• Title/Summary/Keyword: Surface Atmosphere

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The Effects of the Annealing Temperature and Environments on Room Temperature Wear Behavior of Plasma-Sprayed Partially Stabilized Zirconia Coatings (플라즈마 용사된 부분안정화 지르코니아 코팅의 상온 마모거동에 미치는 열처리온도 및 분위기의 영향)

  • 김장엽;임대순
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1176-1180
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    • 1994
  • The sliding wear behavior of the plasma-sprayed zirconia containing 3 mol% yttria was investigated after the annealing at room temperature to 80$0^{\circ}C$ in various concentrations of humid atmosphere as laboratory, humid, dry argon atmosphere. Both of the friction coefficient and the wear loss increased with increasing temperature up to 80$0^{\circ}C$. Surface morphology of the worn samples changed with annealing temperature. The change of monoclinic/tetragonal (m/t) x-ray peak intensity ratio effected the wear behavior. The m/t ratio had maximum value at 20$0^{\circ}C$ and decreased with increased temperature in laboratory and humid atmosphere. In argon atmosphere the m/t ratio had no maximum value and decreased with increasing temperature. At all the annealing temperature humid atmosphere had more the m/t ratio value than any other atmosphere. The change of toughness was showed the inversed result of m/t ratio change. The results indicated that the resudial stress which was induced by the different amount of phase transformation takes a detrimental role in wear behavior.

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Quantifying Climate Regulation of Terrestrial Ecosystems Using a Land-Atmosphere Interaction Model Over East Asia for the Last Half Century

  • Hong, Seungbum;Jang, Inyoung;Jeong, Heon-Mo
    • Proceedings of the National Institute of Ecology of the Republic of Korea
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    • v.1 no.1
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    • pp.58-67
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    • 2020
  • Terrestrial ecosystems influence climate change via their climate regulation function, which is manifested within the carbon, water, and energy circulation between the atmosphere and surface. However, it has been challenging to quantify the climate regulation of terrestrial ecosystems and identify its regional distribution, which provides useful information for establishing regional climate-mitigation plans as well as facilitates better understanding of the interactions between the climate and land processes. In this study, a land surface model (LSM) that represents the land-atmosphere interactions and plant phenological variations was introduced to assess the contributions of terrestrial ecosystems to atmospheric warming or cooling effects over East Asia over the last half century. Three main climate-regulating components were simulated: net radiation flux, carbon exchange, and moisture flux at the surface. Then, the contribution of each component to the atmospheric warming or cooling (negative or positive feedback to the atmosphere, respectively) was investigated. The results showed that the terrestrial ecosystem over the Siberian region has shown a relatively large increase in positive feedback due to the enhancement of biogeochemical processes, indicating an offset effect to delay global warming. Meanwhile, the Gobi Desert shows different regional variations: increase in positive feedback in its southern part but increase in negative one in its eastern part, which implies the eastward movements of desert areas. As such, even though the LSM has limitations, this model approach to quantify the climate regulation is useful to extract the relevant characteristics in its spatio-temporal variations.

Wetting Phenomena between Sealing Glass and Free Cutting Steel (접합유리와 쾌삭강간의 Wetting 현상)

  • Kim, Heung;Kim, Chong-Hee
    • Journal of the Korean Ceramic Society
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    • v.19 no.1
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    • pp.24-34
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    • 1982
  • The effect of the several variables on wetting of AISIB1113 steel by molten glass was studied by Sessible-drop method. Experimental variables were temperature, firing atmospheres, Fe2O3 addition to the sealing glass and steel surface conditions. The degree of wetting in terms of contact angles between molten glass and metal tested at different test conditions was analyzed by using Young's equation. The results showed that contact angles in H2 atmosphere in the glass metal systems were high but in N2 atmosphere, were small for studied glass metal systems. Especially, when the glass drop was in contact with oxidized steel in N2 atmosphere, The best adherence with contact angle of approximately 9°was obtained. In the case of Fe2O3 addition in glass contact angles subtantially increased due to the increase of surface tension of glass. Wetting phenomena were also discussed under the basis of these experimental results.

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The Variation of Radiocarbon-14 Content in the Atmosphere

  • Kyung Rin Yang
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.370-377
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    • 1971
  • The Carbon-14 content in surface air at Seoul, Korea, was measured from February 1970 to August 1971 and a Larix Leptolepis, Gordon tree (Ip-Gal Namu) grown at Kwang-Nung, Kyunggi-Do, Korea, having 37 growth rings, was assayde for $^{14}C$. From the results of the surface air study, it was calculated that during the above period the inventory of excess $^{14}C$ in the atmosphere decreased with a half-time of 4.6 years. The overall yearly decrease was also checked. The tree-ring study showed that the tree's atmosphere was affected by $^{14}C$ from nuclear tests after 1956. In one study, atmospheric $CO^2$ samples were collected bi-monthly by the absorption of $CO^2$ in alkaline hydroxide solution. In the other, 5 year annual growth rings were assayed for radiocarbon. For the radioactivity measurement, carbon atoms in samples were converted to carbon atoms of benzene. The resulting benzene was taken as primary solvent for liquid scintillation counting.

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Numerical studies on dynamic response of interactive system between atmosphere and ocean

  • Ryu, Chan-Su;Lee, Soon-Hwan
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.226-231
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    • 2003
  • A coupling system of MM5 and POM using Stampi with different kinds of parallel computer is proposed and comparative numerical simulations of mesoscale wind induced by topography around East Sea/Sea of Japan are carried out. The results are as follows: 1) Strong horizontal conversion is induced by high mountain Pekdoo at its leeside. 2) The conversion winds at lee of high mountain are not clear in monthly and yearly mean NCEP-reanalysis because of coarse resolution of 1.86 degree by 1.86 degree. But Wind conversion is well simulated at atmosphere and ocean coupling system. And the conversion area of lee side of mountain is also agreed well with observed data of NSCAT launched in satellite ADEOS. 3) The surface ocean current is well correspondent with wind direction, induced by high mountains. And small different wind field information lead the different of particle distribution in numerical experiments of particle distribution on ocean surface.

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Microwave Radiometer for Space Science and DREAM Mission of STSAT-2

  • Kim, Y.H.
    • Bulletin of the Korean Space Science Society
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    • 2008.10a
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    • pp.31.4-32
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    • 2008
  • The microwave instruments are used many areas of the space remote sensing and space science applications. The imaging radar of synthetic aperture radar (SAR) is well known microwave radar sensor for earth surface and ocean research. Unlike radar, microwave radiometer is passive instrument and it measures the emission energy of target, i.e. brightness temperature BT, from earth surface and atmosphere. From measured BT, the geophysical data like cloud liquid water, water vapor, sea surface temperature, surface permittivity can be retrieved. In this paper, the radiometer characteristics, system configuration and principle of BT measurement are described. Also the radiometer instruments TRMM, GPM, SMOS for earth climate, and ocean salinity research are introduce. As first korean microwave payload on STSAT-2, the DREAM (Dual-channels Radiometer for Earth and Atmosphere Monitoring) is described the mission, system configuration and operation plan for life time of two years. The main issues of DREAM unlike other spaceborne radiometers, will be addressed. The calibration is the one of main issues of DREAM mission and how it contribute on the space borne radiometer. In conclusion, the radiometer instrument to space science application will be considered.

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Behavior of the Surface Precipitation of Manganese Oxides during Hot-dip Galvanizing (용융아연 도금욕에서 망간 산화물의 표면석출 거동)

  • Lee, Ho Jong;Kim, Myung Soo
    • Journal of the Korean institute of surface engineering
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    • v.48 no.1
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    • pp.27-32
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    • 2015
  • Advanced high strength steels undergo recrystallization annealing in reducing gas atmosphere before galvanizing to improve mechanical properties. The selective oxidations of elements such as Mn, Si, Cr and Al during annealing decrease wettability of liquid zinc, resulting in bare spots and other defects. In this work, Fe-3wt%Mn steel sheet was annealed at $780^{\circ}C$ for 1200 sec. in 5% $H_2-N_2$ atmosphere and then dipped into zinc bath held at $460^{\circ}C$, which contained 0.2wt% dissolved Al. MnO crystallines in the average size of 200 nm were formed on the surface after annealing. It is estimated that MnO has been detached into bath with the formation and growth of inhibition layer with longer immersion time during galvanizing. No evidence of aluminothermic reduction of MnO has been found in this study.

EFFECTS OF SURFACE TREATMENTS AND STORAGE CONDITIONS ON TARGIS/DENTIN BOND STRENGTH (Targis 표면처리가 상아질과의 전단결합강도에 미치는 영향)

  • Oh, Young-Taek;Hwang, Su-Jin;Lee, Se-Joon;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.25 no.2
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    • pp.262-271
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    • 2000
  • The purpose of this study was to estimate shear bond strength according to difference in Targis surface treatment and storage condition. 140 non-carious extracted human molars and Targis D210(Ivoclar, Liechtenstein) were used in the present study and were divided into 7 experimental groups respectively according to surface treatment of Targis. Group 1 ; No treatment, Group 2 ; $50{\mu}m$ aluminium oxide blasting, Group 3 ; 4% HF etching for 3 minutes, Group 4 ; 4% HF etching after blasting, Group 5 ; silane treatment after blasting, Group 6 ; silane treatment after 4% HF etching, Group 7 ; silane treatment after blasting and 4% HF etching. In Each group, one half of 20 specimens was stored in distilled water at $37^{\circ}C$ for 24 hours and the other half was stored at atmosphere for 24 hours respectively. Dentin surface was etched with 10% $H_3PO_4$ for 15 seconds and luting cement(Variolink II, Vivadent, Liechtenstein) was applied by manufacturer's recommendation. Shear bond strength for each group was then measured. To examine the failure patterns after shear bond test and to observe the change after surface treatment of Targis. Specimens were fabricated and observed under the SEM. Statistical analysis was performed by One Way ANOVA test and t-test. The results were as follows ; 1. The shear bond strength of the groups stored in water significantly lower than that of groups stored at atmosphere (P<0.05). 2. There was no significant difference in shear bond strength in groups stored in water (P>0.05). 3. The shear bond strength without surface treatment of Targis were lowest among all experimental groups in atmosphere condition(P<0.05). 4. There was no significant difference in bond strength between groups using the silane or not(P>0.05). 5. The groups treated by blasting, hydrofluoric acid and silane sequentially showed highest bond strength than that of other groups in atmosphere condition, but there was no significant difference(P>0.05). 6 The proportions of the specimens showing the mixed fracture failure were 20% in HF etching group and blasting + HF group, 40% in blasting + HF + silane group in atmosphere condition. All the specimens stored in water showed adhesive fracture failure.

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A Study on the Breakdown Mechanism of Rotating Machine Insulation

  • Kim, Hee-Gon;Kim, Hee-Soo;Park, Yong-Kwan
    • Journal of Electrical Engineering and information Science
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    • v.2 no.3
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    • pp.71-76
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    • 1997
  • A lot of experiments and analyses have been done to determine the aging mechanism of mica-epoxy composite material used for large generator stator windings in order to estimate remaining life of the generator for last decades. After degrading artificially the mica-epoxy composite material, the surface analysis is performed to analyze breakdown mechanism of insulation in air and hydrogen atmosphere; i) In the case of air atmosphere, it is observed that an aging propagation from conductor to core by partial discharge effect and the formation of cracks between layers is widely carbonized surface. ii) In case of hydrogen atmosphere, the partial discharge effect is reduced by the hydrogen pressure (4kg/$\textrm{cm}^2$). Potassium ions forming a sheet of mica is replaced by hydrogen ions, which can lead to microcracks. It is confirmed that the sizes of crack by SEM analysis are 10∼20[$\mu\textrm{m}$] in length under air, and 1∼5[$\mu\textrm{m}$] in diameter, 10∼50[$\mu\textrm{m}$] in length under hydrogen atmosphere respectively. The breakdown mechanism of sttor winding insulation materials which are composed of mica-epoxy is analyzed by the component of materials with EDS, SEM techniques. We concluded that the postassium ions of mica components are replaced by H\ulcorner, H$_3$O\ulcorner at boundary area of mica-epoxy and/or mica-mica. It is proposed that through these phenomena, the conductive layers of potassium enable creation of voids and cracks due to thermal, mechanical, electrical and environmental stresses.

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Effect of Hydrogen in Rapid Thermal Annealing on the Graphene-Zinc Oxide Electrode for Supercapacitor (슈퍼커패시터용 그래핀-산화아연 전극의 급속열처리에서 수소의 영향)

  • Jeong, Woo-Jun;Oh, Ye-Chan;Kim, Sang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.52 no.3
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    • pp.123-129
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    • 2019
  • With recent demand for the renewable energy resources, we conducted a research on the energy conversion and storage device of supercapacitor. The hybrid graphene-zinc oxide(GZO) electrodes for the supercapacitors (SCs) were fabricated and investigated. To increase the electrical conductivity of the GZO electrode, the rapid thermal annealing(RTA) in $Ar/H_2$(10%) atmosphere was applied and the effect was examined by comparing it with RTA at Ar atmosphere. In Raman spectroscopy, the electrodes annealed at 400? in $Ar/H_2$ atmosphere showed a lower ratio of D/G peak than that of annealed at Ar atmosphere, and had a larger specific capacitance(Sc) in the cyclic voltammetry(CV), and a lower the equivalent series resistance(ESR) in the electrochemical impedance spectroscopy(EIS). The reason seems to come from the better mixing of the graphene and zinc oxide by the RTA in $Ar/H_2$(10%).