• 한국표면공학회지
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• 제55권1호
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• pp.32-37
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• 2022

In a carbon-zero social atmospher, research is underway to reduce the use of fossil fuels. Interest in cleaner energy sources and their storage system is growing, and among them, research on effective energy storage is being actively conducted. Energy storage system(ESS) can be divided into secondary batteries, fuel cells, and capacitors, and the superiority of energy density of secondary batteries has a dominent influence on the ESS market. However, as problems with secondary batteries, charge/discharge speed, safety, and deterioration of electrodes are being highlighted. In this study, an electrode for supercapacitor with superior charge/discharge speed and specific capacitance is manufactured. The manufactured spinel nickel cobalt electrodes had specific capacitances of 1018.8 F/g, 690.8 F/g, and 475.1 F/g at 1 A/g in 1 M KOH electrolyte, and shows a performance retention rate of 77.48%, 63.30%, and 58.16% after 2000cycles at 7 A/g.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2011년도 정기총회 및 추계학술대회 논문집
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• pp.754-760
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• 2011

In the DC traction system, a large load current of electric railcar leads to a voltage drop when a vehicle starts, and the regenerative power generated by brake system increases the catenary voltage. To minimize the voltage fluctuation during the train operation and make use of the regenerative power, several types of energy storage systems are being studied. The energy storage system that is being recently introduced consists of the supercapacitors for energy storage and the bi-direction DC/DC converter for charge/discharge control. The efficiency of the energy storage system depends on the train operation pattern. In this paper, the operation efficiency of the energy storage system was quantitatively analyzed via simulation study taking consideration of the train operation patterns. The simulation was conducted changing the headway of trains with the energy storage system that uses the bi-direction DC/DC converter and supercapacitor. The simulation results showed that the operation efficiency of the energy storage system increases as the headway increase.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.133.1-133.1
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• 2010

In this work, carbon black(CBs)-embed multi-walled carbon nanotubes (MWNTs) as conductive fillers for activated carbon(ACs)-based electrodes for supercapacitor were prepared by chemical reduction of oxidized MWNTs and CBs. The effect of CBs-MWNT composites on electrochemical performances of ACs-based electrodes were investigated as a function of CB-MWNT ratio. It was found that CBs-MWNTs composites were formed by the reduction reaction of the functional groups of oxidized MWNTs and CBs. It was resulted in the conjugation of CBs onto the MWNT having high surface area and aspect ratio, leading to the enhanced electrical properties of MWNTs. The electrochemical performances, such as current density, charge-discharge, and specific capacitance of the ACs/CBs-MWNT electrodes were higher than that of ACs/MWNTs and conventional ACs/CB electrodes, which was attributed to the synergistic effect of CBs-MWNTs as a conductive filler.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.307-309
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• 2006

There are operated the six thousand train in the interior of a country. 95% of them are possible usage of resuscitation. Especially, Among them VVVF-Inverter vehicle has a merit of the highest recycle rate. but we don't use a apt recycled energy. Although the existing recycle energy used inverter method supply with electric power, it is decided in accordance with the state of sources. So efficiency of recycled electric power is of poor quality and catenary-voltage-fluctuation be generate because of recycled electric power. and it is able to affect system of safety train service. We'll research the method of supply according to wire condition after storing recycle energy made during train's stopping relation to Advanced EMU Research. Those methods are divided SMES, Fly-Wheel and Supercapacitor, and Considering the both economical efficiency and system application, we'll develop recycle energy storage system suitable our country condition.

• 한국세라믹학회지
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• 제45권8호
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• pp.493-496
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• 2008

Composite electrodes consisting of $CoMnO_2$ and carbon nanofibers(vapor grown carbon nanofiber, VGCF) with high electrical conducivity($CoMnO_2$/VGCF) were prepared on a porous nickel foam substrate as a current collector and their supercapacitive properties were investigated using cyclic voltammetry in 1 M KOH aqueous solution. The $CoMnO_2$/VGCF electrode exhibited high specific capacitance value of 630 F/g at 5 mV/s and excellent capacitance retention of 95% after $10^4$ cycles, indicating that the used VGCF played the important roles in reducing the interfacial resistance in the composite electrode to improve supercapacitive performance.

• 전기화학회지
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• 제6권2호
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• pp.158-160
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• 2003

We have reported to make nanostructured cobalt oxide electrode that have large capacitance over than 400 F/g (specific capacitance) and good cycleability. But, it had serious demerits of low voltage range under 0.5 V and low power density. Therefore, we need to increase voltage range of cobalt oxide electrode. We report here on the electrochemical properties of sol-gel-derived nanoparticulate cobalt xerogel in 1M KOH solution and aqueous polymeric gel electrolyte. In solution electrolyte, cobalt oxide electrode had over 250 F/g capacitance consisted of EDLC and pseudocapacitance. In gel electrolyte, cobalt oxide electrode had around 100 F/g capacitance. This capacitance was only electric double layer capacitance of active surface area. In solution electrolyte, potassium ion as working ion reacted with both of layers easily. However, In gel electrolyte, reacted with only surface-active layer. Itis very hard to reach resistive layer. So, we have studied on pretreatment of electrode to contain working ions easily. We'll report more details.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.1.1-1.1
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• 2011

Electrospinning has known to be very effective tool for production of versatile one-dimensional (1D) nanostructured materials such as nanofibers, nanorod, and nanotubes and for easily assembly to two-, three-dimensional(2D, 3D) nanostructures such as thin film, membrane, and nonwoven web, etc. We have studied on the electrospinning technology for novel energy storage and conversion materials such as advanced separator, dye sensitized solar cell, supercapacitor, etc. High heat-resistive nanofibrous membrane as a new separator for future lithium ion polymer battery was prepared by electrospinning of PVdF based composite solution. The novel nanofibrous composite nonwovens have tensile strength of above 50 MPa and modulus of above 1.3 GPa. The internal structure of the electrospun composite nanofiber with a diameter of few hundreds nanometer were composed of core-shell nanostructure. And also electrospun $TiO_2$ nanorod/nanosphere based dye-sensitized solar cells with high efficiency are successfully prepared. Some battery performance will be introduced.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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• pp.43-43
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• 2003

Carbon nanotubes(CNTs) have many application points, which are field emission devices, composites, hydrogen storage, nanodevices, supercapacitor and secondary battery. The most promising application point is emitter tip mays of field emission devices. Furthermore, it may be also useful as a vacuum device for high frequency and high power. But, there are some obstacles to fabricate carbon nanotube field emission device. One is that CNTs grown by CVD method has weak adhesion with substrate and the other is non-uniform length of them. These problems are very crucial in aging property and reliability of device in the field emission.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2009년도 추계학술대회 논문집
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• pp.291-295
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• 2009

Economic and environmental concerns over fossil fuels encourage the development of photovoltaic(PV) energy systems. Due to the intermittent nature of solar energy. energy storage is needed in a stand-alone PV system for the purpose of ensuring continuous power flow. Grid-connected PV system that supply power in a critical load demand require to curb power fluctuation. In this case. SCB is a effectiveness in controlling power variation due to intrinsic PV system. We propose the Matlab/Simulink dynamic model and power flow characteristics of a hybrid energy system with PV and SCB.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2009년도 정기총회 및 추계학술대회 논문집
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• pp.114-116
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• 2009

최근 계속되는 유가 상승과 화석에너지의 고갈 문제, 그리고 환경에 대한 관심 증가로 인해 자동차의 연비 개선 및 배기가스 저감을 위한 친환경 저연비 자동차 기술이 요구되고 있다. 이들 중 하이브리드 차량은 화학적 에너지 저장 장치에 차량 감속 시 회생 제동을 통해 전기 에너지를 저장하고 가속 시 이 에너지를 다시 사용함으로써 연비 개선과 배기가스 저감 효과를 가져 올 수 있다. 이를 위하여 회생 제동 시에 발생하는 에너지를 저장하기 위해 배터리 또는 초고용량 커패시터가 사용 된다. 본 논문에서는 두 에너지 저장 장치의 특성을 전기적인 등가회로 모델로 표현하고 주파수 응답을 통해 온도와 SOC에 따른 각각의 회로 정수를 산출할 뿐 아니라 이 때 주파수 변화에 따른 전압과 전류의 위상차와 역률에 관하여 알아보고자한다.