• Title/Summary/Keyword: Strength retention

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Study of Equivalent Retention among Different Polymer-Solvent Systems is Thermal Field-Flow Fractionation

  • 김원숙;박영훈;문명희;유유경;이대운
    • Bulletin of the Korean Chemical Society
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    • v.19 no.8
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    • pp.868-874
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    • 1998
  • An equivalent retention has been experimentally observed in thermal field-flow fractionation (ThFFF) for different polymer-solvent systems. It is shown that iso-retention between two sets of polymer-solvent systems can be obtained by adjusting the temperature difference (ΔT) according to the difference in the ratio of ordinary diffusion coefficient to thermal diffusion coefficient. This method uses a compensation of field strength (ΔT) in ThFFF at a fixed condition of cold wall temperature. It is applied for the calculation of molecular weight of polymers based on a calibration run of different standards obtained at an adjusted AT. The polymer standards used in this study are polystyrene (PS), polymethylmethacrylate (PMMA), and polytetrahydrofuran (PTHF). Three carrier solvents, tetrahydrofuran (THF), methylethylketone (MEK) and ethylacetate (ETAc) were employed. Though the accuracy in the calculation of molecular weight is dependent on the difference in the slope of log λ vs. log M which is related to Mark-Houwink constant a, it shows reasonable agreement within about 6% of relative error in molecular weight calculation for the polymer-solvent systems having similar a value.

Engineering Properties of Fiber Mixed Soil (섬유 혼합토의 공학적 특성)

  • 장병욱;박영곤
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.44 no.1
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    • pp.116-124
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    • 2002
  • Natural resources fur the construction materials such as good soil, sand, and coarse aggregates have been encountered to be short due to excessive use by human. Even though some soil has been found to be unsuitable for construction materials, soil with reinforcement can naturally be an answer to these alternatives. According to recently published papers on fiber mixed soil, fiber mixed with soil can improve shear strength, compressive strength and post-peak load strength retention. In this study, a series of tests were performed to clarify the characteristics of fiber mixed soil and to give basic data for design and construction and their engineering properties, that is, unconfined compressive strength, splitting tensile strength, shear strength, crack by drying, freeze-thaw, creep and Poisson\`s ratio, were investigated and analyzed. It has been shown that fiber mixed soil is one of good alternatives fur the civil and building construction materials.

PREPARATION OF POLYMERS WITH ISOCYANATE GROUPS AND THEIR APPLICATIONS AS PAPER STRENGTH ADDITIVES

  • Xiumei Zhang;Hiroo Tanaka
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.186-191
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    • 1999
  • Results are shown on the preparation and characterization of homopolymer of 2-methacryloyloxyethyl isocyanate(MOI) ad copolymers of MOI with styrene synthesized by radical polymerization. The significant effectiveness of the polymers as additives for paper dry and wet strength was found. Dry strength can be increased by 75% and wet strength retention of sheets can reach 30% based on the increased dry strength and about 50% based on the dry strength of untreated sheet. Based on isocyanate group consumption, copolymers containing less isocyanate can give better effect than homopolymer in sheet wet strength improvement. Furthermore, the base paper containing a small amount of polyallylamine hydrochloride was used for polymer treatment and got higher wet strength improvement.

A study on performance evaluation of fiber reinforced concrete using PET fiber reinforcement (PET 섬유 보강재를 사용한 섬유 보강 콘크리트의 성능 평가에 관한 연구)

  • Ri-On Oh;Yong-Sun Ryu;Chan-Gi Park;Sung-Ki Park
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.25 no.4
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    • pp.261-283
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    • 2023
  • This study aimed to review the performance stability of PET (Polyethylene terephthalate) fiber reinforcing materials among the synthetic fiber types for which the application of performance reinforcing materials to fiber-reinforced concrete is being reviewed by examining short-term and long-term performance changes. To this end, the residual performance was analyzed after exposing the PET fiber to an acid/alkali environment, and the flexural strength and equivalent flexural strength of the PET fiber-reinforced concrete mixture by age were analyzed, and the surface of the PET fiber collected from the concrete specimen was examined using a scanning microscope (SEM). The changes in were analyzed. As a result of the acid/alkali environment exposure test of PET fiber, the strength retention rate was 83.4~96.4% in acidic environment and 42.4~97.9% in alkaline environment. It was confirmed that the strength retention rate of the fiber itself significantly decreased when exposed to high-temperature strong alkali conditions, and the strength retention rate increased in the finished yarn coated with epoxy. In the test results of the flexural strength and equivalent flexural strength of the PET fiber-reinforced concrete mixture, no reduction in flexural strength was found, and the equivalent flexural strength result also did not show any degradation in performance as a fiber reinforcement. Even in the SEM analysis results, no surface damage or cross-sectional change of the PET reinforcing fibers was observed. These results mean that no damage or cross-section reduction of PET reinforcing fibers occurs in cement concrete environments even when fiber-reinforced concrete is exposed to high temperatures in the early stage or depending on age, and the strength of PET fibers decreases in cement concrete environments. The impact is judged to be of no concern. As the flexural strength and equivalent flexural strength according to age were also stably expressed, it could be seen that performance degradation due to hydrolysis, which is a concern due to the use of PET fiber reinforcing materials, did not occur, and it was confirmed that stable residual strength retention characteristics were exhibited.

Substrate Removal Condition in Activated Sludge Process of Wastewater from Acetaldehyde Manufacturing Plant (Acetaldehyde폐수의 활성오이법에 의한 기질제거조건)

  • 금영일;금두조
    • Journal of environmental and Sanitary engineering
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    • v.8 no.1
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    • pp.107-116
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    • 1993
  • This study is conducted to investigate treatability by activated sludge process for wastewater from acetaldehyde manufacturing plant. The optimum hydraulic retention time in aeration tank for removal of high strength substrate were measured. The removal efficiency were checked out by hydraulic retention time : 35hr., 40hr. and 45hr., respectively. $COD_{Cr}$, like substances were removed in all hydraulic retention time zone directed for efficiency, but non-biodegradable substances were remained. $COD_{Cr}$ biomass loading was 0.81kg $COD_{Cr}/kgMLVSS$ . day at 35hr. of retention time, 0.34 kg$COD_{Cr}$/kg MLVSS . day at 40hr., and O.l9kg$COD_Cr$/kgMLVSS . day at 45hr. And the mean $COD_{Cr}$, removal efficiency was 65.5%, 81.6% and 83.0%, respectively. And also $COD_{Cr}$, volume loading was 1.01kg$COD_{Cr}/m^3$ day, 0.87kg$COD_{Cr}/m^3$ - day, and 0.79kg$COD_{Cr}/m^3{\cdot }$day, respectively. The basic design parameter obtained is as fallows. The value of Specific substrate removal rate coefficient (k), Yield coefficient(Y) and Decay coefficient($k_d$) was $0.0013day^{-1}$, $0.505kgMLVSS/kgCOD_{Cr}$ and $0.040day^{-1}$, respectively.

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A Study on Stormwater Retention and Infiltration Ponds System for Improvement of Water Circulation and Increase of Bio-diversity (물 순환 개선 및 생물다양성 증진을 위한 우수저류 및 침투연못 시스템에 관한 연구)

  • Kim, Kwi-Gon;Kim, Hyea-Ju;Lee, Jae-Chul;Kim, Jong-Sub;Jang, Hey-Young;Son, Sam-Gi
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.3 no.2
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    • pp.53-65
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    • 2000
  • The objectives of this study are to develop a stormwater management system that would contribute to improving water circulation, recycling storm water and promoting biodiversity in urban areas, to apply the system in an actual site, and to verify its effectiveness in order to generate a stormwater management system applicable in Korea. This study reviewed former researches and case studies, categorized stormwater management system into pre-treatment, retention and infiltration phases, and analyzed the strength and weakness of the techniques by synthesizing unit techniques of each stage. As a result, the process of the stormwater management system includes the following phases: 1) a rubble filtration layer; 2) a retention pond; 3) a infiltration pond; and 4) a stormwater retention pool (recirculation and recycling). Then, an empirical study to design and create the generated system according to the features of a site and to verify its effectiveness was conducted. The future study direction is to verify the effectiveness of the developed stormwater retention and infiltration ponds. To this end, it is planned to perform hydrological monitoring using automatic measuring equipment and monitoring on habitat bases and the biota living on the base. Based on its outcome, the applied model would be refined and improved to develop an alternative stormwater management system that would allow to achieve the improvement of urban water circulation, increase of biodiversity and efficient use of water resources.

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A Study for Improving the Fluidity Retention in Concrete Used High Range Water Reducing AE Agent (고성능AE감수제 사용 콘크리트의 유동성 유지성능 향상을 위한 연구)

  • 김기형
    • Magazine of the Korea Concrete Institute
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    • v.10 no.6
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    • pp.313-323
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    • 1998
  • Fluidity retention of concrete used high range water reducing AE agent(HWAE) is varied according to main component, dosage amount and dosing method of HWAE. The type and substitution ratio of mineral admixture also have influence on the fluidity retention of concrete used HWAE. In this study, for the purpose of improving the fluidity retention in concrete used HWAE. 3 types of HWAE and ground granulated blast furnace slag(SG) are used in cement paste, mortar and concrete varing dosage amount and dosing time of HWAE and substitution ratio of SG respectively. According to using the HWAE of naphthalene sulfonates and SG, the fluidity retention of mortar and concrete is improved remarkably. And after 30 min, dosing method of HWAE is very effective in improving the fluidity retension and strength of concrete regardless of type of HWAE.

Soil water retention and hysteresis behaviors of different clayey soils at high suctions

  • Li, Ze;Gao, You;Yu, Haihao;Chen, Bo;Wang, Long
    • Geomechanics and Engineering
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    • v.30 no.4
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    • pp.373-382
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    • 2022
  • Unsaturated soil at high suctions is widespread. Many civil engineering projects are related to the hydro-mechanical behavior of unsaturated soils at high suctions, particularly in arid and semiarid areas. To investigate water retention behaviors of nine clayey soils (one is classified as fat clay and the others are classified as lean clay according to the unified soil classification system), the high suction (3.29-286.7 MPa) was imposed on the specimens at zero net stress by the vapor equilibrium technique. In this paper, the effect of void ratio on the water retention behavior at high suction was discussed in detail. Validation data showed that soil types, i.e., different mineralogical compositions, are critical in the soil water retention behavior at a high suction range. Second, the hysteresis behavior at a high suction range is mainly related to the clay content and the specific surface area. And the mechanism of water retention and hysteresis behavior at high suctions was discussed. Moreover, the maximum suction is not a unique value, and it is crucial to determine the maximum suction value accurately, especially for the shear strength prediction at high suctions. If the soil consists of hydrophilic minerals such as montmorillonite and illite, the maximum suction will be lower than 106 kPa. Finally, using the area of hysteresis to quantify the degree of hysteresis at a high suction range is proposed. There was a good correlation between the area of hydraulic hysteresis and the specific surface area.

A comparison of retentive strength of implant cement depending on various methods of removing provisional cement from implant abutment

  • Keum, Eun-Cheol;Shin, Soo-Yeon
    • The Journal of Advanced Prosthodontics
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    • v.5 no.3
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    • pp.234-240
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    • 2013
  • PURPOSE. This study evaluated the effectiveness of various methods for removing provisional cement from implant abutments, and what effect these methods have on the retention of prosthesis during the definitive cementation. MATERIALS AND METHODS. Forty implant fixture analogues and abutments were embedded in resin blocks. Forty cast crowns were fabricated and divided into 4 groups each containing 10 implants. Group A was cemented directly with the definitive cement (Cem-Implant). The remainder were cemented with provisional cement (Temp-Bond NE), and classified according to the method for cleaning the abutments. Group B used a plastic curette and wet gauze, Group C used a rubber cup and pumice, and Group D used an airborne particle abrasion technique. The abutments were observed using a stereomicroscope after removing the provisional cement. The tensile bond strength was measured after the definitive cementation. Statistical analysis was performed using one-way analysis of variance test (${\alpha}$=.05). RESULTS. Group B clearly showed provisional cement remaining, whereas the other groups showed almost no cement. Groups A and B showed a relatively smooth surface. More roughness was observed in Group C, and apparent roughness was noted in Group D. The tensile bond strength tests revealed Group D to have significantly the highest tensile bond strength followed in order by Groups C, A and B. CONCLUSION. A plastic curette and wet gauze alone cannot effectively remove the residual provisional cement on the abutment. The definitive retention increased when the abutments were treated with rubber cup/pumice or airborne particle abraded to remove the provisional cement.

The Effect of Hot Water Soluble Extract from Green Tea on Metabolism of Calcium and Bone Strength in rats fed Soy Protein Diet (녹차 열수 추출물이 콩단백질을 급여한 흰쥐의 칼슘대사와 골격강도에 미치는 영향)

  • Won Hyang Rye
    • The Korean Journal of Community Living Science
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    • v.16 no.1
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    • pp.59-64
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    • 2005
  • This study is to find out effects of hot water soluble extract from green tea, one of the Korean favorites, on the calcium metabolism and bone strength in body. To do so, calcium, phosphate, creatinine concentration and ALP activity in blood and the content of calcium and ash in the organ, the length, weight, strength in bone were measured. In addition, to find the calcium metabolism, the level of calcium intake, excretion, retention were measured. Twenty male Sprague-Dawley rats were divided into two groups and isoloated soy protein was provided as the source of protein and CaCO₃ was provided as the source of calcium. 0.5% hot water soluble extract from green tea was provided to the green tea groups and for the control group deionized water was provided. The results are as follows ; 1. There is no difference between the experimental groups in diet intake, weight gain, and the feed intake. 2. Feed efficiency ratio was low in the group which hot water soluble extract from green tea was provided. 3. There is no difference between groups the level of calcium, phosphorus, creatinine and ALP activity in serum. 4. There is no difference between groups weight, contents of ash and calcium in kidney and liver. 5. There is no difference between groups in calcium intake, absorption, excretion, and retention. 6. There is no difference between groups weight, length and strength in bone. In summary, when hot water soluble extract from green tea was provided with the amount of 150-200mg, which is taken when people generally drink as favorite tea, weight gain was reduced due to the decrease of feed efficiency ratio. However, it did not affect the availability of calcium in body at all. Thus, even if a big quantity of green tea powder or solid of hot green tea extract is not provided, the quantity obtained when people drink green tea lowers the feed efficiency ratio without reducing availability of calcium in body.

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