• 제목/요약/키워드: Structure and spectral properties

검색결과 138건 처리시간 0.021초

Isolation and Properties of Antitumor Antibiotic YS-1649 from Penicillium sp. strain 1649

  • BOO-kIL PARK;YOO, SEONG-JAE
    • Journal of Microbiology and Biotechnology
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    • 제5권1호
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    • pp.31-35
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    • 1995
  • An antitumor antibiotic named YS-1649 was isolated from the culture filtrate of a newly isolated fungus identified as Penicillium sp.. The fermentation yield reached about 40 mg per liter of the broth. YS-1649, a $\gamma$-Iactone - structured antibiotic, has the molecular fomular of $C_7H_6O_4$, Its structure was determined to be patulin by spectral analysis. It is active against some bacteria and showed cytotoxic effect on the proliferation of human breast cancer cell line, MCF-7, at concentrations of more than 0.048 $mu g/ml$. This compound also showed strong cytotoxic effect on the proliferation of human cancer cell lines, A549 and ACHN.

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Study on the Fabrication and Characterization of Red-Light-Emitting Organic Electroluminescent Devices Using Europium Complexes

  • Lee, Sang-Pil;Choi, Don-Soo;Lee, Seung-Hee;Zyung, Tae-Hyung;Kim, Young-Kwan;Kim, Jung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.211-212
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    • 2000
  • Organic electroluminescent devices (OELDs) have received a great deal of attention due to their potential application as full-color displays. Europium complexes are known as excellent red light-emitting materials for OELDs since they show intense photoluminescence at around 612 nm with a narrow spectral bandwidth. In this study, a novel europium complex, $Eu(TTA)_3(TPPO)$ was synthesized and its photoluminescent and electroluminescent characteristics were investigated with a device structure of ITO/TPD/$Eu(TTA)_3(TPPO)$/ $Alq_3$/Al, where sharp emission at the wavelength of 615 nm has been observed. Details on the electrical properties of these structures was also discussed.

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무당개구리의 복피 Carotenoid 색소에 관한 연구 (제3보). 3-Hydroxy-canthaxanthin의 분리 및 확인 (Studies on the Carotenoid Pigment in Abdominal Skin of Bombina Orientalis (Ⅲ). Occurrence of 3-Hydroxy-canthaxanthin in the Abdominal Skin of Bombina Orientalis)

  • 장세희;정의준;최일영
    • 대한화학회지
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    • 제19권1호
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    • pp.34-37
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    • 1975
  • 무당개구리의 복피 색소로 부터 작자색 침상결정인 3-hydroxy-anthaxanthin을 분리하였다. Visible과 IR 스펙트럼의 특성, 크로마토그래피적 성질 및 물리화학적 성질을 이용하여 그의 구조를 확인하였다.

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철도교량 기초지반의 내진성능평가 (Performance Evaluation of Railroad Bridge Foundation under Design Earthquake)

  • 황선근;이진욱;조성호;오상덕
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2002년도 춘계학술대회 논문집
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    • pp.165-170
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    • 2002
  • At the present time, civil structure based of aseismatic design in the Korea began about 1997. However, most of the railway bridge constructed with block and block in the past can easily deteriorate with time due to the increase of repeated traffic loading, increase of train speed, etc. In this study, soil properties of the substructure of railway bridge with block and block was investigated through the SASW(spectral Analysis or Surface Waves) and RCTC test in the field and laboratories. Also, stabilization of liquefaction after occurred earthquake was investigated through the Seed & Idress method use of N value and Andrus and Stoke method use of S-Wave velocity.

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Cluster ing for Analysis of Raman Hyper spectral Dental Data

  • Jung, Sung-Hwan
    • 한국멀티미디어학회논문지
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    • 제16권1호
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    • pp.19-28
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    • 2013
  • In this research, we presented an effective clustering method based on ICA for the analysis of huge Raman hyperspectral dental data. The hyperspectral dataset captured by HR800 micro Raman spectrometer at UMKC-CRISP(University of Missouri-Kansas City Center for Research on Interfacial Structure and Properties), has 569 local points. Each point has 1,005 hyperspectal dentin data. We compared the clustering effectiveness and the clustering time for the case of using all dataset directly and the cases of using the scores after PCA and ICA. As the result of experiment, the cases of using the scores after PCA and ICA showed, not only more detailed internal dentin information in the aspect of medical analysis, but also about 7~19 times much shorter processing times for clustering. ICA based approach also presented better performance than that of PCA, in terms of the detailed internal information of dentin and the clustering time. Therefore, we could confirm the effectiveness of ICA for the analysis of Raman hyperspectral dental data.

후향계단 주위의 난류 박리재부착유동에서의 벽압력변동의 통계적 특징 (Cross-Spectral Characteristics of Wall Pressure Fluctuations in Flows over a Backward-Facing Step)

  • 이인원;성형진
    • 대한기계학회논문집B
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    • 제24권2호
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    • pp.280-287
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    • 2000
  • Laboratory measurements were made of wall pressure fluctuations in a separated and reattaching flow over a backward-facing step. An array of 32 microphones along the streamwise direction was utilized. Various statistical properties of pressure fluctuations were scrutinized. The main emphasis was placed on the flow inhomogeneity along the streamwise direction. One point statistics such as the streamwise distribution of rms pressure and autospectra were shown to be generally consistent with other studies. The coherences and wavenumber spectra in the streamwise directions were indicative of the presence of dual modes in pressure; one is the large-scale vortical structure in low frequency and the other is the boundary-layer-like decaying mode in high frequency.

CHANDRA SPECTROSCOPY OF SUPERNOVA REMNANT 3C 391

  • CHEN YANG;SU YANG;SLANE PATRICK O.;WANG Q. DANIEL
    • 천문학회지
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    • 제38권2호
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    • pp.211-214
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    • 2005
  • We performed a spatially resolved spectroscopic study of the thermal composite supernova remnant 3C 391 by the Chandra observation. Broad- and narrow-band X-ray images show a southeast-northwest elongated morphology and unveil a highly clumpy structure of the remnant. The spectral analysis for. the small-scale features indicates normal metal abundance and uniform temperature for the interior gas. The properties of the hot gas are largely in agreement with the cloudlet evaporation model as a main mechanism for the 'thermal composite' X-ray appearance, though radiative rim and thermal conduction may also be effective. An unresolved X-ray source, with a power-law spectrum, is observed on the northwest border. The equivalent width images reveal a faint finger-like protrusion in Si and S lines out of the southwest radio border.

Design, Synthesis and Biological Activity of Certain 3,4-Disubstituted-5-mercapto-1,2,4-triazoles and Their Hydrazino Derivatives

  • Udupi, R.H.;Sudheendra, Sudheendra;Bheemachari, Bheemachari;Srinivasulu, N.;Varnekar, Rajesh;Purushottamachar, Puranik
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2235-2240
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    • 2007
  • 3-Aryloxy methyl-4-(N-pyrazin-2'yl carboxamido)-5-mercapto-1,2,4-triazoles (3a1-a14) were prepared starting from potassium dithio carbazinates (2a1-a14). These triazoles were then employed in the synthesis of 3-aryloxy methyl-4-(N-pyrazin-2'yl carboxamido)-5-hydrazino-1,2,4-triazoles (4a1-a14). All the newly synthesized compounds were characterized by analytical, IR, NMR spectral studies. The compounds were screened for their antibacterial, antifungal, anti-inflammatory and analgesic properties. Most of the compounds have shown significant antifungal activity while few have shown excellent anti-inflammatory and analgesic activity. An attempt is made to study the structure activity relationship (SAR).

Mössbauer Study of Two Discernable Fe Sites in CaFe2O4

  • Yoon, Sung-Hyun
    • Journal of Magnetics
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    • 제14권2호
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    • pp.86-89
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    • 2009
  • Structural and magnetic properties of polycrystalline $CaFe_2O_4$ prepared by the solid state reaction method were studied using powder X-ray diffraction (XRD) and $M{\ddot{o}}ssbauer$ spectroscopy. The structure of $CaFe_2O_4$ belongs to an orthorhombic system (space group: Pnma) with the lattice parameters $a=9.2373\;{\AA}$, $b=3.0237\;{\AA}$, and $c=10.7124\;{\AA}$. Results of structural refinement indicate, however, that there are two slightly different iron sites in the sample. The $M{\ddot{o}}ssbauer$ spectrum at 4.2 K shows a hyperfine sextet with a hyperfine magnetic field and an isomer shift of 47.3 T and 0.36 mm/s, respectively. An examination of the spectrum revealed that the line widths of the spectral lines were not uniform. The degree of asymmetric line broadening decreases with increasing temperature, suggesting that the difference in the degree of crystalline distortions between two $FeO_6$ octahedra is eliminated as the temperature rises.

Kinetics of the Zn(Ⅱ)-Catalyzed Hydrolysis of 2-Acetylpyridineketoximyl Diphenyl Phosphate

  • 서정훈;김경일
    • Bulletin of the Korean Chemical Society
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    • 제6권4호
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    • pp.230-233
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    • 1985
  • Kinetic data of the Zn(Ⅱ) ion-catalyzed hydrolysis of 2-acetylpyridineketoximyl acetate (S) are measured. The reaction proceeds through the accumulation of an intermediate (I). 2-Acetylpyridineketoxime (Ox) is released in the breakdown step of I. Phenol is not formed as a part of the products, and, therefore, diphenyl phosphate and Ox are produced by the breakdown of I. Based on the dependence of the rates for the formation and the breakdown of I on [Zn(Ⅱ)] and pH, and considering the UV spectral properties of I, the structure of I is tentatively assigned as the penta-covalent intermediate formed by the addition of a water molecule to S.