• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.32 no.1
• /
• pp.54-61
• /
• 2008

Integrated Gasification Combined Cycle (IGCC) power plant converts coal to syngas, which is mainly composed of hydrogen and carbon monoxide, by the gasification process and produces electric power by the gas and steam turbine combined cycle power plant. The purpose of this study is to investigate the influence of using syngas in a gas turbine, originally designed for natural gas fuel, on its performance. A commercial gas turbine is selected and variations of its performance characteristics due to adopting syngas is analyzed by simulating off-design gas turbine operation. Since the heating value of the syngas is lower, compared to natural gas, IGCC plants require much larger fuel flow rate. This increases the gas flow rate to the turbine and the pressure ratio, leading to far larger power output and higher thermal efficiency. Examination of using two different syngases reveals that the gas turbine performance varies much with the fuel composition.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.618-622
• /
• 2007

This paper provides RPF (Refuse Plastics Fuel) gasification characteristics for generating synthesis gas in gasfying reactor which was design in lab-scale. This research is carried out as an immediate work for making pyrolysis gas from RPF into energy resource. This study is consisted of experimental and numerical. The numerical study was accomplished from RPF pyrolysis data, and predicted the maximum operating conditions by STANJAN and FLEUNT. Based on results of STANJAN, it is found that the maximum point of $O_2/O_{2,stoich}$=20${\sim}$30, which is used as injection point of $O_2$. Experiment results shows that CO and $H_2$ were increased but THC was decreased as temperature was increased. It is estimated that the cracking of cracking of THC into CO and H2 is happened at a high temperature. It is observed that as steam was injected, production of CO and H2 were increased, then, H2 is dependent on the amount of injectionsteam.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.106.2-106.2
• /
• 2010

IGCC (Integrated Gasification Combined Cycle) plants are among the most advanced and effective systems for electric energy generation. From a control perspective, IGCC plants represent a significant challenge: complex reactions, highly integrated control to simultaneously satisfy production, controllability, operability and environmental objectives. While all these requirements seem clearly to demand a multivatiable, model predictive approach, not many applications can be easily found in the literature. This paper describes the IGCC dynamic simulation that is capable of simulating plant startup, shutdown, normal, and abnormal operation and engineering studies. This high fidelity dynamic models contain the detailed process design data to produce realistic responses to process operation and upset. And the simulation is used by engineers to evaluate the transient performance and produce graphical information indicating the response of the process under study conditions.

• 한국연소학회:학술대회논문집
• /
• 2012.11a
• /
• pp.147-148
• /
• 2012

The syngas produced from coal gasification is cooled down for gas cleaning by a syngas cooler that produces steam. Due to the presence of fly slag in the syngas, erosion, slagging and corrosion especially in the upper part of the syngas cooler may cause major operational problems. This study investigates the flow, heat transfer and particle behaviors in the syngas cooler of a 300MWe IGCC plant by using computational fluid dynamics. For various operational loads and geometry, the gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. In the evaporate channels inside the syngas cololr, the particle flows were concentrated more on the outer channel where slagging becomes more serious. The heat transfer to the wall was mainly by convection which was larger on the side wall below the inlet level.

• Clean Technology
• /
• v.19 no.3
• /
• pp.333-341
• /
• 2013

This paper presents results on $CO_2$ gasification of 17 raw coals containing a wide range of volatile matter (21-57 wt%). The gasification is performed using a TGA under $CO_2$ and also under $N_2$ atmosphere. An amount of weight loss with increasing temperature is proportional to that of volatile matter in a coal under $N_2$ atmosphere. Reactivity of $CO_2$ gasification also increases with a content of volatile matter. However, the correlation is a little scattered. Oxygenated functional groups in a coal are generally reactive and therefore, an increase in O/C ratio leads to enhanced reactivity. However, $CO_2$ reactivity is affected by neither H/C ratio nor a content of ashes that possibly activate the gasification reaction. These findings are also applicable to steam coal gasification and the reactivity series are confirmed in the test at a fixed bed reactor.

• Clean Technology
• /
• v.19 no.3
• /
• pp.226-232
• /
• 2013

A 5 kg/hr scale integral dual fluidized-bed gasifier for producing medium heating value syngas from biomass or combustible wastes was manufactured. The effect of operating variables including gasification temperature, rate of feeding, and weight ratio of steam/feed on the behavior of the gasifier was investigated. The contents of $H_2$ and CO in syngas, flow rate of feeding, cold gas efficiency increased with the increased gasification temperature or rate of feeding, but decreased with the increased weight ratio of steam/feed within the experimental range. With wood powder as the feed, the concentrations of $H_2$ and CO in the syngas were as high as 41% and 32%, and the cold gas efficiency and lower heating value of the syngas were as high as 70.1% and $3,428kcal/Nm^3$. With food wastes as the feed, the concentrations of $H_2$ and CO in the syngas were as high as 37% and 23.9%, and the cold gas efficiency and lower heating value of the syngas were as high as 66.7% and $3,670kcal/Nm^3$.

• Clean Technology
• /
• v.18 no.4
• /
• pp.426-431
• /
• 2012

Carbon-rich coal can be utilized as a fuel for direct carbon fuel cell (DCFC). However, left-behind ash after the electrochemical oxidation may hinder the electrochemical reactions. In this study, we produced ash-free coal (AFC) by thermal extraction and then tested it as a fuel for DCFC. DCFC was built based on solid oxide electrolyte and the electrochemical performance of AFC mixed with $K_2CO_3$ was compared with AFC only. Significantly enhanced power density was found by catalytic steam gasification of AFC. However, an increase of the power density by catalytic pyrolysis was negligible. This result indicated that a catalyst activated the steam gasification reactions, producing much more $H_2$ and thus increasing the power density, compared to AFC only. Results of a quantitative analysis showed much improved kinetics in AFC with $K_2CO_3$ in agreement with DCFC results. A secondary phase of potassium on yttria-stabilized zirconia (YSZ) surface was observed after the cell operation. This probably caused poor long-term behavior of AFC with $K_2CO_3$. A thin YSZ (30 ${\mu}m$ thick) was found to be higher in the power density than 0.9 mm of YSZ.

• Clean Technology
• /
• v.22 no.1
• /
• pp.53-61
• /
• 2016

Steam reforming of tar produced from biomass gasification was conducted using several Ni-based catalysts. In labscale, the catalytic steam reforming of toluene which is a major component of biomass tar was studied. A fixed bed reactor was used at various temperatures of 400-800 ℃. Ru (0.6 wt%) and Mn or K (1 wt%) were applied as a promoter in Ni based catalysts. Generally, Ni/Ru-K/Al₂O₃ catalyst shows higher performance on steam reforming of toluene than Ni/Ru-Mn/Al₂O₃ catalyst. Used catalysts were analyzed by XRD and TGA to detect sintering and carbon deposition. Base on the lab-scale studies, the monolith and pellet type catalysts were tested in 1 ton/day scale biomass gasification system. Ni/Ru-K/Al₂O₃ monolith catalyst shows high tar reforming performance at high temperature. In addition, Ni/Ru-Mn/Al₂O₃ monolith catalyst was showed deactivation with operation time. Reforming performance of Ni/Ru-K/Al₂O₃ pellet catalyst which showed 66.7% tar conversion at 587 ℃ was compared to regenerated one. Overall, Ni/Ru-K/Al₂O₃ pellet catalyst shows higher stability and performance than other used catalysts.

• Transactions of the Korean hydrogen and new energy society
• /
• v.21 no.5
• /
• pp.452-459
• /
• 2010

This study is aimed to investigate changes of combustion characteristics and heat efficiency when syngas from gasification process using low-rank fuel such as waste and/or biomass is applied partially to an industrial boiler. An experimental study on syngas co-combustion was performed in a 0.7 MW (1 ton steam/hr) water tube boiler using heavy oil as a main fuel. Three kinds of syngas were used as an alternative fuel: mixture gas of pure carbon monoxide and hydrogen, syngas of low calorific value generated from an air-blown gasification process, and syngas of high calorific value produced from an oxygen-blown gasification process. Effects of co-combustion ratio (0~20%) for each syngas on flue gas composition were investigated through syngas injection through the nozzles installed in the side wall of the boiler and measuring $O_2$, $CO_2$, CO and NOx concentrations in the flue gas. When syngas co-combustion was applied, injected syngas was observed to be burned completely and NOx concentration was decreased because nitrogen-containing-heavy oil was partially replaced by the syngas. However, heat efficiency of the boiler was observed to be decreased due to inert compounds in the syngas and the more significant decrease was found when syngas of lower calorific value was used. However, the decrease of the efficiency was under 10% of the heat replacement by syngas.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 2002.05a
• /
• pp.239-244
• /
• 2002

하수슬러지는 산업의 발달 및 인구의 증가로 인하여 증가하는 폐수의 양에 비례하여 증가하고 있다. 폐수 처리량과 함께 슬러지의 발생량은 1997년 이후 매년 3% 이상의 증가를 보이고 있다. 특히 최근에는 수질환경 개선 사업의 확대로 인하여 하수처리장이나 폐수처리장의 처리 용량은 매련 증가하고 있으며, 농축산 산업의 발달로 농촌지역의 농수산 폐수처리장의 시설용량의 증가로 슬러지 발생량 증가는 가속되어 2005년에는 연간 1000만톤 이상이 발생할 것으로 예측되고 있다.(중략)