• 설비공학논문집
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• 제15권4호
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• pp.274-286
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• 2003

Numerical simulations are performed to investigate the turbulent convective heat transfer of the supercritical carbon dioxide flows in vertical and horizontal square ducts. The gas cooling process at the supercritical state experiences a sudden change in thermodynamic and transport properties. This results in the extraordinary variations of the heat transfer coefficients in the supercritical state, which are much different from those of single or two phase flows. Algebraic second moment closure which can include the effects of large thermophysical property variations of carbon dioxide and of buoyancy is employed to model the Reynolds stresses and turbulent heat fluxes in the governing equations. The previous correlations for the turbulent heat transfer coefficient for the supercritical carbon dioxide flows couldn't reflect the buoyancy effect. The present results are used to establish a new heat transfer coefficient correlation including the effects of large thermophysical property variation and buoyancy on in-duct cooling process of supercritical carbon dioxide.

• KSBB Journal
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• 제16권1호
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• pp.95-98
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• 2001

순수한 초임계 이산화탄소로는 대두박으로 부터 daidzein을 추출할 수 없었다. 보조용매로서 에탄올을 사용하면 daidzein을 추출이 가능하였다. 에탄올을 보조용매로 사용한 경우 온도가 증가할수록 daidzein의 추출 효율도 증가하였고, 압력이 증가할수록 추출 효율 역시 증가하였다. 에탄올을 보조용매로 사용하는 경우에 보조용매의 농도가 증가할수록 추출 효율도 비레하여 증가하였고 19% 이상에서는 추출 효율이 완만하게 증가하였다. 보조용매 농도가 15% 이상부터는 보조용매 농도가 증가할수록 daidzein함량은 감소하는 경향을 나타내었다. 보조용매 농도가 15%에서 93% 추출 효율을 나타냈다. 추출시간에 따른 추출 효율의 변화를 연구한 결과, 초기에는 추출 효율이 급격하게 증가하다가 후반부터는 완만하게 증가하는 즉, 포화현상을 나타내었다. 추출시간에 따른 추출된 daidzein함량의 변화는 뚜렷한 경향은 없지만, 대체적으로 추출시간이 증가할수록 감소하는 경향을 나타내었다.

• 한국응용과학기술학회지
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• 제37권4호
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• pp.674-681
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• 2020

The root of Codonopsis lanceolata has been used in traditional medicine. This study was conducted to confirm the comparative effect of ethanol solvent extraction (CLE) and supercritical carbon dioxide extraction (CLS) of C. lanceolata roots. CLS had higher antioxidant than CLE. For supercritical co-solvent modified carbon dioxide extraction (CLS), it were extracted at 250 bar 50℃ 150 min at a flow rate of ethyl alcohol 3 mL/min for 90min. In addition, CLS inhibited the adipocyte differentiation of 3T3-L1 cells. When treated with the extract at a concentration of 100 ㎍/mL, the Wnt/β-catenin pathway reporter luciferase activity of HEK 293-TOP cells increased approximately by 3-folds compared to that of the untreated control group. Also, the treatment by CLS (50 ㎍/mL) showed a significant increase of involucrin expression. These results indicate that supercritical carbon dioxide extract of C. lanceolatamay serve as a cosmeceutical agent for improving skin barrier function and the treatment of obesity.

• Journal of Microbiology and Biotechnology
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• 제4권3호
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• pp.230-232
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• 1994

The enzymes $\alpha$-amylase and glucoamylase used in starch hydrolysis were found active in the supercritical carbon dioxide solvent Higher hydrolysis of starch sluny in supercritical $CO_2$ was achieved by operating the reactor for the first two hours with $\alpha$ -amylase and to subsequent addition of glucoamylase for continued hydrolysis.

• 대한기계학회논문집B
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• 제40권10호
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• pp.673-679
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• 2016

초임계 이산화탄소 사이클은 소형화 및 효율 향상에 대한 잠재력 때문에 최근 관심이 증가하고 있으며, 원자력, 태양열(CSP) 및 화력 발전 분야에서 활발히 연구되고 있다. 이와 관련하여, 본 논문에서는 한국에너지기술연구원(KIER)의 초임계 이산화탄소 동력 사이클 연구 내용과 현황을 소개하였다. 1 단계 연구에서는 단순 초임계 브레이튼 사이클 실험 루프를 제작 및 시운전 하였으며, 현재 진행중인 2 단계 연구에서는 두개의 터빈과 두개의 재생기를 갖는 초임계 이중(dual) 브레이튼 사이클을 설계 및 제작하고 있다. 최적 설계를 위한 초임계 이중 브레이튼 사이클 모델링 및 시뮬레이션 결과, 본 연구에서 고려한 조건하에서, 사이클의 순출력을 극대화시키는 설계 변수가 존재함을 확인하였다.

• International Journal of Precision Engineering and Manufacturing
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• 제9권4호
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• pp.63-65
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• 2008

The increased interest in reducing the environmental effects caused by releasing organic compounds and aqueous waste has motivated the development of polymeric materials in supercritical fluids. Recently, supercritical fluids have been used in material synthesis and processing because of their special properties, such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive because it is non-toxic, non-flammable, and has moderate critical temperature and critical pressure values. Supercritical carbon dioxide can also swell most polymers. In this study, we prepared polymer/clay nanocomposites using supercritical fluids. Cloisites 10A, 15A, 25A, and 30B used in this study are montmorillonites modified with a quaternary ammonium salt. The nanocomposites of polymer/clay were characterized by X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry.

• 한국응용과학기술학회지
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• 제36권4호
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• pp.1136-1142
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• 2019

The root of Paeonia lactiflora has been used in Chinese medicine. We conducted to check the comparative qualities of ethanol solvent extraction (PLE) and supercritical carbon dioxide extraction (PLS) of P. lactiflora root. PLE had higher antioxidant and polyphenol contents than PLS. But, PLS were significantly increased peroxisome proliferator-activated receptor (PPAR)-α. In addition, PLS inhibited the adipocyte differentiation of 3T3-L1 cells. When treated with the extract at a concentration of 100 ㎍/mL, the Wnt/β-catenin pathway reporter luciferase activity of HEK 293-TOP cells increased approximately by 3-folds compared to that of the untreated control group. These results indicate that P. lactiflora supercritical carbon dioxide extract may serve as a cosmeceutical for improving skin barrier function and the treatment of obesity.

• Natural Product Sciences
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• 제25권4호
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• pp.341-347
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• 2019

Luffa cylindrica (LC) is a very fast-growing climber and its fruit have been considered as agricultural wastes. We conducted to check the comparative qualities of ethanol solvent extraction (LCE) and supercritical carbon dioxide extraction (LCS) of L. cylindrica fruit and seed. LCS had higher antioxidant and polyphenol contents than LCE. LCS were significantly increased peroxisome proliferator-activated receptor (PPAR)-a and involucrin expression as epidermal differentiation marker in 3D skin equivalent model. LCS also showed antimicrobial activity against Staphylococcus aureus, a causative bacteria in atopic dermatitis. In addition, LCS inhibited the adipocyte differentiation of 3T3-L1 cells. When treated with the extract at a concentration of 100 ㎍/mL, the Wnt/β-catenin pathway reporter luciferase activity of HEK 293-TOP cells was increased approximately by 2-folds compared to that of the untreated control group. These results indicate that L. cylindrica supercritical carbon dioxide extract may serve as a cosmeceutical for improving skin barrier function and the treatment of obesity.

• 한국수소및신에너지학회논문집
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• 제30권4호
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• pp.297-302
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• 2019

In this paper, the power generation efficiency increase has been studied for a Rankine cycle using both supercritical carbon dioxide as a working fluid and LNG as a coolant with PRO/II with PROVISION release 10.0 from Aveva company. Peng-Robinson equation of the state model with Twu's alpha function was selected for the modeling of the power generation cycle using LNG cold heat. Power generation efficiency was increased from 24.82% to 57.76% when using LNG as a coolant for supercritical carbon dioxide power generation cycle.

• 설비공학논문집
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• 제16권6호
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• pp.538-545
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• 2004

This paper presents the experimental data for the heat transfer and pressure drop characteristics obtained during the gas cooling process of carbon dioxide in a horizontal tube. The tube in which carbon dioxide flows is made of copper with an inner diameter of 7.73 mm. Experiments were conducted for various mass fluxes and inlet pressures of carbon dioxide. Mass fluxes are controlled at 225, 337 and 450 kg/$m^2$s and inlet pressures are adjust-ed from 7.5 to 8.8 ㎫. The experimental results in this study are compared with the existing correlations for the supercritical heat transfer coefficient, which generally under-predict the measured data. Pressure drop data agree very well with those calculated by the Blasius' equation. Based on the experimental data, a new empirical correlation to estimate the near-critical heat transfer coefficients has been developed.