• Title/Summary/Keyword: Structure Stability

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Thermal Performance Evaluation of Composite Phase Change Material Developed Through Sol-Gel Process (졸겔공법을 이용한 복합상변화물질의 열성능 평가)

  • Jin, Xinghan;Haider, Muhammad Zeeshan;Park, Min-Woo;Hu, Jong-Wan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.5
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    • pp.555-566
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    • 2023
  • In this study, a composite phase change material (CPCM) produced using the SOL-GEL technique was developed as a thermal energy storage medium for low-temperature applications. Tetradecane and activated carbon (AC) were used as the core and supporting materials, respectively. The tetradecane phase change material (PCM) was impregnated into the porous structure of AC using the vacuum impregnation method, and a thin layer of silica gel was coated on the prepared composite using the SOL-GEL process, where tetraethyl orthosilicate (TEOS) was used as the silica source. The thermal performance of the CPCM was analysed using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). DSC results showed that the pure tetradecane PCM had melting and freezing temperatures of 6.4℃ and 1.3℃ and corresponding enthalpies 226 J/g and 223.8 J/g, respectively. The CPCM exhibited enthalpy of 32.98 J/g and 27.7 J/g during the melting and freezing processes at 7.1℃ and 2.4℃, respectively. TGA test results revealed that the AC is thermally stable up to 500℃, which is much higher than the decomposition temperature of the pure tetradecane, which is around 120℃. Moreover, in the case of AC-PCM and CPCM thermal degradation started at 80℃ and 100℃, respectively. The chemical stability of the CPCM was studied using Fourier-transform infrared (FT-IR) spectroscopy, and the results confirmed that the developed composite is chemically stable. Finally, the surface morphology of the AC and CPCM was analysed using scanning electron microscopy (SEM), which confirmed the presence of a thin layer of silica gel on the AC surface after the SOL-GEL process.

“Aluminium Nitride Technology-a review of problems and potential"

  • Dryburgh, Peter M.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.75-87
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    • 1996
  • This review is presented under the following headings: 1.Introduction 1.1 Brief review of the properties of AlN 1.2 Historical survey of work on ceramic and single crystal AlN 2.Thermochemical background 3.Crystal growth 4.Doping 5.Potential applications and future work The known properties of AlN which make it of interest for various are discussed briefly. The properties include chemical stability, crystal structure and lattice constants, refractive indices and other optical properties, dielectric constant, surface acoustic wave velocity and thermal conductivity. The history of work in single crystals, thin films and ceramics are outlined and the thermochemistry of AlN reviewed together with some of the relevant properties of aluminium and nitrogen; the problems encountered in growing crystals of AlN are shown to arise directly from these thermochemical relationships. Methods have been reported in the literature for growing AlN crystals from melts, solution and vapour and these methods are compared critically. It is proposed that the only practicable approach to the growth of AlN is by vapour phase methods. All vapour based procedures share the share the same problems: $.$the difficulty of preventing contamination by oxygen & carbon $.$the high bond energy of molecular nitrogen $.$the refractory nature of AlN (melting point~3073K at 100ats.) $.$the high reactivity of Al at high temperatures It is shown that the growth of epitactic layers and polycrystalline layers present additional problems: $.$chemical incompatibility of substrates $.$crystallographic mismatch of substrates $.$thermal mismatch of substrates The result of all these problems is that there is no good substrate material for the growth of AlN layers. Organometallic precursors which contain an Al-N bond have been used recently to deposit AlN layers but organometallic precursors gave the disadvantage of giving significant carbon contamination. Organometallic precursors which contain an Al-N bound have been used recently to deposit AlN layers but organometallic precursors have the disadvantage of giving significant carbon contamination. It is conclude that progress in the application of AlN to optical and electronic devices will be made only if considerable effort is devoted to the growth of larges, pure (and particularly, oxygen-free) crystals. Progress in applications of epi-layers and ceramic AlN would almost certainly be assisted also by the availability of more reliable data on the pure material. The essential features of any stategy for the growth of AlN from the vapour are outlined and discussed.

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Analysis of electrical resistivity characteristics according to the mixing ratio of coarse fillings in artificial rock joint (인공 암반절리의 조립토 충진물 혼합비에 따른 전기비저항 특성 분석)

  • Haeju Do;Tae-Min Oh;Hangbok Lee
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.25 no.2
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    • pp.141-155
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    • 2023
  • Monitoring technology based on electrical resistivity is widely used for non-destructive data collection and health analysis of underground structures and tunnels. Vulnerable sections such as fault zone generates many problems during construction of the tunnel. These problems cause displacement and stress changes of the ground. Therefore, it is necessary to predict the state of the fault zone section to ensure the mechanical stability of the underground structure. Monitoring the size of joints and the porosity of the fillings is essential for rocks. Previous studies have not considered the variety of fillings in rock joints. In this study, electrical resistivity tests were conducted according to the particle mixing state of the sandy fillings. When the size of fillings is decreased at the constant porosity, the electrical resistivity tends to increase. The results of this study are expected to be useful as basic electrical resistivity data for predicting the ground conditions and evaluation of the ground behavior that is containing sandy fillings in the rock joint for tunnels.

Study on Skin Permeation of Tocopheryl Acetate Using Swollen Micelle (Swollen Micelle을 이용한 Tocopheryl Acetate 의 피부흡수 연구)

  • Su-Bin Son;Kyung-Sup Yoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.1
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    • pp.17-27
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    • 2023
  • A study was performed to increase skin permeation of tocopheryl acetate, an oil-soluble component among tocopheryl acetate, salicylic acid, and niacinamide, which are the active ingredients of the anti-hair loss toner. As a method of transparently solubilizing tocopheryl acetate while containing salicyl acid and niacinamide, we used a swollen micelle structure that increased the size of the micelle formed by the aggregation of surfactants. The prepared swollen micelle solution contains three kinds of active ingredients, and poloxamer 407 and octyldodeceth-16 were used as surfactants to increase transparent properties and stability. In addition, isostearic acid was used as a co-surfactant to increase the size of micelles. To evaluate the physical properties of the prepared swollen micelles, turbidity at room temperature (25 ℃) was measured. The Franz diffusion cell method was used to evaluate the skin permeation rate of tocopheryl acetate among the hair-loss prevention components contained in swollen micelles. After 24 h, tocopheryl acetate showed a 6-fold improvement in skin permeation compared to the control group. Therefore, it can be seen that the swollen micelles developed in this study can be applied to hair-loss prevention products or solubilized formulations of various functional cosmetics.

Evaluation Model for Lateral Flow on Soft Ground Using Commitee and Probabilistic Neural Network Theory (군집신경망과 확률신경망 이론을 이용한 연약지반의 측방유동 평가 모델)

  • Kim, Young-Sang;Joo, No-Ah;Lee, Jeong-Jae
    • Journal of the Korean Geotechnical Society
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    • v.23 no.7
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    • pp.65-76
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    • 2007
  • Recently, there have been many construction projects on soft ground with growth of industry and various construction problems concerning soft soil behavior also have been reported. Especially, foundation piles of abutments and (or) buildings which were constructed on the soft ground have been suffering from a lot of stability problems of inordinary displacement due to lateral flow of soft ground. Although many researches for this phenomena have been carried out, it is still difficult to assess the mechanism of lateral flow on soft ground quantitatively. And reliable design method for judgement of lateral flow occurrence is not established yet. In this study, PNN (probabilistic neural network) and CNN (committee neural network) theories were applied for judgment of lateral flow occurrence based on eat data compiled from Korea and Japan. Predictions of PNN and CNN models for new data which were not used during model development are compared with those predicted by conventional empirical methods. It was found that the developed PNN and CNN models can predict more precise and reliable judgment of lateral flow occurrence than conventional empirical methods.

A Experimental Study on the Ready-mixed Shotcrete Using Granulated Blast Furnace Slag (고로슬래그 미분말을 혼입한 레디믹스트 숏크리트의 현장적용성에 관한 실험적 연구)

  • Choi, Hee-Sup;Kim, Dong-Min;Jang, Pil-Sung;Seo, Sin-Seuk
    • Journal of the Korean Geotechnical Society
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    • v.25 no.6
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    • pp.31-45
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    • 2009
  • The aim of this study is to evaluate the applicability of Granulated Blast Furnace Slag to the development of the Powdered Ready-mixed Shotcrete. First of all, after accomplishing SEM analysis and Leaching Test, the laboratory and field experiments for evaluating the utility of Granulated Blast Furnace Slag were performed. As a result of SEM and Leaching test, the environmental stability was confirmed. That is, non-detection of harmful lists and dense shotcrete structure result from mixing Granulated Blast Furnace Slag. As a result of lab. and field test, Blast Furnace Slag is superior to Plain Batch in improving strength and durability. And it will be able to improve to some extent the problem caused by the delayed reaction of existing Granulated Blast Furnace Slag with alkali activated material. Also the proper amount of Granulated Blast Furnace Slag is estimated to be under 30%. Finally, it is possible that Granulated Blast Furnace Slag can apply to economical recycling and development of the Ready-mixed Shotcrete for its price is only about 5% of Silica-finne's price.

On the Evolution of Hong Kong's Nativism and Its Public Law Solutions (论香港本土主义的流变及其公法应对)

  • Man, Lai Pui;Yinhao, Tan
    • Analyses & Alternatives
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    • v.3 no.1
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    • pp.93-133
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    • 2019
  • Throughout history, there are three clues of dualistic structures for the development of Hong Kong's nativism. First, inward attribution and outward lookingare two paths to the formation of Hong Kong's nativism. In the dualistic framework of "self-others", nativism is formed. The formation path of "outward looking"can be seen everywhere in the construction history of Hong Kong's nativism. It is under the reflection of "two mirrors" with Britain and Chinese mainland that Hong Kong people acquire the concept of "Hong Kong's nativism". Second, there are two aspects of Hong Kong's nativism: economic and cultural aspect and political aspect. With the gradual development of Hong Kong's history, these two aspects come into being and are closely bound up, thus constituting Hong Kong's nativism today. The third clue is the most critical one. The subjectivity of colonization and decolonization are two different forms of Hong Kong people's subjectivity. These three clues run through the whole process of the construction of Hong Kong nativism, and are carried out in three stages of development: "Origin (1960s-1970s): Preliminary Construction of Hong Kong's Nativism", "Development of Hong Kong's Nativism (1980s-1997): Awakening of Political Aspect" and "Formation and Alienation of Hong Kong's Nativism (1997-present): Deformed "decolonization". Along the evolution of Hong Kong's nativism, with the disintegration of colonialism, Hong Kong people have gradually transited from the subjectivity of colonization to the subjectivity of decolonization, but the process of "decolonization" has not been completed up to now.When nativism loses its native complex from the perspective of "inherent in China", and further develops into the "separatism" of anti-constitutional system and anti-national continuity and unity, it will challenge the stability of the relationship between the central government and the Special Administrative Region under the "one country, two systems". At the same time, it will have a greater impact on the political structure and the rule of law system of Hong Kong, and trigger a series of public law problems that need to be solved urgently. In this regard, on the one hand, we should re-clarify the relationship between the central government and the region under the "one country, two systems" in light of the new situation of democratic political development in Hong Kong, and improve Hong Kong's governance mechanism on the basis of the constitution and the basic law; on the other hand, we should actively learn from the German defensive democracy system to systematically interpret, integrate and apply Hong Kong's existing legal resources so as to effectively curb the development of local separatist forces.

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Study on evaluation of bond strength of cone-shaped button cablebolt (콘형 케이블볼트의 인발강도 평가 연구)

  • Choi, Jung-In;Kim, Won-Keun;Lee, Dong-Seok;Lee, Seok-Won
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.12 no.1
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    • pp.61-73
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    • 2010
  • The cablebolt which secures a workability and stability has been used in foreign countries as one of supporting materials with rebar rockbolt especially in construction of large underground structures. However, only the rebar rockbolt has been applied up to now to all the constructions of underground structures in Korea due to an absence of recognition of cablebolt and large underground structure projects. Consequently, the research for a performance evaluation and verification of cablebolt is very limited and only the proto-type field tests have been conducted. In this study, the cone-shaped button cablebolt is developed by modifying an existing button cablebolt. To evaluate a performance and applicability of cone-shaped button cablebolt, the laboratory pull tests are conducted and bond capacity is analyzed under a various conditions. The rebar rockbolt, plane cablebolt, and bulb cablebolt which has a similar mechanical behavior with cone-shaped button cablebolt, are also tested and their bond capacities are evaluated and compared with cone-shaped button cablebolt under the same condition. The results show that the bond capacity is in the order of (cone-shaped button cablebolt$\approx$bulb cablebolt) > rockbolt > plane cablebolt. It is found that the bond capacity of cone-shaped button cablebolt developed in this study is at least equivalent with an existing high performance cablebolt developed in foreign countries, therefore the cone-shaped button cablebolt could be used as one of supporting materials for underground structures in construction field.

Management and Supervision Measures for Virtual Asset Ecosystem (가상자산 생태계 관리・감독 방안)

  • Sehyun Lee;Sangyeon Lee;Hee-Dong Yang
    • Knowledge Management Research
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    • v.24 no.3
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    • pp.73-94
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    • 2023
  • With the virtual asset market's rapid growth, government regulations on listing and trading procedures are expected. However, specific measures are currently lacking. To ensure stable inclusion in the institutional framework, precise regulations are needed for market development and investor protection. This study compares self-regulatory guidelines of the top domestic virtual asset exchanges with Korea Exchange's Preliminary Listing Examination Standards (2022) to enhance timeliness and relevance. It defines IEO, IPO, and ICO concepts and addresses conflicts of interest in IEO. Analyzing delisted virtual assets, it categorizes issues and classifies listing examination guidelines into formal and qualitative requirements. The study examines self-regulatory guidelines based on continuity, transparency, stability, corporate characteristics, and investor protection criteria, along with five special requirements for virtual assets. Improvement measures include regular disclosures of governance structure, circulation volume, and the establishment of independent audit institutions. This research further analyzes delisting cases, classifies issues, and proposes solutions. Considering stock market similarities, it offers measures based on the institutional framework.

Performance and Characterization of Ceramic Membrane by Phase Inversion-Extrusion Process with Polymer Binder Mixing (상전이-압출 알루미나 분리막 제조 공정에서 혼합 고분자 바인더 적용에 따른 성능 및 특성 평가)

  • Sojin Min;Ahrumi Park;Yongsung Kwon;Daehun Kim;You-In Park;Seong-Joong Kim;Seung-Eun Nam
    • Membrane Journal
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    • v.33 no.6
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    • pp.439-446
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    • 2023
  • Ceramic membranes are generally used for various industrial processes operating under extreme conditions because of its high thermal and chemical stability. However, due to the trade-off phenomenon of permeability and mechanical strength, preparation of high permeability-high strength membrane is necessary. In this study, the change in characteristics and performances of ceramic membranes was analyzed depending on the type of polymer binder and its mixing ratio. Because the solubility between solvent and polymer binder was higher in PSf (polysulfone) than in PES (polyethersulfone), the viscosity and discharge pressure of the PSf-based dope solution were higher than those of PES-based dope solution. When PSf was used as a polymer binder, ceramic membrane showed high mechanical strength and low water permeability due to the dense structure. On the other hand, in case of PES, the mechanical strength was slightly reduced and the water permeability was increased. It was confirmed that the optimum mixing ratio of the PSf and PES with high water permeability and mechanical strength was 9:1.