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Electrocatalytic properties of Nd1.5Ba1.5CoFeMnOx for water splitting (수전해용 Nd1.5Ba1.5CoFeMnOx 전기촉매 특성 분석)

  • Lee, Ho Jun;Cho, Kyungwon;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.1
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    • pp.17-20
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    • 2020
  • Developing effective and earth-abundant electrocatalyst for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is critical for the commercialization of a water splitting system. In particular, the overpotential of the OER is relatively higher than the HER, and thus, it is considered that one of the important methods to enhance the performance of the electrocatalyst is to reduce the overpotential of the OER. In this work, we present a simple synthetic route for triple perovskite Nd1.5Ba1.5CoFeMnOx with high performance OER and HER activity. This triple perovskite structure which shows high crystallinity through combustion method shows superior bifunctional catalytic performance in alkaline media. We believe that the prepared triple provskite with high performance OER and HER activity can give further feasibility for the commercialization of a water splitting system.

Scavenging Efficiency Based on Long-Term Characteristics of Precipitation and Particulate Matters in Seoul, Korea (서울지역 장기간 강수와 미세먼지의 특성 분석에 기반한 미세먼지 세정효과)

  • Suji Han;Junshik Um
    • Atmosphere
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    • v.33 no.4
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    • pp.367-385
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    • 2023
  • The variabilities of precipitation and particulate matters (i.e., PM10 and PM2.5) and the scavenging efficiency of PMs by precipitation were quantified using long-term measurements in Seoul, Korea. The 21 years (2001~2021) measurements of precipitation and PM10 mass concentrations, and the 7 years (2015~2021) of PM2.5 mass concentrations were used. Statistical analysis was performed for each period (i.e., year, season, and month) to identify the long-term variabilities of PMs and precipitation. PM10 and PM2.5 decreased annually and the decreasing rate of PM10 was greater than PM2.5. The precipitation intensity did not show notable variation, whereas the annual precipitation amount showed a decreasing trend. The summer precipitation amount contributed 61.10% to the annual precipitation amount. The scavenging efficiency by precipitation was analyzed based on precipitation events separated by 2-hour time intervals between hourly precipitation data for 7 years. The scavenging efficiencies of PM10 and PM2.5 were quantified as a function of precipitation characteristics (i.e., precipitation intensity, amount, and duration). The calculated average scavenging efficiency of PM10 (PM2.5) was 39.59% (35.51%). PM10 and PM2.5 were not always simultaneously scavenged due to precipitation events. Precipitation events that simultaneously scavenged PM10 and PM2.5 contributed 42.24% of all events, with average scavenging efficiency of 42.93% and 43.39%. The precipitation characteristics (i.e., precipitation intensity, precipitation amount, and precipitation duration) quantified in these events were 2.42 mm hr-1, 15.44 mm, and 5.51 hours. This result corresponds to 145% (349%; 224%) of precipitation intensity (amount; duration) for the precipitation events that do not simultaneously scavenge PM10 and PM2.5.

A Study on the downconverter Using Sub-Harmonic Mixer for Point to Point System Applications (Sub-Harmonic 혼합기를 이용한 점대점 시스템용 하향 변환기에 관한 연구)

  • Min Jun-Ki;Kim Hyun-Jin;Kim Yong-Hwan;Yoo Hyung-Soo;Yun Ho-Seok;Lee Keun-Tae;Hong Ui-Seok
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.10A
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    • pp.958-964
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    • 2005
  • In this thesis, the matching network at the local oscillator port of the sub-harmonic mixer is optimized for reducing the conversion loss. A downconverter for point to point system applications is designed and fabricated using the such sub-harmonic mixer. The sub-harmonic mixer achieved the conversion loss of 11.8 dB at the 12 dBm input power of the local oscillator and the isolation of less than -40 dB. The downconverter achieved the IF output power flatness of 2 dB and the total noise figure of 5.9 dB.

Electrical Characteristics of Piezoelectric Transformer Composition Pb(Sb1/2Nb1/2)-Pb(Ni1/3Nb2/3)O3-Pb(Zr1Ti)O3 Ceramics for Adaptor (Adaptor용 압전트랜스포머조성 Pb(Sb1/2Nb1/2)-Pb(Ni1/3Nb2/3)O3-Pb(Zr1Ti)O3세라믹스의 전기적 특성)

  • 윤광희;오동언;류주현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.6
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    • pp.499-503
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    • 2002
  • In this study, to develop the high power piezoelectric transformer for adaptor, PSN-PNN-PZT system ceramics were formulated as a function of $MnO_2$ addition and its dielectric and piezoelectric characteristics were investigated. Multi-layer piezoelectric transformer using an excellent composition was also fabricated and its electrical properties evaluated. The composition ceramics added to 0.5wt%$MnO_2$ showed the maximum value of $k_p=0.61$ and $Q_m=1.321$. As the output power of piezoelectric transformer is increased, its temperature rise increased. At the fixed 18W output power, the transformer was stably operated.

Piezoelectric Characteristics of Low temperature Sintering Pb0.76Ca0.24[(Mn1/3Sb2/3)0.04Ti0.96]O3 Ceramics With the Variation of Poling Field (저온소결 Pb0.76Ca0.24[(Mn1/3Sb2/3)0.04Ti0.96]O3 세라믹스의 분극전계에 따른 압전특성)

  • Chung Kwang-Hyun;Yoo Kyung-Jin;Yoo Ju-Hyun;Cho Bong-Hee;Yoon Hyun-Sang;Paik Dong-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.228-232
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    • 2006
  • In this paper, in order to develop low temperature sintering $PbTiO_3$-system piezoelectric ceramics for thickness-vibration-mode piezoelectric transformer, $Pb_{0.76}Ca_{0.24}[(Mn_{1/3}Sb_{2/3})_{0.04}Ti_{0.96}]O_3$ ceramics using $0.25\;wt\%\;CaCO_3$ and $0.2\;wt\%\;Li_{2}CO_3$ as sintering aids were manufactured according to the variation of poling field. The specimens could be sintered at $930\;^{\circ}C$. The piezoelectric properties were investigated according to the poling field. The maximum properties showed at the field of 6.5 kV/mm, which had kt of 0.49, Qmt of 1816, and $d_{33}$ of 81.4 pC/N.

A Comparative Study of the Degradation of the Erionyl Navy R by Different Oxidation Processes: Chemical, Fenton and Fenton-like

  • Belaid, Kumar Djamal;Elhorri, Abdelkader M.;Mered, Yassine;Hichem, Ellali
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.419-424
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    • 2022
  • The oxidative degradation performance of the Erionyl Navy R dye was studied in this article. The investigation mainly focused on a comparative study between chemical oxidations by sodium hypochlorite (NaClO) and hydrogen peroxide (H2O2), and catalytic oxidations including the Fenton (Fe2+-H2O2) and Fenton-Like (Fe2+/ Fe3+/Co2+/ Mn2+-H2O2) or modified Fenton-like (Fe2+/ Fe3+ -NaClO) reactions. A discoloration and degradation of the Erionyl Navy R occurred after 30 minutes, which varies according to the oxidation system involved; 31%, 54%, <20%, 95%, and >96% losses were observed for Co2+-H2O2, Mn2+-H2O2, Fe2+-NaClO, Fe3+-NaClO), and Fe2+-H2O2 and Fe3+-H2O2, respectively.

Phase Behavior Study of Fatty Acid Potassium Cream Soaps (지방산 칼륨 Cream Soaps 의 상거동 연구)

  • Noh, Min Joo;Yeo, Hye Lim;Lee, Ji Hyun;Park, Myeong Sam;Lee, Jun Bae;Yoon, Moung Seok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.1
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    • pp.55-64
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    • 2022
  • The potassium cream soap with fatty acid called cleaning foam has a crystal gel structure, and unlike an emulsion system, it is weak to shear stress and shows characteristics that are easily separated under high temperature storage conditions. The crystal gel structure of cleansing foams is significantly influenced by the nature and proportion of fatty acids, degree of neutralization, and the nature and proportion of polyols. In order to investigate the effect of these parameters on the crystal gel structure, a ternary system consisting of water/KOH/fatty acid was investigated in this study. The investigation of differential scanning calorimeter (DSC) revealed that the eutectic point was found at the ratio of myristic acid (MA) : stearic acid (SA) = 3 : 1 and ternary systems were the most stable at the eutectic point. However, the increase in fatty acid content had little effect on stability. On the basis of viscosity and polarized optical microscopy (POM) measurements, the optimum degree of neutralization was found to be about 75%. The system was stable when the melting point (Tm) of the ternary system was higher than the storage temperature and the crystal phase was transferred to lamellar gel phase, but the increase in fatty acid content had little effect on stability. The addition of polyols to the ternary system played an important role in changing the Tm and causing phase transition. The structure of the cleansing foams were confirmed through cryogenic scanning electron microscope (Cryo-SEM), small and wide angle X-ray scattering (SAXS and WAXS) analysis. Since butylene glycol (BG), propylene glycol (PG), and dipropylene glycol (DPG) lowered the Tm and hindered the lamellar gel formation, they were unsuitable for the formation of stable cleansing foam. In contrast, glycerin, PEG-400, and sorbitol increased the Tm, and facilitated the formation of lamellar gel phase, which led to a stable ternary system. Glycerin was found to be the most optimal agent to prepare a cleansing foam with enhanced stability.

Transmission Electron Microscopy Sample Preparation of Ge2Sb2Te5 Nanowire Using Electron Beam

  • Lee, Hee-Sun;Lee, Jun-Young;Yeo, Jong-Souk
    • Applied Microscopy
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    • v.45 no.4
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    • pp.199-202
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    • 2015
  • A simple and novel transmission electron microscopy (TEM) sample preparation method for phase change nanowire is investigated. A $Ge_2Sb_2Te_5$ (GST) nanowire TEM sample was meticulously prepared using nanomanipulator and gas injection system in a field emission scanning electron microscopy for efficient and accurate TEM analysis. The process can minimize the damage during the TEM sample preparation of the nanowires, thus enabling the crystallographic analysis of as-grown GST nanowires without unexpected phase transition caused by e-beam heating.

A time dependent thermal and solutal convection problem in physical vapor transport of Hg2Cl2-I2 system

  • Kim, Geug Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.2
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    • pp.80-88
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    • 2017
  • In this research a time dependent thermal and solutal convection was computationally investigated for the physical vapor transport of the mixture of $Hg_2Cl_2-I_2$ system with for the convective regime from thermal Rayleigh number of $2.16{\times}10^6$ up to $1.7{\times}10^7$ with marching time to a steady state problem. With time marching, the convective cells are decreased for the thermal Rayleigh number of $2.16{\times}10^6$, and increased for the thermal Rayleigh number of $1.7{\times}10^7$. The convective flow structures are found to be essentially time independent on the horizontal orientation of the enclosure with respect to the gravity vector, and on the other hand, time dependent on the vertical orientation of the enclosure with respect to the gravity vector.

Energy Efficiency and CO2 Emissions of the Transportation System of Kazakhstan: A Case of Almaty

  • Yessekina, Aiman;Urpekova, Amina
    • The Journal of Asian Finance, Economics and Business
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    • v.2 no.3
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    • pp.41-46
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    • 2015
  • Energy saving in the transport sector in the framework of the annual growth of energy consumption, the degree of negative impact on the environment and the amount of harmful emissions are becoming increasingly important. The article considers the world tendencies of energy consumption in transportation sector and emphasizes its dependency from oil. Also article describes the dynamics of energy use and CO2 emissions from transport of city Almaty. In conclusion authors identify a number of problems in the transport sector, which hinder the implementation of energy efficiency measures and measures to reduce CO2 emissions.