• Title/Summary/Keyword: Surface Equation of State

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A New Model and Equation Derived From Surface Tension and Cohesive Energy Density of Coagulation Bath Solvents for Effective Precipitation Polymerization of Acrylonitrile

  • Zhou, You;Xue, Liwei;Yi, Kai;Zhang, Li;Ryu, Seung Kon;Jin, Ri Guang
    • Carbon letters
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    • v.13 no.3
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    • pp.182-186
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    • 2012
  • A new model and resultant equation for the coagulation of acrylonitrile monomers in precipitation polymerization are suggested in consideration of the surface tension (${\gamma}$) and cohesive energy density ($E_{CED}$). The equation was proven to be quite favorable by considering figure fittings from known surface tensions and cohesive energy densities of certain organic solvents. The relationship between scale value of surface tension (${\gamma}$/M) and cohesive energy density of monomers can be obtained by changing the coagulation bath component for effective precipitation polymerization of acrylonitrile in wet spinning.

Determination of active failure surface geometry for cohesionless backfills

  • Altunbas, Adlen;Soltanbeigi, Behzad;Cinicioglu, Ozer
    • Geomechanics and Engineering
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    • v.12 no.6
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    • pp.983-1001
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    • 2017
  • The extent by which economy and safety concerns can be addressed in earth retaining structure design depends on the accuracy of the assumed failure surface. Accordingly, this study attempts to investigate and quantify mechanical backfill properties that control failure surface geometry of cohesionless backfills at the active state for translational mode of wall movements. For this purpose, a small scale 1 g physical model study was conducted. The experimental setup simulated the conditions of a backfill behind a laterally translating vertical retaining wall in plane strain conditions. To monitor the influence of dilative behavior on failure surface geometry, model tests were conducted on backfills with different densities corresponding to different dilation angles. Failure surface geometries were identified using particle image velocimetry (PIV) method. Friction and dilation angles of the backfill are calculated as functions of failure stress state and relative density of the backfill using a well-known empirical equation, making it possible to quantify the influence of dilation angle on failure surface geometry. As a result, an empirical equation is proposed to predict active failure surface geometry for cohesionless backfills based on peak dilatancy angle. It is shown that the failure surface geometries calculated using the proposed equation are in good agreement with the identified failure surfaces.

Effects of Surface Radiation on the Unsteady Natural Convection in a Rectangular Enclosure

  • Baek, Seung-Wook;Kim, Taig-Young
    • International Journal of Aeronautical and Space Sciences
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    • v.3 no.1
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    • pp.95-104
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    • 2002
  • Numerical solution of the full Navier-Stokes equation as well as the energy equation has been obtained for the unsteady natural convection in a rectangular enclosure. One side wall was maintained at very high temperature simulating fires. Especially the effect of surface radiation was taken into account. While the enclosed air was assumed to be transparent, the internal walls directly interacted one another through the surface radiation. Due to a significant temperature difference in the flow field, the equation of state was used instead of the Boussinesq approximation. It was found that the rapid heating of the adiabatic ceiling and floor by the incoming radiation from the hot wall made the evolution at thermo-fluid field highly unstable in the initial period. Therefore, the secondary cells brought about at the floor region greatly affected the heat transfer mechanism inside the enclosure. The heat transfer rate was augmented by the radiation, resulting in requiring less time for the flow to reach the steady state. At the steady state neglecting radiation two internal hydraulic jumps were clearly observed in upper/left as well as in lower/right comer. However, the hydraulic jump in the lower/right comer could not be observed for the case including radiation due to its high momentum flow over the bottom wall. Radiation resulted in a faster establishment of the steady state phenomena.

Steady State Analysis of Magnetic Head Slider at Ultra Low Clearance (마그네틱 헤드 슬라이더의 極小 空氣膜에 대한 定常狀態 解析)

  • 장인배;한동철
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.4
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    • pp.764-770
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    • 1989
  • This paper analyze the steady state performance of a self-acting air lubricated slider bearing in hard disk/head system. Modified Reynolds' equation is derived from the steady state compressible Navier-Stokes equation, under slip-flow conditions. Finite difference technique and numerical procedure are described by using Newton-Raphson iteration method to slove the non-linear equations. These techniques are applied to conventional slider bearings and the effects of molecular mean free path(MMFP) for a recording surface of hard disk are shown. The calculation procedure developed here, wide applicabilities in practical head design procedures, and converges rapidly.

Symmetric Conformal Mapping for Surface Matching and Registration

  • Zeng, Wei;Hua, Jing;Gu, Xianfeng David
    • International Journal of CAD/CAM
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    • v.9 no.1
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    • pp.103-109
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    • 2010
  • Recently, various conformal geometric methods have been presented for non-rigid surface matching and registration. This work proposes to improve the robustness of conformal geometric methods to the boundaries by incorporating the symmetric information of the input surface. We presented two symmetric conformal mapping methods, which are based on solving Riemann-Cauchy equation and curvature flow respectively. Experimental results on geometric data acquired from real life demonstrate that the symmetric conformal mapping is insensitive to the boundary occlusions. The method outperforms all the others in terms of robustness. The method has the potential to be generalized to high genus surfaces using hyperbolic curvature flow.

Surface Saturation Area-Subsurface Outflow-Soil Moisture Storage Relationships: I. Steady-State Analysis (지표포화지역-중간류유출-흙수분저류량 관계: I. 정상류 분석)

  • 이도훈;이은태
    • Water for future
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    • v.28 no.5
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    • pp.129-140
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    • 1995
  • In this study we derived steady-state relationships between surface saturation area and subsurface outflow, and between surface saturation area and soil moisture storage through numerical experiments with Richards equation on a hillslope. Numerical experiments analyzed the sensitivity of topographic and soil hydraulic properties on steady-state relationships between surface saturation area and subsurface outflow. And the power law for the extent of surface saturation area was determined as a function of subsurface outflow or soil moisture storage.

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The Resonance Characteristic Analysis for Speed Control of Parallel Connected Dual SPMSMs fed by a Single Inverter (단일 인버터로 두 대의 영구자석 동기전동기 병렬운전에 대한 공진특성해석)

  • Yun, Chul;Kwon, Woo-Hyen
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.4
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    • pp.643-650
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    • 2017
  • This pap4er analyzes resonance characteristics of a slave motor that is not controlled by load and parameter differences between Dual motors during parallel operation in middle-low speed. Dual SPMSMs(Surface mounted Permanent Magnet Synchronous Motor) connected in parallel to a single inverter controlled by the master and slave control in this paper. Based on the stability analysis of the SPMSM for a variation of torque angle, the 6th nonlinear state equation of the torque angle variation in the SIMM(Single Inverter Multi Motor) structure is derived according to a mathematical model for the dual motors. In general, an analysis of the 6th order nonlinear state equation is complex. Therefore, a resonance frequency generated from the slave motor is found from the characteristic equation of the 2nd order system obtained by linearization and model reduction near steady state operation point. Through simulations and experiments, it is confirmed that the stability analysis of the SPMSMs and state equation models are useful for the variation of the torque angle analyzed in this paper.

Aiming at "All Soils All States All Round Geo-Analysis Integration"

  • Asaoka, Akira;Noda, Toshihiro
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.3-26
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    • 2009
  • Superloading yield surface concept is newly introduced together with subloading yield surface conception in order to describe full gradation continuously of the mechanical behavior of soils from typical sand through intermediate soil to typical clay (All Soils). Finite deformation theory has been applied to the soil skeleton-pore water coupled continuum mechanics, which enables us to discuss things in a perpetual stream from stable state to unstable state like from deformation to failure and vice versa like from liquefaction to post liquefaction consolidation of sand (All States). Incremental form of the equation of motion has been employed in the continuum mechanics in order to incorporate a rate type constitutive equation, which is "All Round" enough to predict ground behavior under both static and dynamic conditions. The present paper is the shortened version of the lecture note delivered in 2008 Theoretical and Applied Mechanics Conference, Science Council Japan, but with newly developed application examples.

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Isotherm for $Ni-O_2$ Adsorption System

  • Kyoung-Hee Ham;Woon-Sun Ahn
    • Bulletin of the Korean Chemical Society
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    • v.11 no.3
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    • pp.231-235
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    • 1990
  • The activation energy of dissociative adsorption of oxygen on polycrystalline nickel surface is calculated from adsorption isotherms obtained using X-ray photoelectron spectroscopy. Negative value of this activation energy (-5.9 kJ/mol) indicates that the adsorption takes place through an undissociated precursor state. An adsorption energy for this precursor state is calculated assuming the precursor state as a moleculary physisorbed state ($E_{ad}$ = -7.9 kJ/mol). Finally, an adsorption isotherm equation is derived as a function of the gas exposure, which agrees with the experimental isotherms reasonably good.

Treatment of Melamine by GAC Adsorption According to Adsorbent Size: Kinetics and Dispersion-Diffusion (흡착제 크기에 따른 GAC의 멜라민 흡착 처리 : 반응속도와 분산-확산)

  • Lee, Jai-Yeop;Lee, Sangjung;Han, Ihnsup
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.65-72
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    • 2013
  • Adsorption of melamine was examined using columns packed with granular activated carbon (GAC). Raw GAC was sieved with 20, 40, 60 and 80 mesh to determine the influence of adsorbent particle size on reaction and diffusion. The mass ratio of the adsorption capacity of GAC for melamine ranged from 9.19 to 11.06%, and adsorption rates increased with decreasing particle size within this range. Rate constants between 3.295 ~ 4.799 $min^{-1}$ were obtained using a pseudofirst-order equation that was used to determine adsorption kinetics. A surface diffusion model was adapted to take into account the unsteady-state equation of a spherical adsorbent by converting the surface concentration from a constant to a variable governed by a dispersion equation. The calculated values were fit with the experimental results by using the diffusion coefficients as regression parameters. The modified equation exhibited a more precise agreement with respect to the sum of the absolute error (SAE).