• 제목/요약/키워드: Surface Impedance

검색결과 750건 처리시간 0.034초

유한배플의 영향을 고려한 정방형 진동면의 방사임피던스계산 (Calculation of Radiation Impedance for Rectangular Piston Vibrators with Finite Baffle)

  • 김무준;김천덕;하강열
    • 한국음향학회지
    • /
    • 제19권7호
    • /
    • pp.3-6
    • /
    • 2000
  • 일반적으로 보고되어있는 방사임피던스는 무한강체 배플에 진동면을 두고있는 경우에 대하여 계산되어져 있어, 실제 유한한 크기의 배플을 갖는 트랜스듀서의 설계에는 적용하기 어려운 경우가 많다. 본 연구에서는 피스톤의 진동면을 작은 점음원의 모임으로 가정하고, 각 점음원의 음원강도와 배플의 크기를 관련지어 유한배플을 갖는 진동면에 대한 방사임피던스의 새로운 계산법을 제안하였다. 그에 대한 예로서 정방형의 피스톤 진동면에 대하여 배플의 크기에 따른 자기방사임피던스의 변화를 계산함으로써 제안한 방법의 유효성을 확인하였다.

  • PDF

Electrochemical Impedance Characteristics of Anodic Oxide Layer Formed on Titanium Binary Alloy Surface

  • Lee, Kang;Choe, Han-Choel;Ko, Yeong-Mu
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2008년도 추계학술대회 초록집
    • /
    • pp.30-30
    • /
    • 2008
  • In this study, electrochemical impedance characteristics of anodic oxide layer formed on titanium binary alloy surface have been investigated. Titanium oxide layers were grown on Ti-$_XTa$ and Ti-$_XNb$(X=10, 20, 30 and 40 wt%) alloy substrates using phosphoric acid electrolytes.

  • PDF

조밀한 표면조직을 갖는 탄소재료의 Impedance Spectroscopy를 통한 전기화학적 거동의 해석 (A Study on the Electrochemical Behavior of Carbon Material with Compact Surface Using Impedance Spectroscopy)

  • 오한준;이종호;이영훈;고영신
    • 대한화학회지
    • /
    • 제40권5호
    • /
    • pp.308-316
    • /
    • 1996
  • Impedance Spectroscopy를 통하여 조밀한 표면조직을 갖는 glassy carbon과 PVDF 합성흑연의 표면에 대한 전기화학적 거동을 조사하였다. 이들 두 탄소재료는 모두 전압에 대한 높은 Faraday-임피던스의존성이 나타났으며, 이를 평가하기 위한 등가회로는 PVDF 흑연의 경우 lassy carbon의 등가회로에 소수성 결합제에 의한 저항과 축전용량이 추가된 형태로 나타났다. 또한 디들 재료는 표면의 차이로 인한 전기화학적 거동의 차이도 나타났다.

  • PDF

Electrochemical Impedance Study for Selective Dissolution of a Cu-Zn Alloy

  • Hoshi, Y.;Tabei, K.;Shitanda, I.;Itagaki, M.
    • Corrosion Science and Technology
    • /
    • 제15권6호
    • /
    • pp.311-313
    • /
    • 2016
  • The anodic dissolution behavior of copper and brass in an electrolyte solution of 0.5M NaCl containing 0.5 mM $NaHCO_3$ was investigated by electrochemical impedance spectroscopy. The Nyquist plots of the copper impedance described a small loop in the high-frequency range and a large locus in the low-frequency range. Additionally, the features of the impedance spectrum of the brass were similar to those of the copper. This indicates that the copper-enriched layer formed on the brass surface due to the selective dissolution of the zinc from the surface. In addition, the rest potential and the anodic polarization curve for each sample were measured in order to discuss the selective dissolution of the zinc from the brass surface.

Impedance Characteristics of Oxide Layers on Aluminium

  • 오한준;장경욱;치충수
    • Bulletin of the Korean Chemical Society
    • /
    • 제20권11호
    • /
    • pp.1340-1344
    • /
    • 1999
  • The electrochemical behavior of oxide layers on aluminium was studied using electrochemical impedance spectroscopy. Impedance spectra were taken at a compact and a porous oxide layer of Al. The anodic films on Al have a variable stoichiometry with gradual reduction of oxygen deficiency towards the oxide-electrolyte interface. Thus, the interpretation of impedance spectra for oxide layers is complicated, with the impedance of surface layers differing from those of ideal capacitors. This layer behavior with conductance gradients was caused by an inhomogeneous dielectric. The frequency response cannot be described by a single RC element. The oxide layers of Al are properly described by the Young model of dielectric constant with a vertical decay of conductivity.

$CF_4$ 플라즈마 처리된 ITO박막을 이용한 유기 EL 소자의 성능향상에 관한 임피던스 분석 (Impedance spectroscopy analysis of organic light emitting diodes with the $CF_4$ anode plasma treatment)

  • 박형준;김현민;이준신;손선영;정동근
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
    • /
    • pp.320-321
    • /
    • 2006
  • In this work, impedance Spectroscopic analysis was applied to study the effect of plasma treatment on the surface of indium-tin oxide (ITO) anodes using $CF_4g$ as and to model the equivalent circuit for organic light emitting diodes (OLEDs) with the $CF_4$ plasma treatment of ITO surface at the anodes. This device with ITO/TPD/$Alq_3$/LiF/Al structure can be modeled as a simple combination of a resistor and a capacitor. The $CF_4$ plasma treatment on the surface of ITO shifts the vacuum level of the ITO as a result of which the barrier height for hole injection at the ITO/organic interface is reduced. The Impedance spectroscopy measurement of the devices with the $CF_4$ plasma treatment on the surface of ITO anodes shows change of values in parallel resistance ($R_p$) and parallel capacitance ($C_p$).

  • PDF

저압 산소 플라즈마 처리된 ITO박막을 이용한 유기 EL 소자의 성능 향상에 관한 임피던스 분석 (Impedance spectroscopy analysis of organic light emitting diodes with the $O_2$ anode plasma treatment)

  • 김현민;박형준;이준신;오세명;정동근
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
    • /
    • pp.436-437
    • /
    • 2006
  • In this work, impedance Spectroscopic analysis was applied to study the effect of plasma treatment on the surface of indum-tin oxide (ITO) anodes using $O_2$ gas and to model the equivalent circuit for organic light emitting diodes (OLEDs) with the $O_2$ plasma treatment of ITO surface at the anodes. This device with ITO/TPD/Alq3/LiF/Al structure can be modeled as a simple combination of a resistor and a capacitor. The $O_2$ plasma treatment on the surface of ITO shifts the vacuum level of the ITO as a result of which the barrier height for hole injection at the ITO/organic interface is reduced. The impedance spectroscopy measurement of the devices with the $O_2$ plasma treatment on the surface of ITO anodes shows change of values in parallel resistance ($R_p$) and parallel capacitance ($C_p$).

  • PDF

Porous Electrodes with Lower Impedance for Vanadium Redox Flow Batteries

  • Park, Su Mi;Kim, Haekyoung
    • Korean Chemical Engineering Research
    • /
    • 제53권5호
    • /
    • pp.638-645
    • /
    • 2015
  • Vanadium redox flow batteries (VRFBs) have been investigated for their potential utility as large energy storage systems due to their advantageous performances in terms of long cycle life, high energy efficiency, low cost, and flexible design. Carbon materials are typically used as electrodes in redox reactions and as a liquid electrolyte support. The activities, surface areas, and surface morphologies of porous carbon materials must be optimized to increase the redox flow battery performance. Here, to reduce the resistance in VRFBs, surface-modified carbon felt electrodes were fabricated, and their structural, morphological, and chemical properties were characterized. The surface-modified carbon felt electrode improved the cycling energy efficiencies in the VRFBs, from 65% to 73%, due to the improved wettability with electrolyte. From the results of impedances analysis with proposed fitting model, the electrolyte-coupled polarization in VRFB dramatically decreased upon modification of carbon felt electrode surface. It is also demonstrated that the compressibility of carbon felt electrodes was important to the VRFB polarization, which are concerned with mass transfer polarization. The impedance analysis will be helpful for obtaining better and longer-lived VRFB performances.

수정진동자의 임피던스 해석에 의한 LB막의 전기적 특성 (Electric Properties of LB Films using Impedance Analysis of Quartz Crystal)

  • 진철남;김경환;유승엽;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제48권7호
    • /
    • pp.503-507
    • /
    • 1999
  • Quartz crystal in contact with viscoelastic medium was described directly in terms of the electrical equivalent circuit of the system. Stearic acid was used as viscoelastic medium and deposited on the surface of quartz crystal using the Langmuir-Blodgett(LB) method. Impedance properties of quartz crystal coated with LB films which were investigated by using admittance diagram and $Ζ-\theta$ plot a method of impedance analysis. When stearic acid LB film was deposited on the surface of quartz crystal, resonant frequency of quartz crystal was changed about 100 Hz/layer. This result illustrates the ability of the sensor system to detect small amounts of special gas in air.

  • PDF

와전류법을 이용한 강의 표면경화층 깊이의 비파괴적 측정 (Nondestructive Measurement of Case Hardening Depth with Eddy Current Method)

  • 이계완;한승룡;박은수
    • 비파괴검사학회지
    • /
    • 제11권1호
    • /
    • pp.38-43
    • /
    • 1991
  • The relationship between eddy current response and case hardening depth has been studied on SM40C(KS D-3752) and SCM440(KS D-3711) steels which were surface hardened by high frequency induction hardening. The results obtained in this study were as follows ; 1) Case hardening depth was successfully measured by observing the eddy current impedance changes of each steel. The impedance decreased linearly with increasing case hardening depth. 2) For large impedance gradient between the hardened surface and core metal, the eddy current response was more sensitive to case hardening depth than for low impedance gradient.

  • PDF