• 제목/요약/키워드: Sulfur Dioxide

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Corrosion of Selected Materials in Boiling Sulfuric Acid for the Nuclear Power Industries

  • Kim, Dong-Jin;Lee, Han Hee;Kwon, Hyuk Chul;Kim, Hong Pyo;Hwang, Seong Sik
    • Corrosion Science and Technology
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    • v.6 no.2
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    • pp.37-43
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    • 2007
  • Iodine sulfur (IS) process is one of the promising processes for a hydrogen production by using a high temperature heat generated by a very high temperature gas cooled reactor(VHTR) in the nuclear power industries. Even though the IS process is very efficient for a hydrogen production and it is not accompanied by a carbon dioxide evolution, the highly corrosive environment of the process limits its application in the industry. Corrosion tests of selected materials were performed in sulfuric acid to select appropriate materials compatible with the IS process. The materials used in this work were Fe-Cr alloys, Fe-Ni-Cr alloys, Fe-Si alloys, Ni base alloys, Ta, Ti, Zr, SiC, Fe-Si, etc. The test environments were 50 wt% sulfuric acid at $120^{\circ}C$ and 98 wt% at $320^{\circ}C$. Corrosion rates were measured by using a weight change after an immersion. The surface morphologies and cross sectional areas of the corroded materials were examined by using SEM equipped with EDS. Corrosion behaviors of the materials were discussed in terms of the chemical composition of the materials, a weight loss, the corrosion morphology, the precipitates in the microstructure and the surface layer composition.

Development of Hazardous Materials Management Standard for Decoction Type of Personalized Herbal Medicine

  • Jeong, Hye-In;Kim, Kyeong-Han;Won, Jae-Hee;Sung, Gi-Un;Kim, Ji-Won;Han, Ji-eun;Sung, Angela Dong-Min;Park, Eun-Jung;Sung, Soo-Hyun
    • Journal of Pharmacopuncture
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    • v.23 no.2
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    • pp.71-78
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    • 2020
  • Objectives: This study was conducted to development of hazardous materials management standards for the decoction type of personalized herbal medicines (PHMs). Methods: This study was conducted in two stages. We searched documents about criteria to use words such as 'Herb', 'Herbal medicine', and 'Botanical Drug' and summarized the results. We organized the committee consisted of seven experts, and held two meetings to reach an agreement on hazardous management standards of the decoction type of PHMs. Results: The seven documents were presented in the literature review and six items related to hazardous management standards of decoction were identified. The second expert meeting brought that a total of six items, including heavy metal, pesticide residues, sulfur dioxide, benzopyrene, mycotoxin, and micro-organism limits, were selected for safety management of decoction type of PHMs. Also, the criteria and test methods for each standard were suggested for monitoring the decoction type of PHMs. Conclusion: The study suggested hazardous material management standards and criteria for the decoction types of PHMs. In the future, it would be necessary to conduct a pilot test to ensure the validity and credibility of the safety management standard and criteria. Furthermore, the government level safety management system should be introduced to verify the safety of decoction medicines.

OPF with Environmental Constraints with Multi Shunt Dynamic Controllers using Decomposed Parallel GA: Application to the Algerian Network

  • Mahdad, B.;Bouktir, T.;Srairi, K.
    • Journal of Electrical Engineering and Technology
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    • v.4 no.1
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    • pp.55-65
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    • 2009
  • Due to the rapid increase of electricity demand, consideration of environmental constraints in optimal power flow (OPF) problems is increasingly important. In Algeria, up to 90% of electricity is produced by thermal generators (vapor, gas). In order to keep the emission of gaseous pollutants like sulfur dioxide (SO2) and Nitrogen (NO2) under the admissible ecological limits, many conventional and global optimization methods have been proposed to study the trade-off relation between fuel cost and emissions. This paper presents an efficient decomposed Parallel GA to solve the multi-objective environmental/economic dispatch problem. At the decomposed stage the length of the original chromosome is reduced successively and adapted to the topology of the new partition. Two subproblems are proposed: the first subproblem is related to the active power planning to minimize the total fuel cost, and the second subproblem is a reactive power planning design based in practical rules to make fine corrections to the voltage deviation and reactive power violation using a specified number of shunt dynamic compensators named Static Var Compensators (SVC). To validate the robustness of the proposed approach, the algorithm proposed was tested on the Algerian 59-bus network test and compared with conventional methods and with global optimization methods (GA, FGA, and ACO). The results show that the approach proposed can converge to the near solution and obtain a competitive solution at a critical situation and within a reasonable time.

On Recent Variations in Solar Radiation and Daily Maximum Temperature in Summer (여름철 일 최고기온과 일사량의 최근 변동에 관하여)

  • Choi, Mi-Hee;Yun, Jin-I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.11 no.4
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    • pp.185-191
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    • 2009
  • Few studies have attempted to analyze variations of daily maximum temperature in the summer whereas many studies have analyzed warming trends in other seasons with respect to greenhouse gases or urban heat islands. We analyzed daily maximum temperature data for the summer season (June to August) at 18 locations in South Korea from 1983 to 2007. Compared to the climatic normal (from 1971 to 2000), an average increase of $0.1^{\circ}C$ was found for the summer daily maximum temperature along with an increase of $0.61MJ\;m^{-2}$ in daily solar radiation. Approximately 65% of the annual variations of the summer daily maximum temperature could be explained by the solar radiance alone. Higher atmospheric transmittance due to lower aerosol concentration (especially of sulfur dioxide) is believed to have caused the recent increase in solar irradiance. Daily maximum temperature of the summer is expected to keep rising if the clean air activities are maintained in the future.

Summertime Heat Waves and Ozone : an Interaction on Cardiopulmonary Mortality? - Based on the 1994 Heat Wave in Korea - (1994년 하절기의 심혈관계 및 호흡기계 초과사망 - 이상고온 및 대기오염의 영향을 중심으로 -)

  • Sung, Joo-Hon;Kim, Ho;Cho, Soo-Hun
    • Journal of Preventive Medicine and Public Health
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    • v.34 no.4
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    • pp.316-322
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    • 2001
  • Objectives : To explore the possible effect of an interaction between summertime heat waves and ozone on cardiopulmonary mortality during the 1994 heat wave in Korea. Methods : The unusually hot summer of 1994 in Korea was defined as the heat wave in this study. We examined the associations of air pollutants with daily cardiopulmonary deaths between 1991-1995, considering the product term of the heat wave and each pollutant, weather and time trends. Results : During the heat wave, while temperatures were uniformly higher than those of other summers, the within-heat-wave difference in mortality paralleled that in the regional ozone levels. In terms of the influence of the heat wave, the results of ozone were different to those of total suspended particles (TSP) and sulfur dioxide $(SO_2)$. The ozone association (relative risk (RR) : 1.036; 95% confidence interval (CI) = 1.018-1.054) was observed only under heat wave conditions, while the TSP (RR : 1.006, 95% CI = 0.999-1.012) and the $SO_2$ (RR = 1.018, 95% CI : 1.011-1.024) associations were found under normal weather conditions (per interquartile increase of each pollutant; results of three pollutants model). The ozone association under heat wave was attributable to the statistical interaction between the heat wave and ozone. Conclusions : These results support the possibility of a biological synergy between the heat wave and ozone, one that is not evident between the heat wave and other major pollutants like particles or $SO_2$.

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Determining Method of Sulfites in Foods by Ion Chromatography

  • Kim, Myung-Hee;Chae, Young-Zoo
    • Journal of Food Hygiene and Safety
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    • v.3 no.4
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    • pp.211-215
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    • 1988
  • Anion chromatographic (lC) method was developed for the determination of sulfites infoods. Sulfites refer to sulfur dioxide that was separated from a food sample by addition of acid and heating, and carried into a trapping solution by distillation. The trapping solution was applied to IC system. Sulfites was separated on an anionic separator column, HPIC-AS4A with 0.75mM $NAHCO_3/2.25mM\;Na_2CO_3$ as the eluent and determined by the use of conductivity detector. The recoveries of sulfites added to water, carrot and apple at level of 1 ppm were 99.8%, 91.6% and 83.5%, respectively. The detection limit was 0.2 ppm in the case of a 10 g sample size. All experiment could be finished within 20 minutes

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Evaluation of Limestone for In-Situ Desulfurization in CFB Boilers (순환유동층 보일러 로내 탈황을 위한 석회석 평가)

  • Lee, See Hoon;Kim, Dong Won;Lee, Jong Min;Bae, Yong Chae
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.853-860
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    • 2019
  • In order to meet more severe environmental regulations, oxy-fuel circulating fluidized bed(CFB) boilers or ultra supercritical CFB boilers, which are a kind of process in that solid particles moves similar to fluid, have been developed in the world. In CFB power generation processes, the method to reduce or remove sulfur dioxide is in-situ desulfurization reaction via limestone directly injected into CFB boilers. However, the desulfurization efficiencies have continuously changed because limestones injected into CFB boilers are affected by various operation conditions (Bed temperature, pressure, solid circulating rate, solid holdup, residence time, and so on). In this study, a prediction method with physical and chemical properties of limestone and operation conditions of CFB boiler for in-situ desulfurization reaction in CFB boilers has developed by integrating desulfurization kinetic equations and hydrodynamics equations for CFB previously published. In particular, the prediction equation for in-situ desulfurization was modified by using experimental results from desulfurization reactions of various domestic limestones.

Effect of Pyunkang-tang on Inflammatory Aspects of Chronic Obstructive Pulmonary Disease in a Rat Model

  • Seo, Hyo-Seok;Lee, Hyun Jae;Lee, Choong Jae
    • Natural Product Sciences
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    • v.25 no.2
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    • pp.103-110
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    • 2019
  • We investigated the anti-inflammatory effect of Pyunkang-tang extract (PGT), a complex herbal extract based on traditional Chinese medicine that is used in Korea for controlling diverse pulmonary diseases, on cigarette smoke-induced pulmonary pathology in a rat model of chronic obstructive pulmonary disease (COPD). The constituents of PGT were Lonicerae japonica, Liriope platyphylla, Adenophora triphilla, Xantium strumarinum, Selaginella tamariscina and Rehmannia glutinosa. Rats were exposed by inhalation to a mixture of cigarette smoke extract (CSE) and sulfur dioxide for three weeks to induce COPD-like pulmonary inflammation. PGT was administered orally to rats and pathological changes to the pulmonary system were examined in each group of animals through measurement of tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$) and interleukin-6 (IL-6) levels in bronchoalveolar lavage fluid (BALF) at 21 days post-CSE treatment. The effect of PGT on the hypersecretion of pulmonary mucin in rats was assessed by quantification of the amount of mucus secreted and by examining histopathologic changes in tracheal epithelium. Confluent NCI-H292 cells were pretreated with PGT for 30 min and then stimulated with CSE plus PMA (phorbol 12-myristate 13-acetate), for 24 h. The MUC5AC mucin gene expression was measured by RT-PCR. Production of MUC5AC mucin protein was measured by ELISA. The results were as follows: (1) PGT inhibited CSE-induced pulmonary inflammation as shown by decreased TNF-${\alpha}$ and IL-6 levels in BALF; (2) PGT inhibited the hypersecretion of pulmonary mucin and normalized the increased amount of mucosubstances in goblet cells of the CSE-induced COPD rat model; (3) PGT inhibited CSE-induced MUC5AC mucin production and gene expression in vitro in NCI-H292 cells, a human airway epithelial cell line. These results suggest that PGT might regulate the inflammatory aspects of COPD in a rat model.

Effect of PGRs and various co-packing materials on storage quality in 'Shine Muscat' grapes

  • Kim, Sung-Joo;Kim, Yu-Rim;Choi, Cheol;Ahn, Young-Jik;Choi, Hyun-Jin;Chun, Jong-Pil
    • Korean Journal of Agricultural Science
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    • v.48 no.2
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    • pp.241-250
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    • 2021
  • This investigation assessed the berry quality after two months of low-temperature storage (3 ± 1℃) of 'Shine Muscat' grapes, which were treated with CPPU (N-[2-chloro-4-pyridyl]-N'-phenylurea) or TDZ (1-phenyl-3-[1,2,3-thiadiazol-5-yl] urea) in combination with gibbrellic acid (GA3). The berry shatter rate was the lowest (1%) in 4 cm + CPPU treatment, while it was the highest (2.4%) in 3 cm floral length treated with CPPU. On the other hand, the 4 cm + TDZ treatment resulted in a shatter rate of 2.0%, which was twice as high as that observed after 4 cm + CPPU treatment. The 4 cm + TDZ treatment resulted in a 5.5% berry decay rate, which was the highest among all treatments. Alternatives to using a sulfur dioxide (SD) pad to maintain the quality of 'Shine Muscat' grapes, namely, using ethylene scrubbers (ESs, 3 g × 2 sachet) and alcohol releasers (ARs, 2 g × 2 sachet) in a 2 kg carton package for export, were explored in this study. The berry shatter rate with ES treatment (1.0%) was found to be comparable to that with SD treatment (0.6%) during three months of cold storage. Regarding the berry decay rate, that of the untreated control surged to 36.0% in the three months of storage, followed by 19.9% and 15.5% in samples subjected to AR and ES treatments respectively. Compared with the untreated control, the samples subjected to SD treatment showed a decay rate of 2.2%, which was the most effective in reducing berry decay by 95%. These results demonstrated that SD pad treatment of 'Shine Muscat' grapes was the most effective method of maintaining berry quality, and ES treatment partially reduced the berry shatter and berry decay rates.

Hot Corrosion Properties of Heat Resistant Chrome Steels (내열강의 고온부식특성에 대한 크롬함량의 영향)

  • Lee, Han-sang;Jung, Jine-sung;Yoo, Keun-bong;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.277-288
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    • 2010
  • The hot corrosion properties of heat-resistant steels were investigated in an oxidation atmosphere including artificial ash and sulfur dioxide. The heat-resistant steels of T22, T92, T122, T347HFG, Super304H and HR3C were evaluated at 620, 670 and $720^{\circ}C$ for 400 hours. The relationship between the corrosion rate and the temperature followed a bell-shaped curve with a peak rate at around $670^{\circ}C$. The corrosion rates showed a decreasing tendency as the chrome contents of these steels increased from 2.15 wt.% to 24.5 wt.%, and austenitic steels had a lower corrosion rate than ferritic steels. Sulfidation by $SO_2$ as well as molten salt corrosion also had an effect on the total corrosion rate, especially showing an increase in the corrosion rate in ferritic steels. Regardless of the chrome content in the steels and irrespective of the test temperature, the corrosion scale was composed of an outer oxide and an artificial ash mixed layer, a middle oxide layer and inner sulfide, and a mixed oxide layer. As the chrome content increased, the proportion of chrome oxide in the corrosion scale increased. Before spalling of the corrosion scale, voids and cracks were initiated in the sulfide and the mixed oxide layer or at the interface with the substrate.