cell operating condition. After 200 hours operation, the behaviors for the corrosion, crack and dissolution of coating layer were investigated by various techniques. The corrosion and exfoliation of coating layer were considerably generated except for SUS316L-Ti/TiN after fuel cell operation even if the electric conductivity and corrosion resistance of coated stainless steel bipolar plates were improved. The adoption of Ti layer between TiN layer and the surface of stainless steel enhanced the adhesion of TiN layer and decreased the possibility of corrosion by the increase of coating layer.

Mechanical and Electrical Reliability of Silver Nanowire Film on Flexible Substrate (유연기판 위에 제작된 Silver Nanowire 필름의 기계 및 전기적 신뢰성 연구)

  • Lee, Yo Seb;Lee, Won Jae;Park, Jin Yeong;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.93-99
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    • 2016
  • In this paper, we investigated the mechanical and electrical reliability of silver nanowire (AgNW) films. In particular, the durability and reliability of AgNW films were studied when the AgNW film was subjected to the bending deformation under current flow. The electrical durability of AgNW was evaluated by observing changes in heat generation and current density occurring in AgNW through voltage and current tests. The AgNW film showed a constant resistance change up to a bending radius of 2 mm and 200,000 cycles in the bending fatigue tests. The over-coating layer has an effect of improving the durability of the AgNW film. In the case of AgNW with the over-coating layer, heat was uniformly dissipated on the surface of AgNW film, whereas in the case of AgNW film without the over-coating layer, heat was generated locally. In the bending test under the current flow, the current density of the AgNW film was continuously decreased up to 52.4%. During bending, the AgNW was deformed due to mechanical deformation such as tensile, bending and sliding of the AgNW, consequently contact resistance of the AgNW was increased, leading to a electrical breakdown of AgNW by Joule heating. It was found that the application of the over-coating layer can improve the electrical and mechanical reliability of the AgNW film.

EFFECTS OF TITANIUM SURFACE COATING ON CERAMIC ADHESION (타이타늄 표면 코팅이 도재 결합에 미치는 영향)

  • Kim, Yeon-Mi;Kim, Hyun-Seung;Lee, Kwang-Min;Lee, Doh-Jae;Oh, Gye-Jeong;Lim, Hyun-Pil;Seo, Yoon-Jung;Park, Sang-Won
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.5
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    • pp.601-610
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    • 2007
  • Statement of problem: The adhesion between titanium and ceramic is less optimal than conventional metal-ceramic bonding, due to reaction layer form on cast titanium surface during porcelain firing. Purpose: This study characterized the effect of titanium-ceramic adhesion after gold and TiN coating on cast and wrought titanium substrates. Material and method: Six groups of ASTM grade II commercially pure titanium and cast titanium specimens$(13mm{\times}13mm{\times}1mm)$ were prepared(n=8). The conventional Au-Pd-In alloy served as the control. All specimens were sandblasted with $110{\mu}m\;Al_2O_3$ particles and ultrasonically cleaned for 5min in deionized water and dried in air before porcelain firing. An ultra-low-fusing dental porcelain (Vita Titankeramik) was fused on titanium surfaces. Porcelain was debonded by a biaxial flexure test at a cross head speed of 0.25mm/min. The excellent titanium-ceramic adherence was exhibited by the presence of a dentin porcelain layer on the specimen surface after the biaxial flexure test. Area fraction of adherent porcelain (AFAP) was determined by SEM/EDS. Numerical results were statistically analyzed by one-way ANOVA and Student-Newman-Keuls test at ${\alpha}=0.05$. Results: The AFAP value of cast titanium was greatest in the group 2 with TiN coating, followed by group 1 with Au coating and the group 3 with $Al_2O_3$ sandblasting. Significant statistical difference was found between the group 1, 2 and the group 3 (p<.05). The AFAP value of wrought titanium was greatest in the group 5 with TiN coating, followed by the group 4 with Au coating and the group 6 with $Al_2O_3$ sandblasting. Conclusion: No significant difference was observed among the three groups (p>.05). The AFAP values of the cast titanium and the wrought titanium were similar. However the group treated with $Al_2O_3$ sandblasting showed significantly lower value (p<.05).