• Title/Summary/Keyword: Striped phase

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Nano-identification for the Cleavage of Disulfide Bond during the Self-Assembly Processes of Unsymmetric Dialkyl Disulfides on Au(111)

  • Noh, Jae-Geun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.4
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    • pp.553-557
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    • 2005
  • The formation of striped phases of unsymmetric hexyl octadecyl disulfide ($CH_3(CH_2)_5SS(CH_2)_{17}CH_3$, HOD) and 1-hydroxyundecyl octadecyl disulfide ($CH_3(CH_2)_{17}SS(CH_2)_{11}$OH, HUOD) on Au(111) and graphite has been investigated by scanning tunneling microscopy (STM) to understand the self-assembly processes of dialkyl disulfides. STM imaging clearly shows the formation of striped phases having corrugation periodicities that are nearly consistent with the molecular length of alkanethiolate moieties formed after the S-S bond cleavage of dialkyl disulfide on a gold surface. On the other hand, self-assembled monolayers (SAMs) of dialkyl disulfides on a graphite surface displayed long-range, well-ordered monolayers with one striped pattern that shows periodicity as a function of molecular length via nondissociative adsorption. From a nonoscopic viewpoint, we have clearly demonstrated that dialkyl disulfide SAMs on gold form via S-S bond cleavage of disulfide.

Ultrasonic Tracking of Movements of Striped Jack ( Caranx Delicatissimus ) in the Nunoura Bay , Japan (초음파 표지를 이용한 양식어의 유영행동 추적)

  • 신현옥
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.4
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    • pp.347-359
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    • 1992
  • The movements of three striped jack (Caranx delicatissimus, 24cm of body length) were tracked by ultrasonic telemetry in the Nunoura Bay in August 1990. A school of the striped jack has been released near by the fish farming rafts by Goto branch of the Fisheries Agency and Japan Sea-Farming Association. To investigate the staying area and the swimming pattern of the fish, small size pinger($\Phi$8.5$\times$L35mm, 140dB re 1$\mu$Pa at 1m, 69kHz) was tagged on the dorsal fin without any anesthesia. The movements of three tagged fish are monitored at the same time with four omni-directional hydrophones. The locations of the fish are calculated by the hyperbolic method and tracked by a technique so called time division scheme which uses both the pulse interval and the phase. Three pingers used have the pulse interval of 1.7, 1.8 and 1.9sec, respectively, and the common pulse duration of 15ms. In results it was capable to estimate behavior right after the release, swimming speeds and approximate moving area of the fish. The movements were tracked for a week continuously, and it was found out that the staying area of the fish was around or under the farming rafts. Sometimes they swam together but most of the time they move separately. The average swimming speed of those fish was about two times of the body length.

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Varietal Differences in Feeding Preference of the Striped Rice Borer Larvae (Chilo suppressalis W.) (이화명나방 유충의 식이선호성에 있어서 수도품종간 차이)

  • Choi S.Y.;Lee H.R.
    • Korean journal of applied entomology
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    • v.15 no.2 s.27
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    • pp.53-56
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    • 1976
  • A laboratory experiment was conducted to investigate varietal differences in feeding preference of striped rice borer larvae (Chilo suppressalis W.) to the stem pieces of the eight rice varieties. The preference of the larvae for feeding was significantly differed with the varieties, and in some varieties they were changed with the stages of the plants after transplanting. The larvae much more preferred the susceptible variety Rexoro than the resistant variety TKM-6. The varieties Tongil (Suweon 213-1), Yushin, Jinheung and IR-26 showed comparatively lower feeding preference than TKM-6. Some varieties exhibited a rather interesting phenomenon; strong preference in feeding was observed during the vegetative phase for Tetep and Tongil (Suweon 213-1) and during the maturing phase for Suweon 240 and Yushin. When the varieties TKM-6, Tongil and Rexore were given in several combinations, Rexore was strongly preferred by the larvae than others, and Tongil was still comparatively low in feeding preference of the larvae. The non-feeding preference of the larvae were considered to be in coincidence with the resistance of rice varieties to the striped rice borer.

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Spermiogenesis in the Korean Striped Fleid Mouse Apodcmus agrarius coreae (한국산 등줄쥐(Apodemus agrarius coreae)에서의 정자변태)

  • 손성원;이정훈
    • The Korean Journal of Zoology
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    • v.38 no.3
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    • pp.395-404
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    • 1995
  • In order to study the process of spermiogenesis of the korean striped field mouse Apodemus agrorfus coreae, the cell differentiation of seminiferous epithelium and morphological features of mature sperm in cauda epididymis was examined and the results are as follows: Spermiogenesis was divided, according to the features of cell structure; Golgi, cap, acrosome and spermiation phases were further subdivided into two steps of early and late phases respectively, and maturation phase has only one step. Hence, the spermiogenesis consists of nine phases. in the changes of the chromatin in nucleus, the chromatin granules began to be condensed in the cap phase and the condensation proceeded to form a globular of nucleus at the acrsome phase. Finally, the chromatin regularization was completed and perfect nucleus of sperm was formed at the maturation phase. Sperm head had the falciform, and the outer dence fibers of middle piece were arranged in a horseshoe fashion. The outer dence fiber number 1, 5, 6 and 9 was larger than other fiber number 2, 3, 4, 7, 8.

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Coexistence of Closely Packed c(4 × 2) and Striped Phases in Self-Assembled Monolayers of Decylthiocyanates on Au(111)

  • Choi, Young-Sik;Kang, Hun-Gu;Choi, In-Chang;Lee, Nam-Suk;Cho, Jun-Hyung;Jang, Chang-Hyun;Noh, Jaeg-Eun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.901-904
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    • 2010
  • Decylthiocyanate (DTC) self-assembled monolayers (SAMs) on Au(111) were prepared by solution and vapor phase deposition methods at $50^{\circ}C$ for 24 h. The formation and surface structure of DTC SAMs were examined using scanning tunneling microscopy (STM). STM imaging revealed that DTC SAMs formed in 1 mM ethanol solution at $50^{\circ}C$ were composed of small ordered domains with lateral dimensions of a few nanometers and disordered phases, whereas DTC SAMs formed in the vapor phase at $50^{\circ}C$ contained two ordered phases: a closely packed c($4{\times}2$) superlattice and a striped phase with an interstripe spacing of 2.6 - 2.8 nm. It was also found that the ordered domain and vacancy island formation for DTC SAMs on Au(111) differs significantly from that of decanethiol SAMs, suggesting that adsorption mechanism is different from each other. From this study, it was confirmed that DTC SAMs with a high degree of structural order can be obtained by vapor phase deposition.

Characteristics of the Aggregation Pattern of the Striped Rice Borer(Chilo suppressalis(Walker) during the Larval Stage (이화명나방유충(幼蟲)의 공간분포특성(空間分布特性))

  • Ryoo, Mun-Il;Lee, Moon-Hong
    • Korean journal of applied entomology
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    • v.24 no.1 s.62
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    • pp.1-6
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    • 1985
  • The data on the striped rice, borer populations, collected in the four years from 1973 to 1976, was reanalyzed to study the characteristics in the aggregation pattern of the insect larvae in the paddy fields. The distribution pattern of the larvae was well fitted to the negative binomial model in both the first and the second generation. With reference to the Green's coefficient of dispersion estimated, the aggregation of the larvae was categorized into three phases: initial high aggregation, changing, and dispersed stable phase. Except the changing phase, each phase in each generation could be defined by a common k. The phase-change was initiated by the larval dispersal between hills of the rice plants: the larvae of the third stage and those of the fifth stage, for the first and second generation, respectively. The characteristics of the aggregation pattern were stable in the second generation. In the first genaration, the pattern was more or less variable, indicating that the life system of the insect in the first generation was more susceptible to the variations of the external physical factors than that in the second generation.

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Surface Potential Change Depending on Molecular Orientation of Hexadecanethiol Self-Assembled Monolayers on Au(111)

  • Ito, Eisuke;Arai, Takayuki;Hara, Masahiko;Noh, Jaegeun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1309-1312
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    • 2009
  • Surface potential and growth processes of hexadecanethiol (HDT) self-assembled monolayers (SAMs) on Au(111) surfaces were examined by Kelvin probe method and scanning tunneling microscopy. It was found that surface potential strongly depends on surface structure of HDT SAMs. The surface potential shift for the striped phase of HDT SAMs chemisorbed on Au(111) surface was +0.45 eV, which was nearly the same as that of the flat-lying hexadecane layer physisorbed on Au(111) surface. This result indicates that the interfacial dipole layer induced by adsorption of alkyl chains is a main contributor to the surface potential change. In the densely-packed HDT monolayer, further change of the surface potential was observed, suggesting that the dipole moment of the alkanethiol molecules is an origin of the surface potential change. These results indicate that the work function of a metal electrode can be modified by controlling the molecular orientation of an adsorbed molecule.

The Evaluation of Imaging Quality Depending the Shift of the Central Axis in FOCUS DWI Investigation (Focus DWI 검사에서 중심축 이동에 따른 화질 평가)

  • Kim, Younghwa;Jeong, Moontaeg;Choi, Namgil
    • Journal of the Korean Society of Radiology
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    • v.12 no.5
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    • pp.631-636
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    • 2018
  • The problem that the existing the magnetic resonance image (MRI) was prone to have not only long readout duration and low bandwidth in the phase-encode direction, but also geometric distortion was pointed out. The purpose of this study is to identify the usefulness of FOCUS-DWI through comparing FOCUS-DWI with the Conventional-DWI on a degree of uniformity and artifacts caused by the distance change in the central axis within the magnetic field. In terms of artifacts, there happened irregular striped artifacts in the Conventional-DWI technique, which in particular, more often arose in the central axis. Also, the overlap of imaging drastically increased. By contrast, there were no irregular striped artifacts in the FOCUS-DWI technique. In conclusion, it was found that the FOCUS-DWI technique was superior to the Conventional-DWI technique in terms of artifacts, the overlap of imaging, and a degree of uniformity. In addition, there was no difference of the change in distance from the central axis between the FOCUS-DWI technique and the Conventional-DWI technique. Thus, it is considered the FOCUS-DWI technique having less imaging distortion and high image quality will be highly clinically used.