• Title/Summary/Keyword: State-Dependence

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Site spectroscopy probing of Eu3+ incorporated into novel LiYxSryZrO3+α host matrix

  • Ahemen, I.;Dejene, F.B.
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1359-1367
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    • 2018
  • In this work, we investigated the spectroscopic properties of $LiY_xSr_yZrO_{3+{\alpha}:Eu^{3+}$, a red emitting nanophosphor based on $SrZrO_3$ perovskite. The synthesis process was an auto-combustion process. X-ray diffractograms show the orthorhombic structure of $SrZrO_3$. Photoluminescence (PL) excitation spectra display a split charge transfer band revealing the presence of two possible sites for the $Eu^{3+}$ ions. The emission spectra at 231 nm excitation illustrate the dominance of the $^5D_0-^7F_1$ transition, which is an indication that the smaller sized $Eu^{3+}$ ions are mostly situated at the more ordered (symmetric) $Sr^{2+}$ sites. The emission spectra at 292 nm & 397 nm excitations show the dominance of $^5D_0-^7F_2$ transition which suggests some of the $Eu^{3+}$ ions are also situated at the distorted $Zr^{4+}$ sites. Both the intensity parameters, asymmetry ratio and the decay lifetimes of the nanophosphors show dependence on $Y^{3+}$ concentration, signifying a modification in the host structure. Maximum quantum efficiency value of ${\approx}46%$ was obtained for the nanophosphors which indicate the need for improvement for practical applications. CIE coordinates show the suitability of this phosphor for both red emission in LED and as a complementary colour for white LED applications.

Photoluminescence properties of Mn4+-activated Li2ZnSn2O6 red phosphors

  • Choi, Byoung Su;Lee, Dong Hwa;Ryu, Jeong Ho;Cho, Hyun
    • Journal of Ceramic Processing Research
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    • v.20 no.1
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    • pp.80-83
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    • 2019
  • The Mn4+-activated Li2ZnSn2O6 (LZSO:Mn4+) red phosphors were synthesized by the solid-state reaction at temperatures of 1100-1400 ℃ in air. The synthesized LZSO:Mn4+ phosphors were confirmed to have a single hexagonal LZSO phase without the presence of any secondary phase formed by the Mn4+ addition. With near UV and blue excitation, the LZSO:Mn4+ phosphors exhibited a double band deep-red emission peaked at ~658 nm and ~673 nm due to the 2E → 4A2 transition of Mn4+ ion. PL emission intensity showed a strong dependence on the Mn4+ doping concentration and the 0.3 mol% Mn4+-doped LZSO phosphor produced the strongest PL emission intensity. Photoluminescence emission intensity was also found to be dependent on the calcination temperature and the optimal calcination temperature for the LZSO:Mn4+ phosphors was determined to be 1200 ℃. Dynamic light scattering (DLS) and field-effect scanning electron microscopy (FE-SEM) analysis revealed that the 0.3 mol% Mn4+-doped LZSO phosphor particles have an irregularly round shape and an average particle size of ~1.46 ㎛.

Explicit Dynamic Coordination Reinforcement Learning Based on Utility

  • Si, Huaiwei;Tan, Guozhen;Yuan, Yifu;peng, Yanfei;Li, Jianping
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.16 no.3
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    • pp.792-812
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    • 2022
  • Multi-agent systems often need to achieve the goal of learning more effectively for a task through coordination. Although the introduction of deep learning has addressed the state space problems, multi-agent learning remains infeasible because of the joint action spaces. Large-scale joint action spaces can be sparse according to implicit or explicit coordination structure, which can ensure reasonable coordination action through the coordination structure. In general, the multi-agent system is dynamic, which makes the relations among agents and the coordination structure are dynamic. Therefore, the explicit coordination structure can better represent the coordinative relationship among agents and achieve better coordination between agents. Inspired by the maximization of social group utility, we dynamically construct a factor graph as an explicit coordination structure to express the coordinative relationship according to the utility among agents and estimate the joint action values based on the local utility transfer among factor graphs. We present the application of such techniques in the scenario of multiple intelligent vehicle systems, where state space and action space are a problem and have too many interactions among agents. The results on the multiple intelligent vehicle systems demonstrate the efficiency and effectiveness of our proposed methods.

A Study on the Local Education Autonomy System in the United States in relation to the Educational Superintendent

  • Jong-Ryeol, Park;Sang-Ouk, Noe
    • Journal of the Korea Society of Computer and Information
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    • v.28 no.2
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    • pp.191-200
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    • 2023
  • The U.S. education policy making and execution process, in which residents can directly participate as members of state or local boards of education, without entrusting a small number of experts to decide on issues of sharply intertwined political interests, can be presumed that it played a role in preventing conflicts and disputes that may arise due to differences of opinion or differences in the interpretation of laws and regulations between subjects. Such a consensus system in the United States suggests a supplementary point to the local education administration system in Korea, where conflicts between various educational entities are occurring because of the current excessive dependence on one superintendent of education.

Effect of Initial Textures on the Plane Strain Stretching (판재의 초기집합조직이 평면변형률 스트레칭 변형에 미치는 영향)

  • Bae, Seok-Yong;Lee, Yong-Sin
    • Transactions of Materials Processing
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    • v.7 no.5
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    • pp.459-464
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    • 1998
  • Effect of the several initial textures such as random texture, rolling texture and cube texture, on the plane strain stretching was studied by interpretation of the finite element method. The calculation of yield locus indicated that the sheet oriented in the cube texture exhibits easy yielding on uniaxial stress state whereas the sheet having either a random or the rolling texture exhibits easy yielding on shear deformation. Upon stretching tests, the thickness strain at the center region contacting the punch was identical regardless of the initial textures while the dependence of the thickness strain on the initial texture was found in the other regions. In general punch loads required or the sheet with an initial cube texture was as expected from calculated yield locus, lower than those for the others.

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Effects of Strain Rate and Temperature on the Hot Strength for Single Phase Cu-Zn Alloy (단상조직을 갖는 Cu-Zn합금의 고온강도에 미치는 변형속도와 온도의 영향)

  • 권용환;유연철
    • Transactions of Materials Processing
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    • v.4 no.2
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    • pp.159-168
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    • 1995
  • The torsion tests in the range of $550~800^{\circ}C$, $5.0{\times}10^{-3}~5.0{\times}10^0/sec$ were performed to study the effects of strain rate$(\.{\varepsilon})$ and temperature(T) on the hot strength of Cu-Zn alloy. High temperature flow stresses of this alloy increased with increasing $\.{\varepsilon}$ and/or decreasing T, and than the more grain refinement could be obtained. The flow curves exhibited a peak followed by a steady steady state regime as a result of dynamic recrystallization. The hot strength dependence of $\.{\varepsilon}$ and T was described by a hyperbolic sine law, $\.{\varepsilon}=A(sinh0.017{\sigma})^4.81$exp(-216KJ/mol). Hot strength could be reduced at the arbitary condition, $\.{\varepsilon}$ and T, by constitutive parameter Z(Zenner-Hollomon parameter), $Z=A(sinh{\alpha}{\sigma})^n=\.{\varepsilon}$exp(Q/RT).

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A study on the stress dependence of diffusion coefficient at the elevated tenperature and the structural characterictics of 12% Cr rotor steel. (12% Cr강의 고온 확산계수의 응력의존성과 조직의 특성에 관한 연구)

  • 장윤석;김태형
    • Journal of Ocean Engineering and Technology
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    • v.11 no.2
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    • pp.39-47
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    • 1997
  • Creep rate the elevated temperature is known to be controller by the softening process of microstructure especially in the solid solution alloys such as 125 Cr rotor steel. The change of structure is a decreasing process of the free energy of the state including stress, diffusivity of the material, and tmeperature. This study shows that diffusion coefficient, D of 12% Cr rotor steel at 953K with 74.8 MPa is 1.084~3.140*$10^{15}mm^2sec^1$ compared to $1.658*10^{24}mm^2sec^1$at 963K without stress. During creep, the growth of martensite laths accelerates the diffusion coefficient under stress due to incoherency of interface between carbides and matrix.

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Effect of Resin Finishing on the Physical Properties of the Knitted Fabrics (수지처리가 환편 니트 소재의 물성에 미치는 영향)

  • Kwon Young-Ah;Park Jong-Sik
    • Textile Coloration and Finishing
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    • v.18 no.3 s.88
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    • pp.23-30
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    • 2006
  • The bending properties, wrinkle resistance, and fabric retention behaviors of cotton knitted fabrics in the wale and course directions were studied for their dependence upon resin finishing, knit structure, and washing cycles. Stiffness, wrinkle recovery angles, and dimensional stability were investigated before and after resin finishing and laundering. It has been found that any change in the physical properties of the knitted fabrics with respect to knit structure and fabric directions are related to accompanying modifications to the state of the fiber properties. The decrease of fabric shrinkage rates and wrinkle recovery properties from increasing laundering cycles is related with resin incorporated on the fiber surface. This study shows that resin finishing on knitted fabrics can be performed only to improve fabric retention properties with reduced wrinkle recovery properties.

Bereavement Care in Hospice and Palliative Care (호스피스.완화의료에서의 사별 돌봄)

  • Kim, Chang-Gon
    • Journal of Hospice and Palliative Care
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    • v.10 no.3
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    • pp.120-127
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    • 2007
  • Bereavement is the state of loss resulting from death. Grief is the emotional response associated with loss, intense and acute sorrow resulting from loss. Complicated grief represent a pathological outcome involving social, physical, emotional, cognitive, spiritual morbidity. The common psychiatric disorders associated complicated grief or abnormal grief responses include clinical depression, anxiety disorders, alcohol abuse or other substance abuse, and dependence, psychotic disorders, and post-traumatic stress disorder (PTSD). Grief tasks involve a series of stage or phases following an important loss that gradually permit adjustment and recovery. Three phases of grief involve phase 1 (walking the edges), phase 2 (entering the depths), and phase 3 (reconnecting the world). For intervention to be effective they need to be individually tailored to abnormal grief reaction or unresolved grief reaction. Clear understandings of complicated grief, abnormal responses, factors increasing risk after bereavement will often enable us to prevent psychiatric disorders in bereaved patients.

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Pt-and $TiO_2-doped\; Nb_2O_5$ Thin Film by Ion-Beam-Enhanced Deposition

  • Zhu, Jianzhong;Ren, Congxin
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.100-105
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    • 1998
  • This paper describes the preparation of Pt-and $TiO_2$-doped $Nb_2O_5$ thin film by Ion-Beam-Enhanced Deposition. Platinum and titanium doping, and Nb2O5 deposition were carried out in situ. The dependence of oxygen sensing properties on the amounts of Pt and Ti dopant in the $Nb_2O_5$ film was investigated. There were the highist sensitivity, the lowest temperature coefficient and the shortest responce time at doping of 5 mol% $TiO_2$ and 0.3 mol%Pt

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