• 한국표면공학회지
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• 제34권5호
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• pp.510-515
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• 2001

It was first time that low frequency R.F. derived plasma enhanced MOCVD with frimethylborate precursor was used to fabricate a new ternary compound $BO_{x}$ $N_{y}$ . The formation of BON molecule was resulted from nitrogen nitrifying B-O, and forming the angular molecule structure proved by XPS and FT-IR results. The relationship between hardness and film thickness was studied. An thickness-independent hardness was fond about 10 GPa. The empirical calculation of band-gap and UV test result showed that our deposited $BO_{x}$ $N_{y}$ thin film was semiconductor material with 3.4eV of wide band gap. The electrical conductivity, $4.8$\times$10^{-2}$ /($\Omega$.cm)$^{-1}$ also confirmed that $BO_{x}$ $N_{y}$ has a semiconductor property. The roughness detected from the as-grown films showed that there was no serious bombarding effect due to anion in the plasma occurring in the RF frequency derived plasma.

• 펄프종이기술
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• 제30권2호
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• pp.40-46
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• 1998

This study was aimed to investigate any improvement of dewatering and energy saving on the papermaking process when the various types of fillers were used, i.e., clay, talc and grounded calcium carbonate (GCC). Cationic polyelectrolyte and alum coagulants neutralized the surface charge of the filler particles and the filler particles were coagulated. The rates of dewatering and drying were investigated. The results indicated that clay tended to intense anion, while talc and GCC tended to anion trend nearly to neutrality. Clay and talc added with EPI-DMA, P-DADMAC and alum respectively as optimum levels showed a significant efficiency on the dewatering and the turbidity dissipation. However, the turbidity and dewatering rate of GCC decreased, when GCC was added with EPI-DMA and P-DADMAC respectively Drying rate of clay was increased when coagulant added. However drying rates of talc and GCC were not affected by coagulant, while the apprarent drying time of talc and GCC in the absence of any coagulant was shorter than the clay in the presence of a coagulant. The result confirmed that talc or GCC was more efficient than clay on the dewatering and drying, which is consistent with a general knowledge in the collodal science.

• 한국환경과학회지
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• 제13권10호
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• pp.921-928
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• 2004

The photocatalytic decolorization of Rhodamine B (RhB) was studied using immobilized $TiO_2$ and fluidized bed reactor. Immobilized $TiO_2$(length: 1$\~$2 mm, width: 1$\~$3 mm, thickness: 0.5$\~$2 mm) onto silicone sealant was employed as the photocatalyst and a 30 W germicidal lamp was used as the light source and the reactor volume was 4.8 L. The effects of parameters such as the amounts of photocatalyst, initial concentration, initial pH, superficial velocity, $H_2O_2$ and anion additives. ($NO_3^{-},\;SO_4^{2-},\;Cl^{-},\;CO_3^{2-}$) The results showed that the optimum dosage of the immobilized $TiO_2$ were 87.0 g/L. Initial removal rate of RhB of the immobilized $TiO_2$ was 1.5 times higher than that of the powder $TiO_2$ because of the adsorption onto the surface of immobilized $TiO_2$ In the conditions of acidic pH, initial reaction rate was increased slowly and reaction time was shorted. The effect of anion type on the reaction rate was not much.

• Bulletin of the Korean Chemical Society
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• 제12권2호
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• pp.143-148
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• 1991

In the unhydrated and hydrated states, conformational free energies of L-ascorbic acid anion (AAA) were computed with an empirical potential function and the hydration shell model (a program CONBIO). The conformational energy was minimized from possible starting conformations expressed with five torsion angles of the molecule. The conformational entropy of each low energy conformation in both states was computed using a harmonic approximation. As found in L-ascorbic acid (AA), intramolecular hydrogen bonds (HBs) are proved to be of significant importance in stabilizing the overall conformations of AAA in both states, and give the folded conformations, which are quite different from those in crystal. There are competitions between HBs and hydration around O3 atom of the lactone ring and hydroxyls of the acyclic side chain. Especially, the whole conformation of AAA is strongly dependent on the water-accessibility of O3 atom. Though there is a significant effect of the hydration on conformational surface, the lowest energy conformation of the unhydrated AAA is conserved. The different patterns of HBs and hydration result in the conformations of AAA in both states being different from those of AA. It can be drawn by several feasible conformations obtained in the hydrated state that there exists an ensemble of several conformations in aqueous solution.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1996년도 춘계학술발표회 논문집
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• pp.158-161
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• 1996

Microfibers of Poly(ethylene terephthalate)(PET)/Nylon 6 (P/N) was heat set at 170C in a fixed state and then treated with hydrazine at 30C for 5, 10, 15, 20, 30 and 40 h. Weight loss from the hydrazine treatment increased according to the hydrazine concentration(Fig.1). In order to investigate in detail the effect of the electrostatic attraction between the dye anion and hydrazide groups in cooperated by hydrazinolysis, -potential of P/N fiber was measured by streaming potential method. The surface charge density, o, of the fiber was evaluated from the -potential.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2005년도 추계학술대회 논문집
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• pp.80-84
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• 2005

Many important properties in colloidal systems are usually determined by surface charge ($\zeta$-potential) of the contacted solid surface. In this study, $\zeta$-potential of glass $\mu$-channel was evaluated from the electro-osmotic velocity distribution. The electro-osmotic velocity inside a glass $\mu$-channel was measured using a micro-PIV velocity field measurement technique. This evaluation method is more simple and easy to approach, compared with the traditional streaming potential technique. The $\zeta$-potential in the glass $\mu$-channel was measured for two different mole NaCl solutions. The effect of an anion surfactant, sodium dodecyl sulphate (SDS), on the electro-osmotic velocity and $\zeta$-potential in the glass surface was also studied. In the range of $0\∼6$mM, the surfactant SDS was added to NaCl solution in four different mole concentrations. As a result, the addition of SDS increases $\zeta$-potential in the surface of the glass $\mu$-channel. The measured $\zeta$-potential was found to vary from-260 to-70mV. When negatively charged particles were used, the flow direction was opposite compared with that of neutral particles. The $\zeta$-potential has a positive sign for the negative particles.

• Journal of Electrochemical Science and Technology
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• 제2권1호
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• pp.8-13
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• 2011

Interfacial compatibility between the Si-Cu electrode and diluted ionic liquid electrolyte containing 50 vol.% of 1M lithium bis(trifluoromethanesulfonyl)imide (LiTFSI)/1-methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide (MPP-TFSI) and 50 vol.% dimethyl carbonate (DMC) in a lithium cell and dilution effect on surface chemistry are examined. ex-situ ATR FTIR analysis results reveal that the surface of the Si-Cu electrode cycled in the diluted ionic liquid electrolyte is effectively passivated with the SEI layer mainly composed of carboxylate salts-containing polymeric compounds produced by the decomposition of DMC. Surface species by the decomposition of TFSI anion and MPP cation are found to be relatively in a very low concentration level. Passivation of electrode surface with the SEI species contributes to protect from further interfacial reactions and to preserve the electrode structure over 200 cycles, delivering discharge capacity of > 1670 $mAhg^{-1}$ and capacity retention of 88% of maximum discharge capacity.

• 전자공학회논문지A
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• 제30A권11호
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• pp.99-104
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• 1993

We analyzed the D.I. water used in wet cleaning process of semiconductor device manufacturing both at the D.I. water plant and at the wafer cleaning bath to detect the impurity source of D.I. water contamination. This shows that the quantity of impurity is related to the resistivity of D.I. water, and we found that the cleanliness of the wafer surface processed in D.I. water bath was affected by the degree of the ionic impurity contamination. So we evaluated the cleaning effect as different method for Fe ion, having the best adsoptivity on wafer surface. Moreover the temperature effect of the D.I. water is investigated in case of anion in order to remove the chemical residue after wet process. In addition to the control of D.I. water resistivity, chemical analysis of impurity control in D.I. water should be included and a suitable cleaning an drinsing method needs to be investigated for a high yielding semiconductor device.

• 복식문화연구
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• 제15권2호
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• pp.276-283
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• 2007

The purpose of this study were to investigate characteristic changes on nonwoven fabric for disposable work clothes by the yellow soil printing. It separate grind yellow soil as two different size of particles $45\sim52{\mu}m$ and $53\sim65{\mu}m$ for hand screen printing on three kind of nonwoven fabrics. To examine the effect of yellow soil printing on nonwoven fabric were to observe, dyeability by using spectrophotometer, moisture regain by oven method, air permeability, anion property and antibacterial activity. The results were as follows: When yellow soil concentration increased from 5 to 10%, K/S value also increased from 1.05 to 1.88. When yellow soil concentration increased, moisture regain also increased. In same concentration, moisture regain occurred higher as particle of small size. Air permeability decreased when the charcoal printing concentration increased. Anion occurrence appeared $140\sim160ion/cc$ from three different kinds of nonwoven fabrics in 3% and 9% yellow soil concentration. Therefore, occurred anion ineffectively. In concentration of 3%, rate of deodorization measured as 89%, 83% and 87%, and 9% concentration caused 96%, 86% and 93% of high deodorization. Antibacterial activity examination in nonfinished nonwoven fabric resulted range of 60%, however, 3% and 9% concentration finished nonwoven fabric resulted 99.9% of excellent antibacterial activity Surface temperature increased $1.5\sim2^{\circ}C$ by yellow soil finishing.

• 한국염색가공학회지
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• 제4권3호
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• pp.82-90
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• 1992

To optimize the foam dyeing procedures for polyester and polyester/nylon blended non-woven fabrics, the effects of organic solvents and surfactants were investigated by measuring the foam heights and surface tensions of the foam dyeing solution. The results of the experiments can be summarized as follows: 1) Organic solvents and surfactants (sodium lauryl sulphate: SLS) solution lower the surface tension (ST) of the water, but ST lowering rate of SLS solution is greater than that of solvents. For a 0.25% SLS solution, the minimum surface tension was 30.3 dyne/cm, which is nearly the same value for organic solvents. 2) For 0.25% SLS solutions, additional adding of a 4.0% organic solvent makes the foam height (FH) be its maximum. 3) At 0.6 g/ι dye concentration, incorporation of 0.4% SLS makes the surface tension of the foam solution be its minimum. The foam height did not show any trend due to the dye type. 4) The effect of foam stabilizers (sodium alginate (Alg-Na) and hydroxy ethyl cellulose (HEC)) were also investigated. The foam height of the foaming solution with HEC was greater than that with Alg-Na. The foam stability of the foaming solution with Alg-Na was better than that with HEC.