• Korean Chemical Engineering Research
• /
• v.48 no.3
• /
• pp.292-299
• /
• 2010

Graphene is a two-dimensional nanosheet consisting of honeycomb lattices of $sp^2$ carbon atoms. It is one of promising active materials for the anode of lithium-ion battery and the electrode of supercapacitor, due to its large specific surface area(theoretically $2600m^2\;g^{-1}$), high electric conductivity(typically $8{\times}10^5S\;cm^{-1}$), and mechanical strength. In this review, the synthetic methods of graphene nanosheet and graphene-based nanocomposite are introduced. Also, the electrochemical properties obtainable when the graphene-based materials are adopted to the electrodes of lithium-ion battery and supercapacitor are discussed along with their nanostructures.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
• /
• 2011.05a
• /
• pp.589-592
• /
• 2011

In this paper, bidirectional DC-DC converter is designed to cover up defects of fuel cell generating system like as low dynamic characteristic, unstable output and lack of storage ability by using bidirectional DC-DC Converter and supercapacitor that available to charge & discharge quickly, high efficient at charge & discharge and semi-permanent. Operating efficiency has been analyzed through simulation and examination. According to these design and data, hybrid system has been made and operation test, evaluation and results evaluation have been performed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2004.11a
• /
• pp.683-686
• /
• 2004

In recent years, the supercapacitor and hybrid capacitor have related with substitutional energy source focused of many scientists because of their usage in power sources for electric vehicles, computers and other electric devices. The storage energy of electrical charge is based on electrostatic interactions in the electric double layer at the electrode/electrolyte interface, resulting in high rate capability and long cycle performance compared with batteries based on Faradaic electrode reactions. So we have been considered to carbon nanofibers as the ideal material for supercapacitors due to their high utilization of specific surface area, good conductivity, chemical stability and other advantages. In this work, we aimed to find out that the capacitance have increased because of electrochemical capacitance to provide by carbon nanofibers. Also carbon nanofibers based on chemical method and water treatment have been resulted larger capacitances and also exhibit better electrochemical behaviors about 15% than before of nontreated state. And also optical observations with treated and nontrteated carbon nanofibers discussed by the TEM, SEM, EDX, BET works and specific surface area analyzer. Their results also focused on the surface area of electrode and electrical capacitance was also improved by the effect of surface treatments.

• Journal of IKEEE
• /
• v.19 no.3
• /
• pp.304-310
• /
• 2015

A SCALDO(Supercapacitor Assisted LDO) regulator is a new regulator having advantages of a SMPS(Switch Mode Power Supply) which has a good efficiency and a LDO(Low Drop-out) regulator which has stable output characteristics and good EMI(Electro Magnetic Interference) characteristics. However, a conventional SCALDO regulator needs a lot of power consumption to control its switches and it drops an efficiency of the circuit. In this paper, to reduce switching power consumption and improve an efficiency of the circuit, a new SCALDO regulator adopting MOSFETs as its switching parts is proposed and it is found out that the proposed SCALDO regulator has the maximum 9.5% higher efficiency than the conventional SCALDO regulator. We also try to simplify production process of the circuit by changing switching control method of the circuit from MCU(Micro-controller unit) based firmware control to hardware control using a comparator and a T-F/F(Flip Flop).

• Membrane Journal
• /
• v.29 no.6
• /
• pp.323-328
• /
• 2019

It is a highly important problem for mankind to supply sufficient energy, which has been connected to production and supply of electricity. In terms of the problems, this study fabricated a new sort of solid polymer electrolyte membrane for supercapacitors. The fabricated electrolyte employed grafting poly(oxyethylene methacrylate) (POEM) side chain on poly(vinyl alcohol) (PVA) main chain by free-radical polymerization. It is the first time to utilize PVA-g-POEM graft copolymer as an electrolyte membrane for supercapacitor. The chain behavior of PVA was transformed by grafting POEM side chains, which was analyzed by FT-IR spectra. Also, the capacitance performances of fabricated supercapacitors were explored by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and ragone plot. We suggest a new point, the grafting of the electrolyte of supercapacitor in this study.

• Applied Chemistry for Engineering
• /
• v.18 no.4
• /
• pp.381-385
• /
• 2007

High density activated carbons electrode materials, for supercapacitor were prepared by chemical KOH activation of cokes as the starting material under Ar atmosphere. By controlling the synthesis conditions and reducing KOH quantity in the activation step, the specific surface area of the product was decreased. BET surface area was measured to be $500{\sim}1260m^2/g$, and the electrode density was in the range of $0.68{\sim}0.83g/cm^3$. Volumetric specific capacitance (unit cell test) was as high as 20 F/cc, which corresponds to gravimetric specific capacitance of about 95 F/cc on the basis of half cell test. It should be noted that the specific capacitance of the activated carbons prepared in this study is superior to that of commercial activated carbons.

• Korean Chemical Engineering Research
• /
• v.46 no.5
• /
• pp.898-902
• /
• 2008

Prepared are three types of composite supercapacitor electrode, such as electroactive polyaniline(PAN), PAN/multi-walled carbon nanotube(CNT), and $CNT/PAN/RuO_2$. Cyclic voltammetry was performed to investigate the supercapacitive properties of these electrodes in an electrolyte solution of 1.0M $H_2SO_4$. The $CNT/PAN/RuO_2$ electrode showed the highest specific capacitance at all scan rates(e.g., 441 and $392F\;g^{-1}$ at 100 and $1,000mV\;s^{-1}$, respectively). In cycle performance, however, the PAN/CNT electrode demonstrated the best capacitance retention (66%) at $10^4th$ cycle.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.18 no.6
• /
• pp.205-212
• /
• 2004

In this paper the design of a 1-[KVA] fuel cell powered line-interactive UPS system employing modular (fuel cell & DC/DC converter) blocks is proposed. The proposed system employs the two fuel cell modules along with suitable DC/DC converters and these modules share the DC-Link of the DC/AC inverter. A supercapacitor module is also employed to compensate for the instantaneous power fluctuations and to overcome the slow dynamics of the fuel processor. The energy stored in the supercapacitor can also be utilized to handle the overload conditions for a short time period. Due to the absence of batteries, the system satisfies the demand for an environmentally friendly and dean source of the energy. A complete design example illustrating the amount of hydrogen storage required for 1hr power outage, and sizing of supercacpacitor for transient load demand is presented for a 1-[KVA] UPS.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2005.07a
• /
• pp.597-598
• /
• 2005

Recently, the performance of portable electric equipment can often improved by a Li-ion battery assisted by a supercapacitor. A supercapacitor can provide high power density as well as a low resistance in the hybrid system. In this study, we have prepared, as the pluse power souce, a commercially supplied Li-ion battery with a capacity of 700mAh and AC resistivity of $60m\Omega$ at 1kHz and nonaqeous asymmetric hybrid capacitor composed of an activated carbon cathode and MCMB anode, and have examined the electrochemical characteristics of hybrid capacitor and the pulse performances of parallel connected battery/hybrid capacitor source. The nonaqueous asymmetric hybrid capacitor, the stacks of 10 pairs of the cathode, the porous separator and the anode electrode were housed in Al-laminated film cell. The hybrid capacitor, which was charged and discharged at a constant current at $0.25mA/cm^2$ between 3 and 4.3V, has exhibited the capacitance of 100F. And the equivalent series resistance was $32m\Omega$ at 1kHz. By combining a Li-ion battery and a hybrid capacitor, the pulse performance of battery can be improved 23% in run time under a pulse discharge of 7C-rate.

• Journal of the Korea Society of Computer and Information
• /
• v.26 no.11
• /
• pp.11-19
• /
• 2021

In this paper, we propose a prototype platform combined with the power management system using, as an auxiliary power storage device, a supercapacitor that can be fast charged and discharged with high power efficiency as well as semi-permanent charge and discharge cycle life. For the proposed platform, we designed a technique which is capable of detecting the state of power cutoff or resumption of power supplied from the solar panel in accordance with physical environment changes through an interrupt attached to the micro-controller was developed. To prevent data loss in a computing environment in which continuous power supply is not guaranteed, we implemented a low-level system software in the micro-controller to transfer program context and data in volatile memory to nonvolatile memory when power supply is cut off. Experimental results shows that supercapacitors effectively supply temporary power as auxiliary power storage devices. Various benchmarks also confirm that power state detection and transfer of program context and data from volatile memory to nonvolatile memory have low overhead.