• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.7
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• pp.598-606
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• 2000

In this paper we investigated the relation between the surface degradations and anti-pollution characteristics of Room Temperature Vulcanized(RTV) silicone rubber coating that has different roughness through immersing into saline water. We utilized several analytic techniques such as atomic force microscopy(AFM) scaning electron microscopy(SEM) contact angle Salt Deposit Density(SDD) and average leakage current under the condition of salt fog. It is found that the surface roughness of treated RTV silicone rubber increased and the hydrophobicity of sample surface decreased with increasing the duration o immersion into water due to the erosion of base polymer the melting down alumina trihydrate(ATH) and the diffusion of Low Molecular weight(LMW) fluid. Despite the roughness of surface had been increased by water immersion excellant anti-pollution and recovery characteristics were maintained and SDD saturated to 0.1~0.14mg/cm$^2$. The average leakage current under salt fog increased with surface roughness. Measurement of average leakage current will be helpful to investigate surface degradation and lifetime expectation of RTV silicone coating.

• Transactions of Materials Processing
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• v.31 no.1
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• pp.11-16
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• 2022

In this paper, wear characteristics of PVD coatings were compared on the die surface for cold stamping of MART1470 steel sheet with the finite element analysis and the pin-on-disc wear test. Three types of PVD coatings (CrN, TiAlCrN, and MoS2TiCr(W)N) were considered for the tool surface made of STD11 material. The stamping process of an auto-body part was analyzed with the finite element method. Ranges of process variables for the wear test such as contact pressure, relative speed, and sliding distance were predicted from analysis results. In order to quantitatively analyze wear characteristics of each coating, the amount of wear was measured and compared according to process variables with the pin-on-disc wear test. The influence of each process variable was investigated and the wear characteristics of the three coating layers were quantitatively compared. It was confirmed that the wear characteristics of MoS₂TiCr(W)N coating were better than those of CrN and TiAlCrN. It was noted that the proposed prediction approach could predict and respond to the wear phenomenon occurring in the stamping process.

• Journal of the Korean Vacuum Society
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• v.12 no.S1
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• pp.21-27
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• 2003

Micro-arc discharge oxidation (MDO) is a cost-effective plasma electrolytic process which can be used to improve the wear and corrosion resistance of Al-alloy parts by forming a alumina coating on the component surface. However, the MDO coated Al-alloy components often exhibit relatively high friction coefficients and low wear resistance fitted with many counterface materials, additionally, the pitting corrosion for the MDO coated AI-alloy components, especially for a thinner alumina coating, often occurs in atmosphere circumstance due to the porous alumina coats. Therefore, a duplex treatment, combining a MDO coated ahumina thin layer with a TiN coating, prepared by magnetron sputtering (MS), has been investigated. The Vicker's microhardness, pin-on-disc, electrochemical measurement, salt spray, XRD and SEM tests were used to characterize and analyze the treated samples. The work demonstrates that the MDO/MS coated samples have a combination of a very low friction coefficient and good wear resistance as well as corrosion since the micro-holes on alumina coating are partly or fully covered by TiN material.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.218-218
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• 2013

We report a simple and cost-effective method to fabricate transparent superhydrophobic surface on various substrates. The surface was fabricated by coating hydrophobic PDMS (polydimethylsiloxane) film on the silica nanoparticle and subsequent fixing of the hydrophobic silica nanoparticles onto substrates. The water contact angle for the prepared surface was determined to be over $150^{\circ}$, whichindicates that the surface is highly repellent to water. The hierarchical structure and roughness of the surface were examined by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Additionally, transparency of the prepared surface was measured with UV-VIS spectrometer. The transmittance of the superhydrophobic surface was ~80%, which is lower than that without PDMS-coated silica by only 5 to 10%. It is also notable that the superhydrophobic surface fully recovers its original transmittance after self-cleaning process. Also the PDMS coating is stable under a wide range of pH conditions, UV radiation and salinity conditions, which is essential for the practical use. Moreover, our fabrication method is applicable in large scale production.

• Journal of the Korean institute of surface engineering
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• v.43 no.2
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• pp.97-104
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• 2010

In this paper, we conducted MATLAB simulation using the reflectance formula and the Planck's black body radiation principle, for the purpose of identifying the opimum material and thickness of anti-reflective coating from double layered structures. We found that the optimum condition was obtained when refractive index of upper layer is 1.44 and that of lower layer is 2.29. As materials close to these refractive indices, $MgF_2$ as the upper layer and $HfO_2$, ZnS, $TiO_2$ as the lower layer were suggested. The best result in an average reflectance of 2.759% was obtained from a double layered structure of $MgF_2$ 94 nm/ZnS 55 nm.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.66 no.6
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• pp.962-967
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• 2017

The Diamond-Like-Carbon (DLC) coating is a new carbon-based amorphous material. Carbon ions in the plasma are electrically accelerated and collide with the substrate to form a thin film. This film has similar properties to diamonds such as high surface hardness, low coefficient of friction, corrosion resistance and durability that do not react with acids and bases. Also, since there is no thermal deformation, it can be printed at room temperature. and coated on almost all materials such as paper, polymer, ceramics and various metals even aspheric lens it is possible to mirror surface coating with excellent surface roughness. In this paper, we have analyzed the DLC film formed by Filtered Arc Ion Plating (Filtered AIP) process.

• Bulletin of the Korean Chemical Society
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• v.31 no.8
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• pp.2304-2308
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• 2010

A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

• Design & Manufacturing
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• v.13 no.4
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• pp.1-9
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• 2019

In-mold Coating is a method that can simultaneously perform injection molding and surface coating in injection mold. The material used for coating is two-component polyurethane which is composed of polyol and isocyanate. L-type mixing head can be used to mix polyol and isocyanate uniformly, and inject them inside the mold cavity. The surface quality of the injection molded products by using in-mold coating depends on the mixing uniformity between main agent and hardener. In this study, flow analysis was performed to design a mixing head for uniform mixing of two-component polyurethane. Especially the effects of design parameters of mixing head on mixing uniformity and nozzle pressure were investigated. The parameters of mixing head were mixing chamber diameter, cleaning cylinder diameter, nozzle alignment angle in the horizontal and vertical direction, and cleaning piston position. It was found that optimal design values were mixing chamber diameter of 3.5 mm, cleaning cylinder diameter of 5.0 mm, nozzle horizontal/vertical alignment angles of 140°/160°, and cleaning piston position of 1.8 mm. The optimal values would be used to develop a two-component mixing head achieving an uniform mixing for in-mold coating.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3233-3237
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• 2010

A $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ cathode was modified by coating with Li-La-Ti-O, and the effect of the coating thickness on their electrochemical properties was studied. The thickness of the coating on the surface of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ was increased by increasing the wt % of the coating material. The rate capability of the Li-La-Ti-O-coated electrode was superior to that of the pristine sample. 1- and 2-wt %-coated samples showed considerable improvement in capacity retention at high C rates. However, the rate capability of a 5-wt %-coated sample decreased. All the coated samples showed a high discharge capacity and slightly improved cyclic performance under a high cut-off voltage (4.8 V) condition. Results of a storage test confirmed that the Li-La-Ti-O coating layer was effective in suppressing the dissolution of the transition metals as it offered protection from the attack of the acidic electrolyte. In particular, the 2- and 5-wt %-coated samples showed a better protection effect than the 1-wt %-coated sample.

• Journal of the Korean Electrochemical Society
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• v.13 no.4
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• pp.246-250
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• 2010

In this study, nano-crystallized $Al_2O_3$ was coated on the surface of $LiFePO_4$ powders via a novel dry coating method. The influence of coated $LiFePO_4$ upon electrochemical behavior was discussed. Surface morphology characterization was achieved by transmission electron microscopy (TEM), clearly showing nano-crystallized $Al_2O_3$ on $LiFePO_4$ surfaces. Furthermore, it revealed that the $Al_2O_3$-coated $LiFePO_4$ cathode exhibited a distinct surface morphology. It was also found that the $Al_2O_3$ coating reduces capacity fading especially at high charge/discharge rates. Results from the cyclic voltammogram measurements (2.5-4.2 V) showed a significant decrease in both interfacial resistance and cathode polarization. This behavior implies that $Al_2O_3$ can prevent structural change of $LiFePO_4$ or reaction with the electrolyte on cycling. In addition, the $Al_2O_3$ coated $LiFePO_4$ compound showed highly improved area-specific impedance (ASI), an important measure of battery performance. From the correlation between these characteristics of bare and coated $LiFePO_4$, the role of $Al_2O_3$ coating played on the electrochemical performance of $LiFePO_4$ was probed.