• Title/Summary/Keyword: Stress corrosion

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Stress Corrosion Cracking Behavior under Cavitation Erosion-Corrosion in Sea Water-Part (II) (해수환경중 캐비테이션 침식-부식 하에서의 응력부식균열 거동 (II))

  • 안석환;임우조
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.36 no.2
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    • pp.139-146
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    • 2000
  • Cavitation can occur in pipes when liquid is moving at high velocity, especially at pittings where the smooth bore of the pipe is interrupted. The effect is usually to produce pitting on the downstream side of the turbulence. However, stress corrosion cracking behavior under cavitation erosion-corrosion was neatly unknown. In this study, therefore, some were investigated of stress corrosion cracking behavior, others were stress corrosion cracking behavior under cavitation erosion-corrosion of water injection. And datas obtained as the results of experiment were compared between the two. Mainresult obtained are as follows: 1) Stress corrosion cracking growth rate of heat affected zone under cavitation erosion-corrosion becomes most rapid, and stress intensity factor $K_1$becomes most high. 2) Stress corrosion cracking growth mechanism by cavitation erosion-corrosion is judgement on the strength of the film rupture model and the tunnel model. 3) The range of potential as passivation of heat affected zone is less noble than that of base metal, and that value is smaller. 4) Corrosion potential under cavitation erosion-corrosion in loaded stress is less noble than that of stress corrosion, and corrosion current density is higher.

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Factors Affecting Stress Corrosion Cracking Susceptibility of Alloy 600 MA Steam Generator Tubes

  • Kang, Yong Seok;Lee, Kuk Hee;Shin, Dong Man
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.22-25
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    • 2021
  • In the past, Alloy 600 nickel-based alloys have been widely used in steam generators. However, most of them have been replaced by thermally treated alloy 690 tubes in recent years because mill annealed alloy 600 materials are known to be susceptible to stress corrosion cracking. Unlike this general perception, some steam generators using mill annealed alloy 600 tubes show excellent performance even though they are designed, manufactured, and operated in the same way. Therefore, various analyses were carried out to determine causes for the degradation of steam generators. Based on the general stress corrosion cracking mechanism, tube material susceptibility, residual stress, and sludge deposits of steam generators were compared to identify factors affecting stress corrosion cracking. It was found that mill annealed alloy 600 steam generator tubes showed higher resistance to stress corrosion cracking when the amount of sludge deposits on tube surface was smaller and residual stress generated during the fabrication was lower.

Stress Corrosion Cracking Behavior under Cavitation Erosion-Corrosion in Sea Water-Part (I) (해수환경중 캐비테이션 침식 -부식 하에서의 응력부식균열거동(I))

  • 안석환;임우조
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.36 no.2
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    • pp.132-138
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    • 2000
  • The effect of fluid flow on corrosion and erosion-corrosion of metal is a well-recognized phenomenon in pipelines and machinery equipment, and so on. Not only are fluid hydrodynamics important, but also the corrosiveness of the process or production stream affects the corrosion system. Recent research demonstrates that it is possible to erosion-corrosion(E/C) phenomena in terms of hydrodynamics, electrochemical corrosion kinetics and film growth/removal phenomena. Stress corrosion cracking behavior under cavitation erosion-corrosion of mild steel(SS41) was investigated of base metal and weldment under loaded stress. Main result obtained are as follows : 1) The cavitation erosion sensitivity of base metal affected weight loss is more susceptive than heat affected zone, 2) The corrosion sensitivity affected weight loss of welding heat cycle is less susceptive on stress corrosion under cavitation erosion-corrosion than stress corrosion.

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Effect of Corrosion Characteristics in Relation to Loaded Stress in the Welded Zone of A5083-H116 Aluminum Alloy (A5083-H116 알루미늄 합금재 용접부의 부하응력에 따른 부식특성의 영향)

  • Jo, S.K.;Kong, Y.S.;Kim, Y.D.
    • Journal of Power System Engineering
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    • v.8 no.3
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    • pp.44-51
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    • 2004
  • Effect of corrosion characteristics in relation to loaded stress in the welded zone of A5083-H116 aluminum alloy, in the seawater was studied. The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded stress. The corrosion crack, corrosion rate, electrode potential, current, and corrosion pattern, etc. were examined for the specimens with the elapse of the immersion time. The main result derived from this study is the crack growth length is increased with the increasing loaded stress. The electrode potential and the corrosion current are decreased rapidly in the early stage of the corrosion, and then decreased gradually and stabilized eventually with the elapse of the immersion time. The test condition of the longer crack growth tends to show the higher corrosion rate. Corrosion pattern of the welded zone indicates that the depth and width of the pitting become increasing with the increasing loaded stress.

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Effect of Corrosion Atmosphere and Strain Rate on the Stress Corrosion Cracking of High Strength 7xxx Aluminum Alloy (고강도 7xxx 알루미늄 합금의 응력부식균열에 미치는 부식환경과 응력속도의 영향)

  • Yun, Yeo-Wan;Kim, Sang-Ha
    • Journal of the Korean institute of surface engineering
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    • v.41 no.3
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    • pp.121-128
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    • 2008
  • High strength 7xxx aluminum alloys have been applied to automotive bump back beam of the some limited model for light weight vehicle. The aluminum bump back beam is manufactured through extrusion, bending and welding. The residual stress given on these processes combines with the corrosive atmosphere on the road spreaded with corrosive chemicals to melt snow to occur the stress corrosion cracking. The composition of commercial 7xxx aluminum has Zn/Mg ratio about 3 and Cu over 2 wt% for better strength and stress corrosion cracking resistivity. But this composition isn't adequate for appling to the automotive bump back beam with high resistance to extrusion and bad weldability. In this study the composition of 7xxx aluminum alloy was modified to high Zn/Mg ratio and low Cu content for better extrusion and weldability. To estimate the resistivity against stress corrosion cracking of this aluminum alloy by slow strain rate test, the corrosion atmosphere and strain rate separate the stress corrosion cracking from conventional corrosion must be investigated. Using 0.6 Mol NaCl solution on slow strain rate test the stress corrosion cracking induced fracture was not observed. By adding 0.3% $H_2O_2$ and 0.6M $Na_2SO_4$ to 1M NaCl solution, the corrosion potential and current density of polarization curve moved to active potential and larger current density, and on the slow strain rate test the fracture energy in solution was lower than that in pre-exposure. These mean the stress corrosion cracking induced fracture can be estimated in this 1M NaCl + 0.3% $H_2O_2$ + 0.6M $Na_2SO_4$ solution. When the strain rate was below $2{\times}10^{-6}$, the stress corrosion cracking induced fracture start to be observed.

C-Ring Stress Corrosion Test for Inconel 600 Tube and Inconel 690 welded by Nd:YAG Laser (Nd:YAG 레이저로 용접한 인코넬 600관과 인코넬 690의 C링 응력 부식시험)

  • 김재도;문주홍;정진만;김철중
    • Proceedings of the KWS Conference
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    • 1998.10a
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    • pp.288-291
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    • 1998
  • Inconel 600 alloy is used as the material of nuclear steam generator tubing because of its mechanical properties, formability, and corrosion properties. According to reports, the life time of nuclear power plants decreases because of the pitting, intergranular attack, primary water stress corrosion cracking(PWSCC), and intergranular stress corrosion cracking(IGSCC), and denting in the steam generator. The SCC test is very important because of SCC appears in various environment such as solutions, materials, and stress. The C-Rig specimen was made of the steam generator welded sleeve repairing by the pulsed Nd:YAG laser. In the corrosion invironment, corrosion solutions are Primary Water, Caustic, and Sulfate solution and corrosion time is 1624-4877hr. The permitted stress is 30-60ksi.In this C-Ring SCC test is the relationship between corrosion depth, crack and corrosion environment is evaluated. SCC was happens in Sulfate and Corrosion solution but doesn't happen in Primary Water. The corrosion time and stress is very affected by the severely environment of Sulfate or Caustic solution. The microstructure observation indicates that SCC causes interganular failure in the grain boundary of vertical direction.

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A Study on Stress Corrosion Behaviors in Welded Zone of the API 5L-X65 Steel for Natural Gas Transmission (천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구)

  • JO SANG-KEUN;SONG HAN-SEOP;KONG YOO-SIK;KIM YUONG-DAI
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.401-407
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    • 2004
  • This study is on the constant-current stress corrosion test related to the load stress in welded zone and non-welded zone of high tensile strength steel for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed global corrosion and narrow pitting, and the pitting was increased by increasing the load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel for natural gas transmission specimens was decreased suddenly, and the average relative electrode potential was higher and the average relative current was lower in welded zone than base metal. and the average relative electrode potential was decreased by increasing the load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone than base metal, and the corrosion rate was decreased by increasing the load stress.

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On Corrosion Behaviors in Welded Zone of API 5L-X65 Steel for Natural Gas Transmission (천연가스 수송용 API 5L-X65강 용접부의 부식거동에 관한 연구)

  • JO SANG-KEUN;SONG HAN-SEOP;KONG Yu-SIK;KIM YOUNG-DAI
    • Journal of Ocean Engineering and Technology
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    • v.18 no.5
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    • pp.50-56
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    • 2004
  • This study is on the constant-current stress corrosion test, related to the load stress, in both the welded and non-welded zones of high tensile strength steel that is used for natural gas transmission. The surface corrosion pattern of the welded zone of API 5L-X65 specimens for natural gas transmission showed general corrosion and narrow pitting, and the pitting was increased with load stress. Initially, the average relative electrode potential and the average relative current of the high tensile strength steel, used for natural gas transmission specimens, were decreased rapidly, and the average relative electrode potential was higher and the average relative current was lower in welded zone, compared to base metal. The average relative electrode potential was decreased with load stress, and the average relative current was somewhat increased by increasing the load stress. The corrosion rate was less in welded zone, compared to base metal, and the corrosion rate was decreased by increasing the load stress.

Effects of Torsional Stress on the Corrosion Characteristics in the Rotor Assembly of Marine Diesel Engine Supercharger (선박용 디젤엔진 과급기 로터 접합체의 부식특성에 미치는 비틀림응력의 영향)

  • Jo, S.K.;Kong, Y.S.;Kim, Y.D.
    • Journal of Power System Engineering
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    • v.9 no.1
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    • pp.50-56
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    • 2005
  • The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

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SCC Mechanism of Ni Base Alloys in Lead Contaminated Water

  • Hwang, Seong Sik;Kim, Dong Jin;Lim, Yun Soo;Kim, Joung Soo;Park, Jangyul;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.187-191
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    • 2008
  • Transgranular stress corrosion cracking of nickel base alloys was reported by Copson and Dean in 1965. Study to establish this cracking mechanism needs to be carried out. Laboratory stress corrosion tests were performed for mill annealed(MA) or thermally treated(TT) steam generator tubing materials in a high temperature water containing lead. An electrochemical interaction of lead with the alloying elements of SG tubings was also investigated. Alloy 690 TT showed a transgranular stress corrosion cracking in a 40% NaOH solution with 5000 ppm of lead, while intergranular stress corrosion racking was observed in a 10% NaOH solution with 100 ppm lead. Lead seems to enhance the disruption of passive film and anodic dissolution of alloy 600 and alloy 690. Crack tip blunting at grain boundary carbides plays a role for the transgranular stress corrosion cracking.