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Characteristics of Pitch Production of Pyrolyzed Fuel Oil/Coal-tar Blending Feedstock by Thermal Polymerization Reaction (Pyrolyzed Fuel Oil/Coal-tar 혼합원료의 열중합 반응에 따른 Pitch 제조 특성)

  • Lee, Eunbyul;Kim, Hyeong Gi
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.328-333
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    • 2020
  • In this study, blended feedstock derived pyrolyzed fuel oil (PFO) and coal-tar was prepared to produce a pitch by thermal polymerization reaction for manufacturing artificial graphite materials. The aromaticity value of 0.355 and 0.818 was obtained for PFO and coal-tar, respectively. In addition, PFO and coal-tar exhibited the difference tendency of weight loss curve for thermogravimetric analysis, which is related to the structural stability depending on the aromaticity and functional groups. The production characteristics confirmed that the pitch derived PFO showed lower production yield and higher softening point than that using blended feedstock. In particular, when comparing P360 (138.5 ℃) and B420 (141.4 ℃) having similar softening points, the production yields of both pitches exhibited 29.89 and 49.03 wt%, respectively. This is mainly due to the blending of PFO and coal-tar having high pitch polymerization reactivity including a large amount of alkyl groups and coal-tar having high thermal stability. This phenomenon indicated that the increased production yield is because of a synergic effect of both the high reactivity of PFO and thermal stability of coal-tar.

A Study on Feedstuff Utilization of Agricultural By-Products as a Major Feed Source in Korean Native Goat (농산부산물을 이용한 한국재래산양의 사료개발에 관한 연구)

  • 조익환;이성훈;김재홍;송해범;전하준
    • Korean Journal of Organic Agriculture
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    • v.5 no.2
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    • pp.117-128
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    • 1997
  • This study was carried out to investigate the amounts of voluntary intake, digestibility and nitrogen retention in Korean native goats (KNG) fed agricultural by-products containing rice straw (RS) and apple pomace (AP) and to obtain a basic information for establishing the feeding system of KNG. The result are as follows. 1. Among the chemical composition of experimental diets, the highest values in crude protein (CP ; 18.6%) and crude ash contents (10.7%) were observed in alfalfa hay. Those of RS+AP treatment were significantly low 6.0 and 4.8%, respecitively. Acid detergent fiber (ADF), ether extract and non-structural carbohydrate (NSC) contents were shown an adverse tendency. 2. Dry matter (DM) intakes per day in KNG fed RS+commercial diet (CD), RS+AP and RS+AP+CD were significantly lower (P<0.05) 210.3, 228.3, respectively than 358.1g in alfalfa hay. 3. DM intakes per basal weight expressed as DM g/kg of BW0.75 and DM g/kg of BW(%) were highest (P<0.05) 60.5g and 3.3%, respectively in KNG fed alfalfa hay, any other treatments showed 35.6 to 42.5g and 2.0 to 2.3%, respectively and this result was similar to those of DM intake per day. 4. Digestibilities of DM, organic matter, CP, ADF, neutral detergent fiber (NDF). crude ash and ether extract in alfalfa hay and RS+AP+CD treatment were significantly higher (P<0.05) than RS+CD treatment. Those of CP, ADF and NDF of RS+AP treatment in not significantly different with these treatments. 5. NSC digestibility was higher in alfalfa hay (66.7%) than those of other treatments (44.2~52.0% ; P<0.05). 6. Nitrogen retentions expressed as N retention(g) and N retention (%) in KNG were highest (P<0.05) 0.6g and 15.6%, respectively in RS+AP+CD treatment and RS+CD treatment was lowest (P<0.05) -06g and -21.4%, respectively.

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Identification and Molecular Characterization of Parkin in Clonorchis sinensis

  • Bai, Xuelian;Kim, Tae Im;Lee, Ji-Yun;Dai, Fuhong;Hong, Sung-Jong
    • Parasites, Hosts and Diseases
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    • v.53 no.1
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    • pp.65-75
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    • 2015
  • Clonorchis sinensis habitating in the bile duct of mammals causes clonorchiasis endemic in East Asian countries. Parkin is a RING-between-RING protein and has E3-ubiquitin ligase activity catalyzing ubiquitination and degradation of substrate proteins. A cDNA clone of C. sinensis was predicted to encode a polypeptide homologous to parkin (CsParkin) including 5 domains (Ubl, RING0, RING1, IBR, and RING2). The cysteine and histidine residues binding to $Zn^{2+}$ were all conserved and participated in formation of tertiary structural RINGs. Conserved residues were also an E2-binding site in RING1 domain and a catalytic cysteine residue in the RING2 domain. Native CsParkin was determined to have an estimated molecular weight of 45.7 kDa from C. sinensis adults by immunoblotting. CsParkin revealed E3-ubiquitin ligase activity and higher expression in metacercariae than in adults. CsParkin was localized in the locomotive and male reproductive organs of C. sinensis adults, and extensively in metacercariae. Parkin has been found to participate in regulating mitochondrial function and energy metabolism in mammalian cells. From these results, it is suggested that CsParkin play roles in energy metabolism of the locomotive organs, and possibly in protein metabolism of the reproductive organs of C. sinensis.

COLLOIDAL PROPERTIES OF HOLLOW LATICES AND THEIR ROLES IN CONTROLLING COLORIMETRIC PARAMETERS OF COATED PAPER SURFACE

  • Hitomi HAMADA;Yoko SAITO
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.309-314
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    • 1999
  • With a view to seek the influence of hollow sphere pigments of latex upon the printed color on coated paper surface, the hollow sphere pigments were compared with filled ones in a variety of experimental approaches. Colloidal properties of latices were determined by measuring zeta potential and particle size distribution. For the amphoteric filled sphere pigment of latex, the polarity was reversed from the negative side to the positive side with decreasing pH. An extraordinarily high peak in the particle size distribution of the amphoteric filled evidenced aggregation between latex particles near the isoelectric point, depending on the electrolyte concentration and pH of the suspending medium. Coated papers containing the hollow sphere pigment in their coating improved optical properties like gloss and brightness. Optical parameters solely of the coating could account for this finding. An equation derived from the Kubelka-Munk equation calculated them fro twice measurements of reflectance of a coated paper over two substrates of different reflectances. This method permitted to predict brightness of coated paper of which coat weight would be different fro the actual one. The colorimetric parameters of solid-printed surfaces of the coated papers closely related to optical and structural properties of the coated papers. The color of the printed surfaces was dominated by the brightness and the smoothness of the coated papers. The hollow sphere pigments were proved to improve optical properties of coated paper and to control minutely colorimetric parameters of printed surfaces.

Chemically Prestressed Precast Concrete Box Culvert with Expansive Additives

  • Park, Hong-Yong;Kim, Chul-Young;Park, Ik-Chang;Bae, Sang-Wook;Ryu, Jong-Hyun
    • KCI Concrete Journal
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    • v.13 no.1
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    • pp.43-51
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    • 2001
  • Although portland cement concrete is one of the most universal construction materials, it has some disadvantage such as shrinkage, which is an inherent characteristic. Because of this shrinkage, combined with the low tensile strength of the material, cracks of varying sizes can be found in every reinforced concrete. To prevent this cracking, keeping the concrete in compression by mechanical prestress has been used. This study discusses application of expansive additives for concrete to improve the serviceability of precast concrete box culvert by inducing chemical prestress. For this purpose, both expansive concrete slabs and normal concrete slabs are tested to verify the effect of expansive additives. Then the failure tests of the fullscale precast box culverts were carried out and the critical aspects of the structural behavior were investigated. The result of the material testis shows that the optimal proportion of expansive additives is 13 percent of cement weight, and the properties of expansive concrete are the same as those of normal concrete in that proportion. Both the experimental cracking load and service load of the expansive concrete members are increased in comparison with those of the normal concrete, but the ultimate load is decreased slightly. In addition to the above results, the deformation of expansive concrete member is lets than that of normal concrete member, and permanent strain which results from cyclic load is decreased. It can be concluded that the use of expansive additives to induce chemical prestress in precast concrete box culvert greatly improves the serviceability.

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SNU Human Powered Aircraft Design and Manufacturing (서울대학교 인간동력항공기의 설계 및 제작)

  • Eun, Won-Jong;Kim, Jung-Heon;Park, Seong-Woo;Kang, Jung-Pyo;Kim, Tae-Hwan;Park, Jae-Hyun;Han, Yoo-Ri;Lee, Da-Woon;Hong, Jong-Hwa;Lee, Yoon-Hyuk;Choi, Han-Seul;Park, Ji-Eun;Park, Joong-Hyun;Lee, Woo-Hee;Jang, Bum-Chan;Shin, Sang-Joon
    • Aerospace Engineering and Technology
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    • v.12 no.2
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    • pp.230-240
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    • 2013
  • Human powered aircraft: the aim is to fly only by human power, features many challenging issues. Contrary to the general aircraft operated by an engine, human powered aircraft, that manoeuvres by lower power, requires additional consideration about weight, material, aerodynamical and structural analysis. Since this aircraft flies at a low speed, low Reynolds number flight will need to be taken into account. In this paper, SNU (Seoul National University) Human Powered Aircraft was designed by comparing it with the existing human power aircrafts, as well as by using theoretical analysis that obtains the design parameters. Also, this paper discuss about the manufacturing process using composite material for real human powered aircraft.

Densification Method of Controlled Low Strength Materials Made with Coal Ashes (수중 가압식 매립방법을 이용한 석탄회 저강도고유동화재의 고밀도화 특성)

  • Kim, Juhyong;Cho, Samdeok;Kim, Ukgie;Kong, Jinyoung;Jung, Hyuksang;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.2
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    • pp.5-11
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    • 2013
  • This study introduces a densification technique of controlled low strength materials (CLSM) made with coal ashes by pump discharge pressure. Based on a small-scale laboratory test results, unit weight of CLSM around discharge pipe is greater than that of relatively some distant area from discharge pipe. It is also found that densification of CLSM depends on not only mixture rate of pond ash but also fly ash and location of discharge pipe.

Effectiveness of fibers and binders in high-strength concrete under chemical corrosion

  • Nematzadeh, Mahdi;Fallah-Valukolaee, Saber
    • Structural Engineering and Mechanics
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    • v.64 no.2
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    • pp.243-257
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    • 2017
  • Investigating the properties and durability of high-strength concrete exposed to sulfuric acid attack for the purpose of its application in structures exposed to this acid is of outmost importance. In this research, the resistance and durability of high-strength concrete containing macro-polymeric or steel fibers together with the pozzolans of silica fume or nano-silica against sulfuric acid attack are explored. To accomplish this goal, in total, 108 high-strength concrete specimens were made with 9 different mix designs containing macro-polymeric and steel fibers at the volume fractions of 0.5, 0.75, and 1.0%, as well as the pozzolans of silica fume and nano-silica with the replacement levels of 10 and 2%, respectively. After placing the specimens inside a 5% sulfuric acid solution in the periods of 7, 21, and 63 days of immersion, the effect of adding the fibers and pozzolans on the compressive properties, ultrasonic pulse velocity (UPV), and weight loss of high-strength concrete was investigated and the respective results were compared with those of the reference specimens. The obtained results suggest the dependency of the resistance and durability loss of high-strength concrete against sulfuric acid attack to the properties of fibers as well as their fraction in concrete volume. Moreover, compared with using nano-silica, using silica fume in the fibrous concrete mix leads to more durable specimens against sulfuric acid attack. Finally, an optimum solution for the design parameters where the crushing load of high-strength fibrous concrete is maximized was found using response surface method (RSM).

A study on eccentric load acted on cut and cover tunnel by numerical approach (복개 터널구조물에 작용하는 편토압 고려를 위한 수치해석적 연구)

  • Bae, Gyu-Jin;Chung, Hyung-Sik;Lee, Gyu-Phil
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.5 no.3
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    • pp.227-239
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    • 2003
  • For environment-friendly construction, cut-and-cover tunnels have been constructed, thereby leading to embankment slopes with a number of steps. The slopes cause eccentric load on concrete lining of the tunnel. Nevertheless, uniform vertical and horizontal earth pressures, which are determined by considering a self-weight of embankment and $K_0$, are routinely used in structural calculation. Distribution of the earth pressures applied to the lining will lead to a biased calculation far from the actual behavior of the lining. In this study, basic study, therefore, was performed to consider the eccentric load properly in design and analysis of a cut-and-cover tunnel. A method capable of considering the eccentric load in design was proposed and its applicability was numerically examined through a number of examples.

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Buckling and vibration analyses of MGSGT double-bonded micro composite sandwich SSDT plates reinforced by CNTs and BNNTs with isotropic foam & flexible transversely orthotropic cores

  • Mohammadimehr, M.;Nejad, E. Shabani;Mehrabi, M.
    • Structural Engineering and Mechanics
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    • v.65 no.4
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    • pp.491-504
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    • 2018
  • Because of sandwich structures with low weight and high stiffness have much usage in various industries such as civil and aerospace engineering, in this article, buckling and free vibration analyses of coupled micro composite sandwich plates are investigated based on sinusoidal shear deformation (SSDT) and most general strain gradient theories (MGSGT). It is assumed that the sandwich structure rested on an orthotropic elastic foundation and make of four composite face sheets with temperature-dependent material properties that they reinforced by carbon and boron nitride nanotubes and two flexible transversely orthotropic cores. Mathematical formulation is presented using Hamilton's principle and governing equations of motions are derived based on energy approach and applying variation method for simply supported edges under electro-magneto-thermo-mechanical, axial buckling and pre-stresses loadings. In order to predict the effects of various parameters such as material length scale parameter, length to width ratio, length to thickness ratio, thickness of face sheets to core thickness ratio, nanotubes volume fraction, pre-stress load and orthotropic elastic medium on the natural frequencies and critical buckling load of double-bonded micro composite sandwich plates. It is found that orthotropic elastic medium has a special role on the system stability and increasing Winkler and Pasternak constants lead to enhance the natural frequency and critical buckling load of micro plates, while decrease natural frequency and critical buckling load with increasing temperature changes. Also, it is showed that pre-stresses due to help the axial buckling load causes that delay the buckling phenomenon. Moreover, it is concluded that the sandwich structures with orthotropic cores have high stiffness, but because they are not economical, thus it is necessary the sandwich plates reinforce by carbon or boron nitride nanotubes specially, because these nanotubes have important thermal and mechanical properties in comparison of the other reinforcement.