• Title/Summary/Keyword: Sub System

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Flame Retardant Properties of Cotton Fiber with Phosphoric/citric Acid Catalysts and TiO2 (인산/구연산 복합 산촉매 및 이산화티타늄을 적용한 면섬유의 난연 특성)

  • Yang, Heejin;Kim, Samsoo;Lee, Sangoh;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.238-249
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    • 2021
  • In this study, the effect on flame retardancy and various physical properties when TiO2 was added with a citric acid/phosphate complex acid catalyst together with Pyrovatex CP new (N-methylol dimethylphosphonopropionamide), a phosphorus-based flame retardant, was studied on cotton fibers. SEM-EDS analysis was performed to confirm the surface characteristics and surface element analysis of the flame-retardant treated cotton fibers, and a vertical carbonization test was performed to confirm the char formation capability and flame retardancy according to the phosphoric acid ratio. By comparing the LOI index before and after washing 10 times, the washing durability of the flame retardant solution containing the phosphoric acid catalyst and TiO2 was tested by LOI index after ten washing cycles. In addition, the influence of the flame-retardant processing on the physical properties were compared including thermogravimetric analysis (TGA), tear strength and whiteness.

Analytical study on seepage behavior of a small-scale capillary barrier system under lateral no-flow condition

  • Byeong-Su Kim
    • Geomechanics and Engineering
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    • v.35 no.1
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    • pp.13-27
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    • 2023
  • The model production for large-scale (lateral length ≥ 2.0 m) capillary barrier (CB) model tests is time and cost-intensive. To address these limitations, the framework of a small-scale CB (SSCB) model test under the lateral no-flow condition has been established. In this study, to validate the experimental methodology of the SSCB model test, a series of seepage analyses on the SSCB model test and engineered slopes in the same and additional test conditions was performed. First, the seepage behavior and diversion length (LD) of the CB system were investigated under three rainfall conditions. In the seepage analysis for the engineered slopes with different slope angles and sand layer thicknesses, the LD increased with the increase in the slope angle and sand layer thickness, although the increase rate of the LD with the sand layer thickness exhibited an upper limit. The LD values from the seepage analysis agreed well with the results estimated from the laboratory SSCB mode test. Therefore, it can be concluded that the experimental methodology of the SSCB model test is one of the promising alternatives to efficiently evaluate the water-shielding performance of the CB system for an engineered slope.

Influence of the CO2Concentration level on Sleep Quality (실내 CO2농도가 재실자의 수면의 질에 미치는 영향)

  • NA, LI;Han, Jin-kyu;Choi, Yoorim;Chun, Chung-yoon
    • Journal of Korean Living Environment System
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    • v.19 no.4
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    • pp.479-488
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    • 2012
  • This study investigated the influence of the indoor CO2concentration level on sleep quality by polysomnography(PSG). One healthy female subject was selected among several subjects based on RI(Risk Indicator) value and BMI(Body Mass Index) value to evaluate judging the risk level of obstructive sleep apnea hypopnea. To get the impact of the indoor carbon dioxide concentration to sleep quality, both CO2concentration levels were set up using ventilating form with 700~800 ppm and 2000~3000 ppm. Other environments were controlled in the comfortable sleep scope by previous researches. To measure the sleep quality, measurements have carried on polysomnography(PSG). In conclusion, it have shown that high carbon dioxide concentration leads arousal effect about central nervous system and to sustaining dreams and excited condition by bring about REM sleep split phenomenon.

Development of a High throughput Spectrometric Method for Determination of Vitamin C (비타민 C의 분석을 위한 고효율 분광분석법)

  • Kim, So Yeon;Suh, Yeoun Suk;Kim, Kyung Min;Kim, Young Ho;Jeon, Chi Wan;Choi, Jong Ha;Lee, Sang Hak
    • Applied Chemistry
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    • v.15 no.1
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    • pp.33-36
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    • 2011
  • A chemiluminescent method with gold nanoparticles for determination of vitamin C has been presented. Gold nanoparticles highly increased chemiluminescence intensity of lumimol-H2O2 system by its catalytic effect. The gold nanoparticles enhanced chemiluminescent method is applicable for the determination of an antioxidant such as vitamin C. When vitamin C was introduced to the lumimol system with gold nanoparticles, chemiluminescence intensity was reduced with the concentration of the added vitamin C. Low concentrated vitamin C solutions in the range of 1×10-3-1×10-9 M were produced reduced chemiluminescence intensity of lumimol-H2O2 with gold nanoparticles system.

Preparation of Flexible Terpolymers using Various Metallocene Catalyst/Borate Cocatalyst System and their Epoxidation

  • Kim, Jung Soo;Choi, Jun;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.54 no.4
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    • pp.286-293
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    • 2019
  • In this study, flexible poly(ethylene-ter-1-hexene-ter-divinylbenzene) was prepared using four types of metallocene catalysts (rac-Et(Ind)2ZrCl2, rac-SiMe2(Ind)2ZrCl2, rac-SiMe2(2-Me-Ind)2ZrCl2, (C5Me5)TiCl2[O-2,6-iPr2(C6H3)]) and two types of borate catalysts (trityl tetrakisborate and dimethylanilinium tetrakisborate). The yield, catalytic activity, molecular weight, structure, composition, and thermal properties of the terpolymers prepared using the various catalysts and cocatalyst systems were evaluated. Epoxidation of the terpolymers was successfully performed and this transformation was studied by 1H NMR and FTIR.

An Analysis of the Effects of Fine Dust Reduction Policies on PM10 Concentration and Health Using System Dynamics (시스템다이내믹스를 활용한 미세먼지 저감 정책이 미세먼지 농도와 건강에 미치는 영향 분석)

  • Seho Lee;Jung Eun Kang;Ji-Yoon Lee;Minyeong Park;Ji Yoon Choi
    • Journal of Environmental Impact Assessment
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    • v.32 no.5
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    • pp.318-337
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    • 2023
  • This study utilizes system dynamics to examine the effects of fine dust reduction policies on PM10 concentration and health. System dynamics has the advantage of modeling the dynamic and circular relationship between PM10 emission sources, reduction policies, PM10 concentration, and health effect. The study created policy scenarios for Korea's representative fine dust reduction policies - industrial PM10 emission control, diesel vehicle regulation, expansion of electric vehicles, and expansion of parks and green areas - and compared the results with the 2030 baseline if the current trend is maintained. The analysis showed that the policy of supporting electric vehicles reduced PM10 concentration by 0.21 ㎍/m3 and reduced the number of people with circulatory diseases by 494, and the effect was evenly distributed across the country. The industrial emissions regulation scenario resulted in the highest PM10 concentration reduction of 0.22 ㎍/m3, but had a lower reduction in the number of people affected (358) than the EV support strategy, which could be attributed to the fact that this policy had a particularly high PM10 reduction effect in industrial areas such as Danyang-gun, Chungcheongbuk-do, and Sahagu, Busan. As a policy implication, this study suggests that it is necessary to apply fine dust policies tailored to the characteristics of local emission sources.

Rod effects on transferred energy into SPT sampler using smart measurement system

  • Park, Geunwoo;Kim, Namsun;Hong, Won-Taek;Lee, Jong-Sub
    • Smart Structures and Systems
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    • v.30 no.2
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    • pp.159-172
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    • 2022
  • To improve the accuracy of the standard penetration test (SPT) results, smart measurement system, which considers the energy transfer ratio into the sampler (ETRSampler), is required. The objective of this study is to evaluate the effects of joints and rod length on the transferred energy into the sampler. The energy transfer ratios into the rod head (ETRHead) and ETRSampler, and the energy ratio from the head to the sampler (ERHS) were obtained using energy modules, which were installed at the rod head and above the SPT sampler. Linear regression analyses are conducted to correlate the ERHS with the number of joints, rod length, and SPT N-values. In addition, the dynamic resistances are calculated using both transferred energies into the rod head and into the sampler, and are compared with the corrected cone tip resistance measured from the cone penetration test (CPT). While the ETRHead are generally constant, but the ETRSampler and ERHS gradually decrease along the depth or the number of joints, except at certain depths with high SPT N-values. Thus, the ERHS can be estimated using the number of joints, rod length, and SPT N-values. The dynamic resistance evaluated by ESampler produces a better correlation with the corrected cone tip resistance than that by EHead. This study suggests that transferred energy into the SPT sampler may be effectively used for more accurate subsurface characterization.

Synthesis and Luminescent Characteristics of Sr4Al14O25 Phosphor (Sr4Al14O25 형광체의 합성과 발광특성)

  • Han Sang Hyuk;Kim Young Jin
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.529-534
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    • 2004
  • $Sr_{4}Al_{14}O_{25}$ was synthesized by solid state reaction with flux. $H_{3}BO_3$ was used to synthesize $SrO-Al_{2}O_{3}$ phosphor system as a flux. The effect of doping system such as Eu+Dy, Eu, and Ce on the luminescent properties of $Sr_{4}Al_{14}O_{25}$ was investigated. Both PL spectra of $Sr_{4}Al_{14}O_{25}$:Eu and $Sr_{4}Al_{14}O_{25}$:Eu+Dy excited at 390 nm showed greenish-blue emission at about 490 nm, while the emission wavelength was shifted to 400 nm by doping Ce. The reduction of $Eu^{3+}$ ions to $Eu^{2+}$ could be accomplished by the annealing process under $N_{2}^{+}$ vacuum atmosphere, and attributed to the emission at 490 nm. It is verified that $Sr_{4}Al_{14}O_{25}$:Eu phosphor is suitable for white LEDs became of a broad absorption band peaking at 390 nm.

Synthesis and Thermal Analysis of Mullite Whiskers in Al(OH)3-SiO2-AIF3 System (Al(OH)3-SiO2-AIF3계에서 뮬라이트 휘스커 합성과 열분석)

  • Lee Hong-rim;Lee Young-Woo;Lee Jung-Won;Kang Jong-Bong
    • Korean Journal of Materials Research
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    • v.15 no.10
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    • pp.644-651
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    • 2005
  • The thermal analysis of $Al(OH)_3-SiO_2-AIF_3$ system was done. The thermal behaviors of components and the effect of moisture on the formation of mullite were investigated via TG-DTA and XRD analysis. The mixture of $Al(OH)_3,\;SiO_2,\;AIF_3$showed two endothermic peaks with drastic weight loss and one exothermic peak. Fluorotopaz was formed at $800^{\circ}C$ and turned into mullite completely at $1100^{\circ}C$. But the mixture $Al_2O_3$ of or dehydrated $Al(OH)_3$ and $SiO_2$ could not form mullite even at $1200^{\circ}C$ in which the crystalline phases were $\alpha-Al_2O_3$ ana cristobalite. It was found that the synthesized mullite was aciculate shaped single crystalline whisker.

Dielectric and Piezoelectric Characteristics of Low Temperature Sintering PbTiO3 System Ceramics with amount of Bi2O3 Addition (Bi2O3 첨가량에 따른 저온소결 PbTiO3계 세라믹스의 유전 및 압전특성)

  • Yoo, Ju-Hyun;Kim, Do-Hyung;Lee, Sang-Ho;Sohn, Eun-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.771-775
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    • 2007
  • In this study, in order to develop low temperature sintering ceramics for thickness vibration mode multilayer piezoelectric transformer, $PbTiO_3$ system ceramics were fabricated using $Na_2CO_3,\;Li_2CO_3,\;MnO_2\;and\;Bi_2O_3$ as sintering aids and their dielectric and piezoeletric properties were investigated according to the amount of $Bi_2O_3$ addition. At the sintering temperature of $900^{\circ}C\;and\;Bi_2O_3$ addition of 0.1 wt%, density, grain size, thickness vibration mode eletromechanical coupling factor($k_t$), thickness vibration mode mechanical quality factor($Q_{mt}$) and dielecteic constant(${\varepsilon}_r$) showed the optimum value of $6.94g/cm^3,\;2.413{\mu}m$, 0.497, 3,162 and 209, respectively, for thickness vibration mode multilayer piezoelectric transformer application.