• Title/Summary/Keyword: Sudden gelation

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A Study on the Initial Shear Strength Characteristics of Sudden Gelation Grout (순결형 그라우트의 초기 전단강도 특성에 대한 연구)

  • Heo, Hyung-Seok;Park, Inn-Joon
    • Journal of the Korean Geotechnical Society
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    • v.36 no.9
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    • pp.33-44
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    • 2020
  • In order to analyze the shear strength characteristics of the grout with sudden gelation in the pre-hardening state, the viscosity of the mixture and the indoor vane shear test were performed. The grout was prepared according to the water-cement (w/c) ratio and the shear strength test was conducted. The plastic-state shear strength of grout was affected by the w/c ratio, so the lower the w/c ratio, the higher the initial shear strength was, and the longer the curing time was, the higher the shear strength was. The maximum shear strength occurred at the faster rotation angle as the higher shear strength was developed, and the lower shear strength occurred at the larger rotation angle. In addition, it was confirmed that the pre-hardening grout rapidly decreased in strength after the maximum shear strength was gained, and converged at a certain level after the rotation angle of the vane blade was about 70° to 90°.

The effect of calcium concentration and temperature on the gelation of Aigeok Polysaccharide (Aigeok polysaccharide의 겔화에 미치는 칼슘농도와 온도의 효과)

  • Lee, Hyang-Aee;Kim, Keyng-Yi
    • Korean Journal of Food Science and Technology
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    • v.33 no.1
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    • pp.7-11
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    • 2001
  • The influence of temperature and calcium concentration on the gelation kinetics of purified Aigeok system has been investigated by small deformation oscillatory measurement. DE(degree of esterification) of the present sample was indicated of low methoxyl Aigeok polysaccharide by FT-IR. The calcium induced gelation of Aigeok has been studied. Both moduli reached the saturation value during the period of experiments. Rate constant increased with increasing calcium concentration, however above 4.08 mM calcium chloride caused a sudden drop in gel strength. The experimental result that the decrease in gel strength at high calcium concentration was seems to be phase separation or competitive inhibition between calcium ions. The storage and loss shear moduli decreased with increasing temperature. The rate constant of Aigeok system remarkably dropped above $35^{\circ}C$. Thus hydrogen bonding is prior to hydrophobic interaction for Aigeok molecule.

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