• Title/Summary/Keyword: Surface and interfaces

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Quantitative Analysis on Electrochemical Phenomena at the Colloidal Semiconductor Interfaces (Colloid 半導體 界面의 電氣化學的 現象에 關한 定性的 解析)

  • Chun, Jang-Ho
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.10
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    • pp.1209-1215
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    • 1988
  • A space charge effect at the doped silicon semiconductor/organic solvent ($C_6H_6$, $CH_3OH$, $C_2H_5OH$) interfaces and a mechanism for two reversals of zeta potentials at the undoped polycrystalline gallium arsenide semiconductor/electrolyte (NaCl, KCl, KI solution) interfaces has been qualitatively analyzed using microelectrophoresis measurements. It has been found that the space charge effect in the organic solvents can be neglected and the two reversals of zeta potentials depend on surface states, specific adsorption, electronegativity and size of specifically adsorbed ions at the undoped polycrystalline gallium arsenide/electrolyte interfaces. The position of shear plane of colloidal semiconductors is a fixed distance from the surface and is almost or exactly coincides with the outer Helmholtz plane (OHP).

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Microstructural observations of shear zones at cohesive soil-steel interfaces under large shear displacements

  • Mamen, Belgacem;Hammoud, Farid
    • Geomechanics and Engineering
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    • v.25 no.4
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    • pp.275-282
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    • 2021
  • Failure mechanism which can affect geotechnical infrastructures (shallow foundations, retaining walls, and piles) constitutes one of the most encountered problems during the design process. In this respect, the shear behavior of interfaces between grained soils and solid building materials, as well as those between cohesive soils should be investigated. Therefore, a range of ring shear tests with different cohesive soils and stainless-steel interfaces have been carried out through the Bromhead apparatus that allows simulating large displacements along a failure surface. The effects of steel rings roughness and soil type on the residual friction coefficient and the shear zone features (structure, thickness, and texture orientation angle) have been investigated using the Scanning Electron Microscopy. The obtained results indicate that the residual friction coefficient and the structural characteristics of the shear zone vary according to the surface roughness and the soil type. Scanning electron microscopy reveals that the particles inside the shear zone tend to be re-oriented. Also, the shear failure mechanism can be identified along with the interface, within the soil, or simultaneously at the interface and within the soil specimen.

Wettability of Biomimetic Riblet Surface like Sharkskin (상어 표피 모사 리블렛 구조의 젖음성 평가)

  • Kong, Yu Sik;Kim, Tae Wan
    • Tribology and Lubricants
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    • v.29 no.5
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    • pp.304-309
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    • 2013
  • Shark skin has functionalities such as self-cleaning and antifouling; it also exhibits excellent drag reduction owing to a hierarchical structure of microgrooves and nanometer-long chain mucus drag reduction interfaces around the shark body. In this study, the wettability of a shark skin surface and its replicas are evaluated. First, a shark skin template is taken from a real shark. Then, shark skin replicas are produced directly from a shark skin template, using a micromolding technique. The quantitative replication precision of the shark skin replicas is evaluated by comparing the geometry of the shark skin template to the replica using 2D surface profiles. Contact angles at the solid-air-water interfaces are evaluated for the shark skin template and its replicas under two conditions: with and without hydrophobic coating. The results show that the microriblets on shark skin improve the hydrophobic feature and play a critical role in self-cleaning.

A STUDY ON AN INTERFACE CAPTURING METHOD APPLICABLE TO UNSTRUCTURED MESHES FOR THE ANALYSIS OF FREE SURFACE FLOW (자유표면유동 해석을 위한 비정렬격자계에 적합한 경계면포착법 연구)

  • Myong, H.K.;Kim, J.E.
    • Journal of computational fluids engineering
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    • v.11 no.4 s.35
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    • pp.14-19
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    • 2006
  • A conservative finite-volume method for computing 3-D flow with an unstructured cell-centered method has been extended to free surface flows or two-fluid systems with topologically complex interfaces. It is accomplished by implementing the high resolution method(CICSAM) by Ubbink(1997) for the accurate capturing of fluid interfaces on unstructured meshes, which is based on the finite-volume technique and is fully conservative. The calculated results with the present method are compared to show the ease and accuracy with available numerical and experimental results reported in the literature.

Molecular-scale Structure of Pentacene at Functionalized Electronic Interfaces

  • Seo, Soon-Joo;Peng, Guowen;Mavrikakis, Manos;Ruther, Rose;Hamers, Robert J.;Evans, Paul G.;Kang, Hee-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.299-299
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    • 2011
  • A dipolar interlayer can cause dramatic changes in the device characteristics of organic field-effect transistors (OFETs) or photovoltaics. A shift in the threshold voltage, for example, has been observed in an OFET where the organic semiconductor active layer is deposited on SiO2 modified with a dipolar monolayer. Dipolar molecules can similarly be used to change the current-voltage characteristics of organic-inorganic heterojunctions. We have conducted a series of experiments in which different molecular linkages are placed between a pentacene thin film and a silicon substrate. Interface modifications with different linkages allow us to predict and examine the nature of tunneling through pentacene on modified Si surfaces with different dipole moment. The molecular-scale structure and the tunneling properties of pentacene thin films on modified Si (001) with nitrobenzene and styrene were examined using scanning tunneling spectroscopy. Electronic interfaces using organic surface dipoles can be used to control the band lineups of a semiconductor at organic/inorganic interfaces. Our results can provide insights into the charge transport characteristics of organic thin films at electronic interfaces.

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Experimental Study on Shear Mechanism Caused by Textured Geomembrane (돌기형 지오멤브레인에 의한 전단 메카니즘에 관한 실험 연구)

  • 이석원
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.11c
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    • pp.57-68
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    • 1999
  • This paper summarizes the results of a study which uses the recently developed Optical Profile Microscopy technique (Dove and Frost, 1996) as the basis for investigating the role of geomembrane surface roughness on the shear mechanism of geomembrane/geotextile interfaces. The alternative roughness parameters which consider the direction of shearing are described. These directional parameters are compared with the existing roughness parameters, and the relationship between these directional and non-directional parameters are investigated. Then, the relationship between interface shear strength and surface roughness quantified at the interface is investigated. The results show that interface friction can be quantitatively related to the surface roughness of the geomembrane. The peak and residual interface strengths increase dramatically through the use of textured geomembranes as opposed to smooth geomembranes. For the smooth geomembranes, the sliding of the geotextile is the main shear mechanism. For the textured geomembranes, the peak interface strength is mainly mobilized through the micro-texture of the geomembrane, however, the residual interface strength is primarily attributed to macro scale surface roughness which pulls out and breaks the filaments from the geotextile. The results of this study can be extended to the other interfaces such as joints in rock mass, and also can be used to provide a quantitative framework that can lead to a significantly improved basis for the selection and design of geotextiles and geomembranes in direct contact.

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MOMENT-OF-FLUID METHOD FOR FREE SURFACE FLOW SIMULATION USING UNSTRUCTURED MESHES (비정렬 격자상에서 Moment-of-Fluid 방법을 이용한 자유표면유동계산)

  • Ahn, H.T.
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.65-67
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    • 2011
  • The moment-of-fluid (MOF) method is a new volume-tracking method that accurately treats evolving material interfaces. The MOF method uses moment data, namely the material volume fraction, as well as the centroid, for a more accurate representation of the material configuration, interfaces and concomitant volume advection. In this paper, unstructured mesh extension of the MOF method is to be presented. The MOF method is coupled with a stabilized finite element incompressible Navier-Stokes solver for two materials. The effectiveness of the MOF method is demonstrated with a free-surface dam-break problem.

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Photoeffects at p-GaP Semiconductor Interfaces (p형 GaP 반도체 계면의 광효과)

  • Chun, Jang-Ho
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.10
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    • pp.1528-1534
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    • 1989
  • Photoeffects at the p-GaP semiconductor/CsNO3 electrolyte interface were investigated in terms of their current-voltage characteristics. The photoeffects at the semiconductor-electrolyte interfaces and their photocurrent variations are verified using Ar ion laser and continuous cyclic voltammetric methods. The mechanism of charge transfer at the photogeneration in the depletion layer rather than the photodecomposition of the p-GaP semiconductor electrode surface and/or the water photoelectrolysis. The adsorption of Cs+ ions at the interface is physical adsorption.

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Studies on the Evolution of the Surface Roughness with Development of Surface Compound Layer in Salt Bath Nitrocarburising (Tufftride) (침질침탄시 화합물층의 성장에 따른 표면조도 변화에 관한 연구)

  • Song, K.S.;Moon, K.I.;Kim, S.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.5
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    • pp.253-259
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    • 2003
  • In this study, to find out the reason of deterioration in surface roughness of steel and cast iron after Tufftride, it has been investigated on the relation between the surface roughness and various factors such as the evolution of compound layer, surface morphology, and surface hardness, and change of pore ratio in the compound layer during Tufftride at $580^{\circ}C$. It is found that the surface roughness was increased with the evolution of compound layer during Tufftride of steel and cast iron. The change of surface roughness after Tufftride was reduced with decreasing tho content of carbon and cementite ($Fe_3C$) in the materials. in the cast irons, the various shaped graphites that was exposed to the surface should induce the discontinuous growth of the compound layer, and this resulted in the incoherent interfaces between matrix and compound layer and the deterioration of surface roughness. In the steels, the existence of cementites in the matrix resulted in the incoherent interfaces between matrix and compound layer. It is considered that during Tufftride the surface roughness must be mainly influenced by the formation of the incoherent interface between compound layer and matrix that is affected by some factors such as the microstructure, the composition, and the hardness of the matrix.

SURFACE ROUGHNESS AND MICROLEAKAGE OF CLASS V COMPOSITE RESTORATIONS : EFFECT OF SURFACE SEALING (치경부 5급 와동 수복물의 표면 거칠기와 미세누출에 관한 연구 : 표면 전색의 효과)

  • Kim, Min-Jeong;Lee, Mi-Jeong;Yu, Mi-Kyung;Park, Soo-Joung;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.30 no.1
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    • pp.22-30
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    • 2005
  • The purpose of this study was to compare the effect of surface sealing materials on microleakage and surface roughness in Class V composite restorations. Twenty five standardized Class V cavity preparations were made on the facial surface of human premolars and were randomly assigned to 5 groups. The teeth were restored with Z-250 after applying Single Bond. Following 7 days storage in distilled water at $37^{\circ}C$, the restorations were sealed as following systems : No sealing ; Single Bond Adhesive ; Biscover ; Fortify ; Optiguard. Then, toothbrush abrasion test was conducted using a wear testing machine. Surface roughness was measured by means of profilometer before and after toothbrushing and the results were statistically analysed by using a paired t-test and ANOVA. The bonded interfaces and the changes of surface roughness were examined by SEM. For microleakage test, specimens were stained in a $2\%$ methylene blue solution, then longitudinally sectioned and analyzed for leakage at occlusal and cervical interfaces using stereomicroscope. The results were statistically analysed by using a Kruskal-Wallis and Mann-Whitney U test. Surface roughness was increasing in all groups after toothbrushing, but no statistically significant differences. In SEM observation, surface sealant was partially retained and partially detached in bonded interfaces. Especially, microgap was identified in cervical margins. In microleakage test, there was better seal in the enamel region and a significant difference between groups at occlusal margin. Control group and Single Bond group had significantly better marginal seal at enamel margin than cervical margin.