• Title/Summary/Keyword: Stoichiometry

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Effects of Crystallinity and Stoichiometry on the Mobility of InSb Thin Films (InSb 박막의 결정성 및 화학양론이 이동도에 미치는 영향)

  • Lee, Jeong-Young;Lee, Byung-Soo
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.1
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    • pp.75-80
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    • 2012
  • $InSb$ films were fabricated by DC magnetron sputtering and the effects of deposition temperature, heat treatment, passivation from evaporation and multi-layered structure were investigated. Electron mobility and electron concentration were linearly increased with deposition temperature for as-deposited specimens. It was found that the mobilities depend on the grain size rather than the stoichiometry for the samples with very low mobilities. The mobilities largely increased for the specimens with evaporation passivation compared with those without passivation layer. The mobility also increased with the amount of indium deposition in the multi-layer structured $InSb$ films. It was found that the mobility increments in both cases are due to the matching of the stoichiometry in $InSb$ films. For the heat treated and passivated specimens, the mobilities increased with annealing time and the maximum mobility was measured as 1612 $cm^2$/Vs.

A Study on Properties of CuInS2 Thin Films by Cu/ln Ratio (Cu/In 비에 따른 CuInS2 박막의 특성에 관한 연구)

  • Yang, Hyeon-Hun;Park, Gye-Choon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.7
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    • pp.594-599
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    • 2007
  • [ $CulnS_2$ ] thin films were synthesized by sulfurization of Cu/In Stacked elemental layer deposited onto glass Substrates by vacuum furnace annealing at temperature $200^{\circ}C$. And structural and electrical properties were measured in order to certify optimum conditions for growth of the ternary compound semiconductor $CuInS_2$ thin films with non-stoichiometry composition. $CuInS_2$ thin film was well made at the annealed $200^{\circ}C$ of SLG/Cu/In/S stacked elemental layer which was prepared by thermal evaporator, and chemical composition of the thin film was analyzed nearly as the proportion of 1 : 1 : 2. Physical properties of the thin film were investigated at various fabrication conditions substrate temperature, annealing and temperature, annealing time by XRD, FE-SEM and Hall measurement system. The compositional deviations from the ideal chemical formula for $200^{\circ}C$ material can be conveniently described by non-molecularity$({\Delta}x=[Cu/In]-1)$ and non-stoichiometry $({\Delta}y=[{2S/(Cu+3In)}-1])$. The variation of ${\Delta}x$ would lead to the formation of equal number of donor and accepters and the films would behave like a compensated material. The ${\Delta}y$ parameter is related to the electronic defects and would determine the type of the majority charge carriers. Films with ${\Delta}y>0$ would behave as p-type material while ${\Delta}y<0$ would show n-type conductivity. At the sane time, carrier concentration, hall mobility and resistivity of the thin films was $9.10568{\times}10^{17}cm^{-3},\;312.502cm^2/V{\cdot}s\;and\;2.36{\times}10^{-2}\;{\Omega}{\cdot}cm$, respectively.

Prediction of the Combustion Performance in the Coal-fired Boiler using Response Surface Method (반응표면법을 이용한 석탄 화력 보일러 연소특성 예측)

  • Shin, Sung Woo;Kim, Sin Woo;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.32 no.1
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    • pp.27-32
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    • 2017
  • The experimental design methodology was applied in the real scale coal-fired boiler to predict the various combustion properties according to the operating conditions and to assess the coal plant safety. Response surface method (RSM) was introduced as a design of experiment, and the database for RSM was provided with the numerical simulation of the coal-fired boiler. The three independent variables, high heating value of coal (HHV), overall stoichiometry excess air ratio (OST), and burner-side stoichiometry excess air ratio (BST), were set to characterize the cross section averaged NOx concentration and temperature distribution. The maximum NOx concentration was predicted accurately and mainly controlled by BST in the boiler. The parabola function was assumed for the zone averaged peak temperature distribution, and the prediction was in a fairly good agreement with the experiments except downstream. Also, the location of the peak temperature was compared with that of maximum NOx, which implies that thermal NOx formation is the main mechanism in the coal-fired boiler. These results promise the wide use of statistical models for the fast prediction and safety assessment.

A Study on Properties of $CuInS_{2}$ thin films by Cu/In ratio (Cu/In 비에 따른 $CuInS_{2}$ 박막의 특성에 관한 연구)

  • Yang, Hyeon-Hun;Kim, Young-Jun;Jeong, Woon-Jo;Park, Gye-Choon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.326-329
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    • 2007
  • $CuInS_{2}$ thin films were synthesized by sulpurization of Cu/In Stacked elemental layer deposited onto glass Substrates by vacuum furnace annealing at temperature 200[$^{\circ}C$]. And structural and electrical properties were measured in order to certify optimum conditions for growth of the ternary compound semiconductor $CuInS_{2}$ thin films with non-stoichiometry composition. $CuInS_{2}$ thin film was well made at the heat treatment 200[$^{\circ}C$] of SLG/Cu/ln/S stacked elemental layer which was prepared by thermal evaporator, and chemical composition of the thin film was analyzed nearly as the proportion of 1 : 1 : 2. Physical properties of the thin film were investigated at various fabrication conditions substrate temperature, annealing and temperature, annealing time by XRD, FE-SEM and Hall measurement system. At the same time, carrier concentration, hall mobility and resistivity of the thin films was $9.10568{\times}10^{17}$ [$cm^{-3}$], 312.502 [$cm^{2}/V{\cdot}s$] and $2.36{\times}10^{-2}$ [${\Omega}{\cdot}cm$], respectively.

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Characteristics of Laminar Lifted Flames in Coflow Jet with Various Coflow Velocities (동축류 제트에서 동축류 속도에 따른 층류 부상화염의 특성 연구)

  • Lee, S.J.;Kim, K.N.;Won, S.H.;Chung, S.H.
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.21-26
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    • 2004
  • Characteristics of laminar lifted names in coflow jet with various coflow velocities have been studied experimently. USlI1g the fuel nozzle with d=0.254 for the pure propane, liftoff heights are fitted by using power equation with jet velocity. As coflow velocity increases up to 60 cm/s powers of fitting equation steeply decrease. From the result of numerical analysis using the FLUENT, the stoichiometry contour and the axial velocity nondimensionalized by initial jet velocity along the stoichiometry contour are changed with variations of coflow velocities, The change of axial velocity along stoichiometric contour is more sensitive than that of stoichiometric contour, For this reason, powers of fitting equation for liftoff height with jet velocity decreases with the increase of coflow velocity. Using the fuel nozzle with d=4,35 mm for the highly diluted propane by nitrogen, the liftoff height increases with the increase of coflow velocity when coflow velocity is less than the maximum value of initial jet velocity. But when coflow velocity is faster than that, the liftoff height decreases with the increase of coflow velocity.

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Fabrication and Properties of Ferroelectric Thin Film for Capacitor (캐패시터용 강유전체 박막의 제조 및 특성)

  • So, Byung-Moon;Park, Choon-Bae
    • Proceedings of the KIEE Conference
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    • 1999.11a
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    • pp.31-34
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    • 1999
  • In the present study, we fabricated stoichiometric $(Ba_{1-x}Sr_x)TiO_3$ thin films at various substrate temperature and contents using of magnetron sputtering method on optimized Pt-based electrodes (Pt/TiN/$SiO_2$/Si). The substate temperature deposited at 200[ $^{\circ}C$], 400[$^{\circ}C$] and 600[$^{\circ}C$] and crystalline BST thin films show above 400[$^{\circ}C$]. Also, the composition of $(Ba_{1-x}Sr_x)TiO_3$ thin films deposited on Si wafer substrate at 400[$^{\circ}C$] were closed to stoichiometry($1.015{\sim}1.093$ in A/B ratio), but compositional deviation from a stoichiometry is larger as $SrCO_3$ is added. The drastic decrease of dielectric constant and increase of dielectric loss in $(Ba_{1-x}Sr_x)TiO_3$thin films is observed above 100[kHz]. V-I characteristics of $(Ba_{1-x}Sr_x)TiO_3$ thin films show the decrease of leakage current with the increase of $SrCO_3$ contents.

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A Study on the Structural Properties of rf Magnetron Sputtered $Ba_{1-x}Sr_xTiO_3$ Thin Film (Rf Magnetron Sputtering 방법으로 제조된 $Ba_{1-x}Sr_xTiO_3$ 박막의 구조적 특성에 대한 연구)

  • 김태송;오명환;김종희
    • Journal of the Korean Ceramic Society
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    • v.30 no.6
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    • pp.441-448
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    • 1993
  • The Ba1-xSrxTiO3 thin films deposited on ITO-coated glass substrate at 55$0^{\circ}C$ by rf magnetron sputtering method have individual preferential orientations as a function of composition (X=0, 0.25, 0.5, 0.75, 1) due to the stress relief interactions among the intrinsic compressive stress, thermal tensile stress adn extrinsic compressive stress (compressive stress in case of BaTiO3(Tc=12$0^{\circ}C$) and Ba0.75Sr0.25TiO3(Tc=57$^{\circ}C$)). This behavior also appears on the (BaSr)TiO3 thin films (X=0.5) deposited on ITO-coated glass substrate at deposition temperature between 35$0^{\circ}C$ and 55$0^{\circ}C$. The composition of Ba1-xSrxTiO3 thin films deposited on ITO-coated glass substrate at 55$0^{\circ}C$ is close to stoichiometry (1.009~1.089 in A/B ratio), but the compositional deviation from a stoichiometry is larger as SrTiO3 is added. The morphology of Ba1-xSrxTiO3 thin films is very similar for over all substrate temperatures, and the roughness due to the differences of cluster size is the smallest at X=0.25.

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