• 제목/요약/키워드: Structural transformation

검색결과 552건 처리시간 0.025초

매립 연령에 따른 침출수중에 존재하는 휴믹물질의 분광학적 특성 분석 (Spectroscopic Characterization of Humic Substances Present in Landfill Leachates with Respect to Landfilling Age)

  • 강기훈;신현상;박희경
    • 대한환경공학회지
    • /
    • 제22권6호
    • /
    • pp.1113-1126
    • /
    • 2000
  • 매립지 침출수에 의한 지하수의 오염으로 생성되는 대수층내 오염대 내에서 휴믹물질이 다른 오염물질의 이동 및 변환에 미치는 영향을 평가하기 위한 기초연구로서 매립지의 매립년한에 따른 침출수중에 존재하는 휴믹물질을 추출하여 그 특성을 분석하였다. 추출된 휴믹물질에 대해 원소분석을 실시하였으며, 분광학적 분석으로서 자외선-가시광선, 적외선, 형광 분광분석과 $^1H$$^{13}C$ 핵자기공명 분석을 실시하였다. 침출수중에 존재하는 휴믹물질은 토양 및 수중으로 부터 추출된 휴믹물질에 비해 구조적으로는 지방족 화합물에 의한 특성이 방향족 화합물에 의한 특성에 비교하여 우세하였으며, 이로부터 침출수 휴믹물질의 휴믹화 정도가 상대적으로 낮음을 알 수 있었다. 한편 매립지의 매립년한이 증가할수록 침출수 휴믹물질의 휴믹화 정도는 증가하는 특성을 보였다.

  • PDF

기계적 합금화법과 방전 플라즈마 소결법으로 제조된 Al-25Ti-8Mn 금속간 화합물의 산화 거동 (Oxidation Behavior of Al-25Ti-8Mn Intermetallic Compound Fabricated by Mechanical Alloying and Spark Plasma Sintering)

  • 최재웅;김기홍;황길호;홍석준;강성군
    • 한국재료학회지
    • /
    • 제15권7호
    • /
    • pp.439-443
    • /
    • 2005
  • The oxidation behavior and the thermal stability of nanocrystalline Al-25Ti-8Mn intermetallic compound were investigated. $Al_3Ti$ intermetallic compound, which has a potential for high temperature structural material, was fabricated by mechanical alloying(MA) with $8at.\%$ Mn to enhance the thermal stability and ductility. And Al-25Ti-8Mn intermetallic compound was sintered by spark plasma sintering(SPS) at $700^{\circ}C$. After sintering process, cubic $Ll_2$ structure was maintained without phase transformation and the grain size was about 50nm. To investigate the oxidation behavior of the specimens, thermal gravimetric analysis(TGA) was performed at 700, 800, 900, and $1000^{\circ}C$ for 24 h in $O_2$. As the temperature increased from $700^{\circ}C\;to\;900^{\circ}C$ the weight gain of specimens increased. However at $1000^{\circ}C$, unlike the oxidation behavior of $700^{\circ}C\;to\;900^{\circ}C$, the weight gain of specimen decreased drastically and the transition from linear rate region to parabolic rate region occurred rapidly due to the dense $\alpha-Al_2O_3$.

매체순환연소공정용 CaSnO3 산소전달입자의 산화·환원 특성 연구 (A Study on Redox Properties of CaSnO3 Oxygen Carrier for Chemical Looping Combustion Process)

  • 손은남;백승훈;이루세;손정민
    • 공업화학
    • /
    • 제30권1호
    • /
    • pp.43-48
    • /
    • 2019
  • 본 연구는 매체순환연소공정용 산소전달입자로서 $CaSnO_3$ 입자의 타당성을 조사하기 위해 수행하였다. $CaSnO_3$은 페롭스카이트 구조를 가지고, 반복되는 환원-산화 반응 후에도 구조적안정성을 보였다. 산소전달량은 환원 반응 시 결정구조 변화를 통해 계산된 이론 수치와 거의 동일한 15.4 wt%를 가졌다. 10번의 환원과 산화 반응 후에, 산소전달량과 산소전달속도는 작동 온도에서 일정하게 유지되었다. 결론적으로, $CaSnO_3$ 입자는 CLC의 산소 운반체로서 좋은 대체 물질이 될 수 있다고 판단하였다.

1987년 민주항쟁 30년, 민주노조운동의 평가와 전망 (A Study on the Evaluation of Three Decades of the 'Minjoonojoundong' in Korea)

  • 노중기
    • 산업노동연구
    • /
    • 제24권1호
    • /
    • pp.1-28
    • /
    • 2018
  • 이 논문은 노동자대투쟁 30주년을 맞아 민주노조운동의 현재를 거시적으로 평가하고 전망을 제시하고자 하였다. 민주노조운동은 1987년 노동체제의 공세기를 지나 1998년 이후 크게 약화되었다. 그 배경에는 종속 신자유주의 노동체제라는 노동체제의 구조변동이 자리하고 있었다. 노동운동은 과거의 전투적 노조주의를 그대로 유지함으로써 변화된 구조적 조건에 전략적으로 대응하지 못했던 것이다. 현재 민주노조운동은 전투적 경제주의, 정치경제주의, 불완전한 산별노조운동이라는 3중의 위기 상황에 봉착해있다. 그런데 2016년 갑자기 발생한 촛불혁명은 민주노조운동이 새로운 노동체제를 만들 수 있는 전망을 열어주었다. 촛불혁명은 일차적으로 정치변동이었지만 기존 노동체제의 문제점인 사회적 양극화와 비정규직 문제, 그리고 노동기본권문제를 해결하라는 요구를 담고 있었기 때문이다. 지금은 민주노조운동의 전면적 혁신이 긴요하다. 그리고 그것은 노동체제 전환이라는 전략적 목표 위에서 조직될 필요가 있다.

PRAM용 Cu-도핑된 Ge8Sb2Te11 박막의 특성 (Characteristics of Cu-Doped Ge8Sb2Te11 Thin Films for PRAM)

  • 김영미;공헌;김병철;이현용
    • 한국전기전자재료학회논문지
    • /
    • 제32권5호
    • /
    • pp.376-381
    • /
    • 2019
  • In this work, we evaluated the structural, electrical and optical properties of $Ge_8Sb_2Te_{11}$ and Cu-doped $Ge_8Sb_2Te_{11}$ thin films prepared by rf-magnetron reactive sputtering. The 200-nm-thick deposited films were annealed in a range of $100{\sim}400^{\circ}C$ using a furnace in an $N_2$ atmosphere. The amorphous-to-crystalline phase changes of the thin films were investigated by X-ray diffraction (XRD), UV-Vis-IR spectrophotometry, a 4-point probe, and a source meter. A one-step phase transformation from amorphous to face-centered-cubic (fcc) and an increase of the crystallization temperature ($T_c$) was observed in the Cu-doped film, which indicates an enhanced thermal stability in the amorphous state. The difference in the optical energy band gap ($E_{op}$) between the amorphous and crystalline phases was relatively large, approximately 0.38~0.41 eV, which is beneficial for reducing the noise in the memory devices. The sheet resistance($R_s$) of the amorphous phase in the Cu-doped film was about 1.5 orders larger than that in undoped film. A large $R_s$ in the amorphous phase will reduce the programming current in the memory device. An increase of threshold voltage ($V_{th}$) was seen in the Cu-doped film, which implied a high thermal efficiency. This suggests that the Cu-doped $Ge_8Sb_2Te_{11}$ thin film is a good candidate for PRAM.

미래 제조시스템 성숙도평가 프레임워크 (Framework for Assessing Maturity of Future Manufacturing System)

  • 이정철;장태우;박종경;황규선
    • 한국전자거래학회지
    • /
    • 제24권2호
    • /
    • pp.165-178
    • /
    • 2019
  • 스마트공장 등으로 변화하는 경쟁 환경 속에서 제조시스템의 현 수준을 측정하고 개선 목표와 과제를 도출, 추진하여 제조경쟁력의 수준을 높이는 것이 기업의 기본적 활동이 되고 있다. 그러나 기업의 미래 제조경쟁력을 갖추기 위한 구성요소 분석과 성숙도평가에 관한 연구는 부분적으로 진행되고 있고 초기단계에 있다. 본 연구는 제조시스템에 대한 다양한 관점의 모델, 개발프로세스, 프레임워크 등에 대한 기존 연구를 분석하였다. 또한 스마트공장 관련 성숙도평가 연구들을 통해 미래 제조시스템의 구성요소들을 도출하여 구조모델을 설계하였다. 평가모델, 변환모델까지 포함하는 메타모델을 설계하고 프레임워크 개발 프로세스를 도출하여 미래 제조시스템의 성숙도평가를 위한 통합적 프레임워크를 제안하였다. 또한 실제 스마트공장 평가에 적용하여 검증하였다. 제시된 프레임워크는 미래 제조시스템의 성숙도평가를 위한 기반 도구로 활용될 수 있을 것이다.

Quantitative aspects of the hydrolysis of ginseng saponins: Application in HPLC-MS analysis of herbal products

  • Abashev, Mikhail;Stekolshchikova, Elena;Stavrianidi, Andrey
    • Journal of Ginseng Research
    • /
    • 제45권2호
    • /
    • pp.246-253
    • /
    • 2021
  • Background: Ginseng is one of the most valuable herbal supplements. It is challenging to perform quality control of ginseng products due to the diversity of bioactive saponins in their composition. Acid or alkaline hydrolysis is often used for the structural elucidation of these saponins and sugars in their side chains. Complete transformation of the original ginsenosides into their aglycones during the hydrolysis is one of the ways to determine a total saponin group content. The main hurdle of this approach is the formation of various by-products that was reported by many authors. Methods: Separate HPLC assessment of the total protopanaxadiol, protopanaxatriol and ocotillol ginsenoside contents is a viable alternative to the determination of characteristic biomarkers of these saponin groups, such as ginsenoside Rf and pseudoginsenoside F11, which are commonly used for authentication of P. ginseng Meyer and P. quinquefolius L. samples respectively. Moreover, total ginsenoside content is an ideal aggregated parameter for standardization and quality control of ginseng-based medicines, because it can be directly applied for saponin dosage calculation. Results: Different hydrolysis conditions were tested to develop accurate quantification method for the elucidation of total ginsenoside contents in herbal products. Linearity, limits of quantification, limits of detection, accuracy and precision were evaluated for the developed HPLC-MS method. Conclusion: Alkaline hydrolysis results in fewer by-products than sugar elimination in acidic conditions. An equimolar response, as a key parameter for quantification, was established for several major ginsenosides. The developed approach has shown acceptable results in the analysis of several different herbal products.

영상 생성적 데이터 증강을 이용한 딥러닝 기반 SAR 영상 선박 탐지 (Deep-learning based SAR Ship Detection with Generative Data Augmentation)

  • 권형준;정소미;김성태;이재석;손광훈
    • 한국멀티미디어학회논문지
    • /
    • 제25권1호
    • /
    • pp.1-9
    • /
    • 2022
  • Ship detection in synthetic aperture radar (SAR) images is an important application in marine monitoring for the military and civilian domains. Over the past decade, object detection has achieved significant progress with the development of convolutional neural networks (CNNs) and lot of labeled databases. However, due to difficulty in collecting and labeling SAR images, it is still a challenging task to solve SAR ship detection CNNs. To overcome the problem, some methods have employed conventional data augmentation techniques such as flipping, cropping, and affine transformation, but it is insufficient to achieve robust performance to handle a wide variety of types of ships. In this paper, we present a novel and effective approach for deep SAR ship detection, that exploits label-rich Electro-Optical (EO) images. The proposed method consists of two components: a data augmentation network and a ship detection network. First, we train the data augmentation network based on conditional generative adversarial network (cGAN), which aims to generate additional SAR images from EO images. Since it is trained using unpaired EO and SAR images, we impose the cycle-consistency loss to preserve the structural information while translating the characteristics of the images. After training the data augmentation network, we leverage the augmented dataset constituted with real and translated SAR images to train the ship detection network. The experimental results include qualitative evaluation of the translated SAR images and the comparison of detection performance of the networks, trained with non-augmented and augmented dataset, which demonstrates the effectiveness of the proposed framework.

Modeling of a rockburst related to anomalously low friction effects in great depth

  • Zhan, J.W.;Jin, G.X.;Xu, C.S.;Yang, H.Q.;Liu, J.F.;Zhang, X.D.
    • Geomechanics and Engineering
    • /
    • 제29권2호
    • /
    • pp.113-131
    • /
    • 2022
  • A rockburst is a common disaster in deep-tunnel excavation engineering, especially for high-geostress areas. An anomalously low friction effect is one of the most important inducements of rockbursts. To elucidate the correlation between an anomalously low friction effect and a rockburst, we establish a two-dimensional prediction model that considers the discontinuous structure of a rock mass. The degree of freedom of the rotation angle is introduced, thus the motion equations of the blocks under the influence of a transient disturbing force are acquired according to the interactions of the blocks. Based on the two-dimensional discontinuous block model of deep rock mass, a rockburst prediction model is established, and the initiation process of ultra-low friction rockburst is analyzed. In addition, the intensity of a rockburst, including the location, depth, area, and velocity of ejection fragments, can be determined quantitatively using the proposed prediction model. Then, through a specific example, the effects of geomechanical parameters such as the different principal stress ratios, the material properties, a dip of principal stress on the occurrence form and range of rockburst are analyzed. The results indicate that under dynamic disturbance, stress variation on the structural surface in a deep rock mass may directly give rise to a rockburst. The formation of rockburst is characterized by three stages: the appearance of cracks that result from the tension or compression failure of the deformation block, the transformation of strain energy of rock blocks to kinetic energy, and the ejection of some of the free blocks from the surrounding rock mass. Finally, the two-dimensional rockburst prediction model is applied to the construction drainage tunnel project of Jinping II hydropower station. Through the comparison with the field measured rockburst data and UDEC simulation results, it shows that the model in this paper is in good agreement with the actual working conditions, which verifies the accuracy of the model in this paper.

Optimum arrangement of stiffener on the buckling behaviour of stiffened composite panels with reinforced elliptical cutouts subjected to non-uniform edge load

  • Kalgutkar, Akshay Prakash;Banerjee, Sauvik;Rajanna, T.
    • Steel and Composite Structures
    • /
    • 제42권4호
    • /
    • pp.427-446
    • /
    • 2022
  • Cutouts in the beams or plates are often unavoidable due to inspection, maintenance, ventilation, structural aesthetics purpose, and sometimes to lighten the structures. Therefore, there will be a substantial reduction in the strength of the structure due to the introduction of the cutouts. However, these cutouts can be reinforced with the different patterns of ribs (stiffener) to enhance the strength of the structure. The present study highlights the influence of the elliptical cutout reinforced with a different pattern of ribs on the stability performance of such stiffened composite panels subjected to non-uniform edge loads by employing the Finite element (FE) technique. In the present formulation, a 9-noded heterosis element is used to model the skin, and a 3-noded isoparametric beam element is used to simulate the rib that is attached around a cutout in different patterns. The displacement compatibility condition is employed between the plate and stiffener, and arbitrary orientations are taken care by introducing respective transformation matrices. The effect of shear deformation and rotary inertia are incorporated in the formulation. A new mesh configuration is developed to house the attached ribs around an elliptical cutout with different patterns. Initially, a study is performed on the panels with different stiffener schemes for various ply orientations and for different stiffener depth to width ratios (ds/bs) to determine an optimal stiffener configuration. Further, various parametric studies are conducted on an obtained optimal stiffened panel to understand the effect of cutout size, cutout orientation, panel aspect ratio, and boundary conditions. Finally, from the analysis, it can be observed that the arrangement of the stiffener attached to a panel has a major impact on the buckling capacity of the stiffened panel. The stiffener's depth to width ratio also significantly influences the buckling characteristic.