• Title/Summary/Keyword: Stirring energy

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A Study on Photo-Luminescence Spectrum Properties of ZnS:Mn QD Prepared by Wet-Process (습식공정을 이용한 ZnS:Mn2+계 QD의 합성 조건에 따른 광 특성 변화 연구)

  • Cha, Ji Min;Lee, Yoon Ji;Moon, Seong Cheol;Lee, Seong Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.42-47
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    • 2017
  • In this study, the physical and optical properties of $ZnS:Mn^{2+}$ Quantum Dot prepared by wet-process condition with Mn/Zn ratio was valuated. The powder characteristics and optical behavior were investigated through XRD, TEM and Photo spectrometer exicted by various UV light source. We found the main peak of ZnS (111) was shifted by 0.8 degree to low angle position with increasing stirring energy from 200 RPM to 600 RPM, which is thought to be the increase of lattice defects during wet process. The photo luminescence at 600 RPM shows also higher blue intensity which is well correlated with XRD results. With increasing Mn/Zn ratio, the PL intensity become higher and shifed by 8.5nm to right side, by the increment of substitutional $Mn^{2+}$ ions.

Experimental Investigation on the Enhancement of Methane Hydrate Formation in the Solid Transportation of Natural Gas (천연가스 고체화 수송을 위한 메탄 하이드레이트 충진율 증대에 대한 실험적 연구)

  • 김남진;정재성;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.10
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    • pp.863-870
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    • 2002
  • Fossil fuels have been depleted gradually and new energy resource which can solve this shortage is needed now. Methane hydrate, non-polluting new energy resource, satisfies this requirement and considered the precious resource prevent the global warming. Fortunately, there are abundant resources of methane hydrate distribute in the earth widely, so developing the techniques that can use these gases effectively is fully valuable. the work presented here is to develop the skill which can transport and store methane hydrate. As a first step, the equilibrium point experiment has been carried out by increasing temperatures in the cell at fixed pressures. The influence of gas consumption rates under variable degree of subcooling, stirring and water injection has been investigated formation to find out kinetic characteristics of the hydrate. The results of present investigation show that the enhancements of the hydrate formation in terms of the gas/water ratio are closely related to operational pressure, temperature, degrees of subcooling, stirring rate, and water injection.

Detection of Irradiated Cereals by Viscosity Measurement

  • Yi, Sang-Duk;Chang, Kyu-Seob;Yang, Jae-Seung
    • Preventive Nutrition and Food Science
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    • v.5 no.2
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    • pp.93-99
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    • 2000
  • A study was performed to establish the detection method of irradiated cereals. A drastic reduction of the apparent viscosity of suspensions with heat treatment was observed up to 1∼2 kGy in brown rice, Job's-tears, polished barley and polished rice. They were gently reduced to samples irradiated at 15 kGy. This trend was similar for all stirring speeds. The viscosity of unirradiated brown rice, Job's-tears, polished barley and polished rice reduced with in-creasing stirring speeds and this tendency was similar for irradiation doses. Regression expressions and coefficients of brown rice, Job's s-tears, polished barley and polished rice on different doses were 0.9399($y=3408.0e^{-0.2338x}$), 0.8855($y=3597.8e^{-0.6864x}$), 0.9343($y=7554.0e^{-0.4998x}$) and 0.9714($y=3228.2e^{-0.5312x}$), respectively, at 120 rpm. These results sug-gest that detection of irradiation for cereals could be possible by viscometric methods.

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Influence of Reducing Agents and Additives on the Synthesis of ZnSe Nanoparticles (ZnSe 나노분말 합성에 미치는 환원제와 첨가제의 영향)

  • Back, Geum Ji;Lee, Da Gyeong;Lee, Min Seo;Song, Ha Yeon;Hong, Hyun Seon
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.233-240
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    • 2020
  • Nano-sized ZnSe particles are successfully synthesized in an aqueous solution at room temperature using sodium borohydride (NaBH4) and thioglycolic acid (TGA) as the reducing agent and stabilizer, respectively. The effects of the mass ratio of the reducing agent to Se, stabilizer concentration, and stirring time on the synthesis of the ZnSe nanoparticles are evaluated. The light absorption/emission properties of the synthesized nanoparticles are characterized using ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy, and particle size analyzer (PSA) techniques. At least one mass ratio (NaBH4/Se) of the reducing agent should be added to produce ZnSe nanoparticles finer than 10 nm and to absorb UV-vis light shorter than the ZnSe bulk absorption wavelength of 460 nm. As the ratio of the reducing agent increases, the absorption wavelengths in the UV-vis curves are blue-shifted. Stirring in the atmosphere acts as a deterrent to the reduction reaction and formation of nanoparticles, but if not stirred in the atmosphere, the result is on par with synthesis in a nitrogen atmosphere. The stabilizer, TGA, has an impact on the Zn precursor synthesis. The fabricated nanoparticles exhibit excellent photo-absorption/discharge characteristics, suggesting that ZnSe nanoparticles can be alloyed without the need for organic solutions or high-temperature environments.

Development of Automatic Rewetting System for Rough Rice Stored in Round Steel Bin with Stirring Device -Adsorption characteristics of rough rice- (원형철제빈용 벼 자동흡습장치 개발에 관한 연구(I) -벼의 흡습특성-)

  • Kim, J. Y.;Keum, D. H.;Kim, H.;Park, S. H.
    • Journal of Biosystems Engineering
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    • v.26 no.5
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    • pp.469-474
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    • 2001
  • Milling the rice with low moisture requires more energy, produces more cracked rice, and results in reducing taste of cooked rice. Accordingly, it is necessary to add moisture to the rice with low moisture to obtain optimum moisture level for milling and taste of rice. This study was performed to evaluate the influence of initial moisture content and absorption rate on rice crack, milling energy and whiteness of milled rice and to obtain the information for design of rewetting system mounted on stirring device in grain bin. The tests were conducted for the four levels of initial moisture content in the range of 11.4 to 14.5%(w.b.) and six levels of absorption rate in the range of 0.04 to 1.0%, w.b./hr. In the case of lower moisture content below 12%(w.b.), crack ratios of brown rice were remarkably high regardless of initial moisture contents. Therefore, it was found that rough rice below 12%(w.b.) in initial moisture content could not rewetted by spraying water without crack generation of low level. Absorption rate must be below 0.3%, w.b./hr to maintain crack ratio increase of less than 1% regardless of initial moisture contents. In the case of allowable crack ratio increase of 2% and 5%, it was found that the maximum absorprion rate was respectively 0.6%, w.b./hr and 1.0%, w.b./hr in the initial moisture content of above 13.5%(w.b.). Rewetting the rough rice in moisture content of 11.4 to 14.5%(w.b.) to 14.3 to 16.9%(w.b.) decreased milling energy consumption by 15.9 to 22.3%. The effect of energy saving was higher in the samples of higher initial moisture content. Whiteness of milled rice was decreased by 0.5 to 1.5.

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Fan and Heater Management Schemes for Layer Filling and Mixing Drying of Rough Rice with Natural Air by Simulation (시뮬레이션에 의한 벼의 누적혼합 상온통풍건조의 송풍기 및 가열기의 운영방법에 관한 연구)

  • 금동혁;한충수;박춘우
    • Journal of Biosystems Engineering
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    • v.23 no.3
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    • pp.229-244
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    • 1998
  • This study was performed to determine proper fan and heater management schemes for natural air drying of rough rice in round steel bin with stirring device under Korean weather conditions. A computer simulation model was developed to predict moisture content changes, energy requirements, and drymatter losses during drying of rough rice by natural air. Drying test was conducted to validate the simulation model using round steel bin of holding capacity of 300ton at Rice Processing Complex in Jincheon. The bin was filled with rough rice every day and mixing by stirring device. Moisture contents, ambient air temperatures, relative humidities, static pressures in plenum chamber in the bin, airflow rates, and electrical and fuel energy were measured. Relative errors of moisture content changes predicted by the simulation model were below 5ft, and relative errors of final moisture content, final grain weight, required energy ranged from 0.9% to 6%. These not levels indicated that the simulation model can satisfactorily predict the performance factors of natural air drying system such as drying rates and energr consumptions comparing error level of 10% to 15% in other drying simulation models generally used in dryer desists. Twelve different fan and heater management schemes were evaluated using the computer simulation model based on three hourly weather data from Suweon for the period of 1952-1994. The best management schemes were selected comparing the drymatter losses, required drying times, required energy consumptions. Operating fan without heating only when ambient relative humidity was below 85% or 90% appeared to be the most effective method of In operation in favorable drying weather. Under adverse drying climates or to reduce required drying time, operating fan continuously, and heating air with $1.5^{\circ}C$ temperature rise only when ambient relative humidity was over 85% appeared to be the most suitable method.

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The Experimental Research for the Collecting Characteristics of the Passive and Active type Domestic Solar Hot Water Systems (자연형 및 설비형 태양열 온수기의 집열특성에 대한 실험적 연구)

  • Lee, Dong-Won;Lee, Kyoung-Ho
    • Journal of the Korean Solar Energy Society
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    • v.33 no.6
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    • pp.12-18
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    • 2013
  • Domestic solar hot water system can be divided into a passive type and an active type. In a passive type the storage tank is horizontally mounted immediately above the solar collectors. No pumping is required as the hot water naturally rises into the storage tank from the collectors through thermo-siphon flow. While, in an active type the storage tank is ground- or floor-mounted and is below the level of the collectors; a circulating pump moves water or heat transfer fluid between the storage tank and the collectors. We installed two types solar hot water systems consisting of the same storage tank and collectors at the same place, and were measured and compared typical operating characteristics under the same external conditions. In particular, the daily system performance was presented through the stirring test after the sunset. The results show that the amount of solar radiation obtained for an active type were less than a passive type on a cloudy day, because the operation of the circulation pump stops frequently took place on that day. However, on a sunny day, depending on the stable operation of the circulation pump, the amount of solar radiation obtained for an active type were increased than a passive type.

Technology Trend for Gas Hydrate Production Method by the Patent Analysis (특허 분석에 의한 가스 하이드레이트 제조 기술 동향)

  • Kang, Seong-Pil;Seo, Yu-Teak;Keum, Young-Sup;Ahn, Myung-Hee
    • Journal of Hydrogen and New Energy
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    • v.19 no.2
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    • pp.171-181
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    • 2008
  • There are several methods for the gas hydrate production such as spraying water with countercurrent gas flow, stirring water-gas mixture, and flowing water with micro-bubble, etc. These days it has been widely studied for the gas hydrate production method, having low energy consumption and high efficiency. In this paper, patents in the gas hydrate production method were gathered and analyzed. The search range was limited to the open patents of USA, European Union (EP), Japan (JP), and Korea (KR) from 1991 to 2007. Patents were gathered by using keywords searching and filtered by crucial criteria. The trends of the patents were analyzed by the years, countries, companies, and technologies.

A Experimental Study of the Kinetic Characteristics of Methane Hydrate (메탄 하이드레이트 동적특성에 대한 실험적 연구)

  • Kim, Nam-Jin;Chun, Won-Gee
    • Journal of the Korean Solar Energy Society
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    • v.26 no.2
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    • pp.19-25
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    • 2006
  • Methane hydrate, non-polluting new energy resource, satisfies requirement and considered as a precious resource that can prevent the global warming. Fortunately, there are abundant resources of methane hydrate distribute in the earth widely. Therefore, developing the techniques that can utilize these gases effectively is highly desired. The work in this paper here is to develop a skill which can transport and store methane hydrate. As a first step, the equilibrium experiment was carried out by increasing temperatures in the cell at fixed pressures. The influence of gas consumption rates under variable degree of subcooling, stirring and water injection has been investigated formation to clarify kinetic characteristics of the hydrate. The results of present investigation showed that the enhancements of the hydrate formation in terms of the gas/water ratio are closely related to operational pressure, temperature, degrees of subcooling, and water injection.

Competitive Extraction and Trace Analysis of BTEX and MTBE by Solid-Phase Microextraction (SPME) (고체상미량추출법을 이용한 BTEX와 MTBE의 경쟁적 추출효과 및 미량분석에 관한 연구)

  • An, Sang-Woo;Chun, Suk-Young;Lee, Si-Jin;Park, Jae-Woo;Chang, Soon-Woong
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.622-628
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    • 2010
  • In this study, Solid-phase microextraction (SPME) with GC/FID was studied as a possible alternative to liquid-liquid extraction for the analysis of BTEX and MTBE. Experimental parameters affecting the SPME process (such as kind of fibers, adsorption time, desorption time, volume ratio of sample to headspace, salt addition, and magnetic stirring) were optimized. Experimental parameters such as CAR/PDMS, adsorption time of 20 min, desorption time of 5 min at $250^{\circ}C$, headspace volume of 50 mL, sodium chloride (NaCl) concentration of 25% combined with magnetic stirring were selected in optimal experimental conditions for analysis of BTEX and MTBE. The general affinity of analytes to CAR/PDMS fiber was high in the order p-Xylene>Toluene>Ethylbenzene>MTBE>Benzene. The linearity of $R^2$ for BTEX and MTBE was from 0.970 to 0.999 when analyte concentration ranges from $30{\mu}g/L$ to $500{\mu}g/L$, respectively. The relative standard deviation (% RSD) were from 2.5% to 3.2% for concentration of $100{\mu}g/L$ (n=5), respectively. Finally, the limited of detection (LOD) observed in our study for BTEX and MTBE were from $7.5{\mu}g/L$ to $15{\mu}g/L$, respectively.