• Title/Summary/Keyword: Sulfur contents

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CO2 Emission Characteristics of Bunker C Fuel Oil by Sulfur Contents (C 중유의 황 함유량에 따른 CO2 배출 특성)

  • Lim, Wan-Gyu;Doe, Jin-Woo;Hwang, In-Ha;Ha, Jong-Han;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.4
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    • pp.368-377
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    • 2015
  • Bunker C fuel oil is a high-viscosity oil obtained from petroleum distillation as a residue. The sulfur content of bunker C fuel oil is limited to 4.0% or even lower to protect the environment. Because bunker C fuel oil is burned in a furnace or boiler for the generation of heat or used in an engine for the generation of power, carbon dioxide is emitted as a result of combustion. The objective of this study is to investigate $CO_2$ emission characteristics of bunker C fuel oil by sulfur contents. Calorific values and carbon contents of the fuels were measured using the oxygen bomb calorimeter method and the CHN elemental analysis method, respectively. Sulfur and hydrogen contents, which were used to calculate the net calorific value, were also measured and then net calorific values and $CO_2$ emission factors were determined. The results showed that hydrogen content increases and carbon content decreases by reducing sulfur contents for bunker C fuel oil with sulfur contents less than 1.0%. For sulfur contents between 1.0% and 4.0%, carbon content increases as sulfur content decreases but there is no evident variation in hydrogen content. Net calorific value increases by reducing sulfur contents. $CO_2$ emission factor, which is calculated by dividing carbon content by net calorific value, decreases as sulfur content decreases for bunker C fuel oil with sulfur contents less than 1.0% but it showed relatively constant values for sulfur contents between 1.0% and 4.0%.

A Study on the Contents of Soluble Sulfur and Heavy Metals in the Leaves of the Roadside Tree in Seoul Area (서울시내 가로수목의 수용성유황 및 중금속 함량에 관한 연구)

  • 김면섭;이광국
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.1
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    • pp.1-12
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    • 1988
  • This study was carried out to measure the contents of soluble sulfur and heavy metals in the leaves of roadside tree at 34 sampling sites of Seoul area from the Sep. 1 to Sep. 30 during 1985 and 1986. The results were as follows; 1. Average contents of soluble sulfur at all sampling sites were; Plantanus orientalis 0.474%, Ginkgobioloba 0.562%, and Salix pseudolasiogyne 0.566%. 2. Correlation between sulfur dioxide concentration in the air and soluble sulfur in the leaves by area were; Green belt area R = 0.985, Residential area R = 0.856, Commercial area R = 0.668, Industrial area R = 0.886. Correlation by species were ; Platanus orientalis R = 0.817, Ginkgobiloba R = 0.771, Salix pseudo-lasiogyne R = 0.824. 3. Correlation between $SO_X$ concentration in the air and sulfur contents in the leaves showed positive significance. 4. Contents of soluble sulfur in the heavy traffic area were higher than that of light traffic area. 5. Heavy metal contents of 1986 were higher than that of 1985; Fe> Mn > Zn > Pb > Cu > Cd > Cr. 6. Lead contents in the leaves of 1986 were; Platanus orientalis 16, 701 ppm, Gingobiloba 21,729ppm, Salix Pseudo-lasiogyne 12.418 ppm.

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A Relationship Between AtmosPheric $SO_{2}$ Concentrations and Water Soluble Sulfur Contents in Gingko biloba in Seoul (서울 일부지역의 도로변 대기중 $SO_{2}$ 농도와 은행나무잎의 수용성 황함량과의 관계)

  • 박정숙;정문식;박석환
    • Journal of Environmental Health Sciences
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    • v.17 no.1
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    • pp.1-12
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    • 1991
  • The atmospheric SO$_{2}$ concentrations and water soluble sulfur contents in Ginkgo biloba were measured and analyzed in auto-measuring station, Kwangleung, and Yongmun from August 5 to October 21, 1990. The results of the study are as follows: 1. Atmospheric SO$_{2}$ concentrations between the seoul area(Pulkwang, Ssangmun, Myonmok, Oilurn) in which the concentrations exceeded the air quality standards and the surburb of seoul (Kwangleung, Yongmun) revealed the significant difference (p<0.01). 2. Water soluble sulfur contents in Ginkgo biloba in autumn were higher than those in Ginkgo biloba in summer (p<0.01). Water soluble sulfur contents in leaves showed a significant difference between seoul and its surburb(p<0.01). 3. Correlation between atmospheric SO$_{2}$ concentration and water soluble sulfur content of Ginkgo biloba in autumn was as follow Y=0.2714+9.8123 X, r=0.6362 (X: Airborne SO${_2}$ Concentration according to sampling location, Y: Water Soluble Sulfur Contents)

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Effect of Carbon Content of Sulfur Electrode on the Electrochemical Properties of Lithium/Sulfur Battery Using PEO Electrolyte (유황전극의 탄소량 변화에 따른 리튬/유황 전지의 방전특성 변화)

  • Kang, K.Y.;Ryu, H.S.;Kim, J.S.;Kim, K.W.;Ahn, J.H.;Lee, G.H.;Ahn, H.J.
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.3
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    • pp.317-323
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    • 2006
  • Electric conductive material should be homogeneously mixed with sulfur in sulfur electrode fabrication of lithium/sulfur battery, because sulfur is electric insulator. In this paper electrochemical properties of Li/S battery was studied with various compositions of sulfur electrodes. When content of sulfur changed from 40 wt.% to 80 wt.%, the 60 wt.% sulfur electrode showed the maximum capacity of 1489 mAh/g-sulfur. Electrochemical properties of Li/S battery using 60 wt.% sulfur was also investigated with various carbon contents. The discharge capacity changed as a function of carbon contents. The optimum composition was 25 wt.% carbon for 60 wt.% sulfur electrode.

A Study on the Effect of Air Pollutants in Daegu Area by Biological Indicator of Roadside (道路 指標生物을 이용한 대기오염이 植物에 미치는 영향에 관한 연구)

  • Kang, Hoe-Yang;Cha, Sang-Eun;Ha, Cheong-Gun
    • Journal of Environmental Health Sciences
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    • v.14 no.2
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    • pp.29-41
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    • 1988
  • This study was performed to investigate the air pollution levels in Daegu area titrough measuring of contents of water, chlorophyll, water soluble sulfur and lead metal in the leaves of roadside trees and chemical properties of soil under the urban trees. The results can be summarized as follows 1. The range of water content was from 60.4% to 74.6%. The comparisons of chlorophyll, water soluble sulfur and water content were regression equation, chlorophyll=0.1981+ 0.0040 water content (July), water soluble sulfur=3,139-0.0416 water content (July). and correlation coefficient, r=0.561 and r=0.549 respectively 2. Average contents of chlorophyll, water soluble sulfur and lead metal in the leaves of roadside tree at sampling sites were chlorophyll 0.050, 0.072mg/cm$^2$, water soluble sulfur 0.244, 0.333%, and lead metal 12.25, 12.68ppm in Oct. and Jul. respectively. 3. Correlation between chlorophyll and contents of water soluble sulfur and lead metal in the leaves of roadside tree at sampling sites were water soluble sulfur r=-0.564, -0.613 and lead metal r=-0.693, -0.699 in October and July, respectively. 4. Correlation between chlorophyll and water content, water soluble sulfur and lead metal in the leaves of tree showed positive significance.

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Studies on the Contents of Naturally Occurring of Sulfite in Foods (식품중 천연유래 이산화황 함유량에 관한 연구)

  • Kim, Hee-Yun;Lee, Young-Ja;Hong, Ki-Hyoung;Kwon, Yong-Kwan;Ko, Hyun-Sook;Lee, Young-Kyong;Lee, Chul-Won
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.544-549
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    • 2000
  • This study was performed to compare optimum analytical method for the contents of naturally occurring sulfur dioxide in foods and to investigate the contents of sulfur dioxide in foods in order to provide a fundamental data when distinguish between added and naturally occurring sulfur dioxide. The determination of the contents of sulfur dioxide in foods from the 20 kinds, 180 cases of samples has been analyzed by the optimized Monier-Williams method, modified Rankine method and Acid Distillation/Ion Chromatography. As a result of the study, the contents of naturally occurring sulfur dioxide in foods by the optimized Monier-Williams method showed from 1.02 to 43.87 ppm and highly content of 43.87, 15.37, 11.50, 11.21 and 10.60ppm were observed in garlic, platicodon, green onion, cabbage and onion, the others were less than 10.00ppm. The sulfur dioxide contents in green onion and garlic by modified Rankine method were showed to be 2.87 and 6.14ppm, respectively, the others were detected less than 2.50ppm. The contents of sulfur dioxide by Acid Distillation/Ion Chromatography showed 15.43, 9.82, 5.74, 5.37, 2.14 and 0.49ppm in garlic, cabbage, green onion, onion, potato and apple, respectively and the others were not detected. And the contents of sulfur dioxide in green onion, onion, cabbage and garlic showed higher levels of sulfur dioxide in these foods than the others because of the naturally occurring sulfur containing compounds. The optimized Monier-Williams method, which is the of official analytical method of Korean Food Code, was suitable for monitoring of sulfur dioxide of most foods. Acid Distillation/Ion Chromatography was thought to be adequate for sulfur containing foods such as green onion, onion and cabbage. In order to distinguish between added and naturally occurring sulfur dioxide, it is though to be need of the fundamental data for the contents of sulfur dioxide in sulfite-free foods and continue the investigation for it.

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The Effect of Sulfur Dioxide by Burn out on Enzyme Activity and Lipid Content in Rats (소환시 발생되는 아황산 가스가 흰쥐 혈청 중의 효소 활성도 및 지질 함량에 미치는 영향)

  • Kim, Hae-Dong;Kim, Byung-Hak;Ha, Hun;Cho, Soo-Yeul;Yoon, Soo-Hong
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.61-66
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    • 1997
  • Recently, incidences of pulmonary-related diseases are increasing and natural ecosystem is destroyed year by year owing to air pollutions by industrial noxious gases such as sulfur dioxide and carbon dioxide, etc. Sulfur dioxide produced by oxidation of sulfur compounds is water soluble and causes several kinds of pulmonary diseases, damaging on plants and animals. This study was undertaken to investigate effects of acute exposure of rats to sulfur dioxide using biochemical parameters. The sAST (aspartate transaminase) activity was not significantly affected but sALT (alanine transaminase), sLDH (lactate dehydrogenase) and sALP (alkaline phosphatase) activities were significantly increased by acute sulfur dioxide gas exposure. Also sulfur dioxide gas treatment significantly diminished serum cholinesterase activity. The total lipid, triglyceride, total-, HDL- and LDL-cholesterol contents were significantly increased by sulfur dioxide gas exposures. But the body and liver weight were generally diminished in comparison with control group. Our results' showed increased enzyme activities and lipid contents, but body and liver weight were all diminished by sulfur dioxide gas treatment.

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Influence on Compressive Strength and Drying Shrinkage of Concrete with Urea-Water Soluble Sulfur Admixture (요소-수용성 유황 혼화제가 콘크리트 압축강도 및 건조수축에 미치는 영향)

  • Park, Jae Kyu;Han, Sang Hoon;Hong, Ki Nam;Cho, Yong In;Chai, Yuzhe
    • Journal of the Korean Society of Safety
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    • v.31 no.5
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    • pp.74-81
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    • 2016
  • This paper presents an experimental study to ivestigate mechanical property of concretes according to addition of urea and urea-water soluble sulfur contents. Urea was added at 5~20% replacement by weight of water, and water soluble sulfur was used at 2%, 4% replacement by weight of cement. The setting times, the hydration heat, the compressive strength, and the drying shrinkage, were measured on concretes with single and binary admixtures. From the test result, it was confirmed that the hydration heat of urea-water soluble sulfur was lower than that of normal concrete by $10.1^{\circ}C$, and the drying shrinkage of urea-water soluble sulfur concrete was more excellent than normal concrete. In the case of urea of 5%, Compressive strength were improved with an increase of water soluble sulfur contents. The urea-water soluble sulfur used in this research can be used as improvement materials for drying shrinkage and compressive strength.

An Experimental Study on Characteristics of Soot by Pyrolysis of Fuel with Different Sulfur Contents. (연료의 황 함량에 따른 열분해 매연입자 특성화의 실험적 연구)

  • Lee, Seunghoon;Lim, Sangchul;Ahn, Teakook;Nam, Younwoo;Park, Sunho
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.261-264
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    • 2015
  • Soot particles of diesel and bunker-A with different sulfur contents were generated by pyrolysis with varying conditions of fuel flow rate and residence time in the ceramic tube at $1300^{\circ}C$. TEM and particle size analyzer were used for analysing the primary and the secondary particle size distributions. The results showed that the sulfur content in fuel influences soot inception while the fuel concentration and residence time affects the growth of incepted soot particles.

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Effects of Nitrogen and Sulfur Application on Yield and contents of Amino Acids Containing Sulfur of Rice (질소(窒素) 및 유황시용(硫黃施用)이 수도(水稻)의 수량(收量)과 함유황(含硫黃)아미노산(酸) 조성(組成)에 미치는 영향(影響))

  • Kim, Bok-Jin;Back, Jun-Ho;Choi, Hyuk
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.2
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    • pp.122-128
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    • 1997
  • A pot experiment was carried out using Seomjin-byeo and Samgang-byeo to investigate the effects of nitrogen and sulfur on the growth, yields, and sulfur containing amino acid content of rice. The yields and number of tillers at 50 days after transplanting were increased with the increase of the amounts of nitrogen and sulfur, but N/S ratio was decreased in both varieties. There were a positive correlations between yield and contents of nitrogen and sulfur in straw and brown rice, but a negative correlation between N/S ratio and yields at harvesting stage. Crude protein contents increased with the increase of amounts of nitrogen and sulfur. contents of amino acid containing sulfur in brown rice were positively correlated with the sulfur and nitrogen contents in rice straw.

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