• Title/Summary/Keyword: State-Dependence

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Coherent director rotation and memory effects, and their dependence on the morphology of the constituent molecules in thiol-ene polymer stabilized ferroelectric liquid crystal system

  • Lim, Tong-Kun;Lee, Ji-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.199-202
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    • 2005
  • We have studied the origin of coherent director rotation [CDR] as well as memory behavior in thiol-ene polymer stabilized ferroelectric liquid crystal [FLC]. The ene constituents are found to be always located at the inter-layer space and induce the coherent director rotation motion of liquid crystal molecule. On the other hand, the thiols are more intersticed between ferroelectric liquid crystal molecules at intra-layer as the thiol gets longer, and these intersticed thiols enhance the multistability and the resolution of memory state of FLCs.

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Kinetics of Reversible Consecutive Reactions

  • Park, Tae Jun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.243-245
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    • 2013
  • Rate equations are exactly solved for the reversible consecutive reaction of the first-order and the time-dependence of concentrations is analytically determined for species in the reaction. With the assumption of pseudo first-order reaction, the calculation applies and determines the concentration of product accurately and explicitly as a function of time in the unimolecular decomposition of Lindemann and in the enzyme catalysis of Michaelis-Menten whose rate laws have been approximated in terms of reactant concentrations by the steady-state approximation.

Intercepting Filter Approach to Injection Flaws

  • Salem, Ahmed
    • Journal of Information Processing Systems
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    • v.6 no.4
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    • pp.563-574
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    • 2010
  • The growing number of web applications in the global economy has made it critically important to develop secure and reliable software to support the economy's increasing dependence on web-based systems. We propose an intercepting filter approach to mitigate the risk of injection flaw exploitation- one of the most dangerous methods of attacking web applications. The proposed approach can be implemented in Java or .NET environments following the intercepting filter design pattern. This paper provides examples to illustrate the proposed approach.

A Nonlinear Transformation Approach to Adaptive Output Feedback Control of Uncertain Nonlinear Systems

  • Ahn, Choon-Ki;Kim, Beom-Soo;Lim, Myo-Taeg
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.48.1-48
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    • 2001
  • In this paper, we present a global adaptive output feedback control scheme for a class of uncertain nonlinear systems to which adaptive observer backstepping method may not be applicable directly. The allowed output feedback structure includes quadratic and multiplicative dependency of unmeasured states. Our novel design technique employs a change of coordinates and adaptive backstepping. With these proposed tools, we can remove linear and quadratic dependence on the unmeasured states in the state equation. Also, the multiplication of the two unmeasured states can be eliminated ...

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Analysis of Complex Forced Raleigh Scattering Decay Profiles for the Diffusion of Methyl Yellow in Binary Solution

  • 박하선;성정문;이현정;장태현;Daniel R. Spiegal
    • Bulletin of the Korean Chemical Society
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    • v.18 no.9
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    • pp.1006-1010
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    • 1997
  • The nature and analysis methods of complicated decay profiles found in forced Rayleigh scattering (FRS) have been investigated for the probe diffusion of methyl yellow in 2-propanol. The complementary shifted and ground state grating effect, which is known to be the origin of non-single exponential decays, was analyzed by non-linear regression fitting to a double exponential model function. We confirmed that the parameters were highly correlated so that it was difficult to extract a unique set of parameters in the presence of experimental noise. Nevertheless, a reasonable range of decay time constants could be estimated from the grating spacing dependence.

Structure-Activity Relationship Study on Cephalosporins with Mechanism-based Descriptors

  • Jun-Ho Choi;Hojing Kim
    • Bulletin of the Korean Chemical Society
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    • v.14 no.5
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    • pp.631-635
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    • 1993
  • The polarizability and the transition state energy of a cephalosporin are assumed to be theoretical indices of the permeability through the outer membrane and of reactivity of ${\beta}$ -lactam ring with penicillin binding proteins, respectively, in Gram-negative bacteria. They are computed by AM1 method and used as variables of quantitative structure-activity relationship study. The results justify quadratic dependence of the activity on the variables. The intersection of difference volumes between $\beta-lactamase$ stable cephalosporins and unstable ones manifests that the steric hindrance of 7-side chain is responsible for the ${\beta}$ -lactamase stability.

RHEOLOGICAL PROPERTIES OF MAGNETIC PARTICLE SUSPENSIONS

  • Kwon, T.M.;Choi, H.J.;Jhon, M.S.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.667-671
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    • 1995
  • The viscometric technique is used to study the effects of microstructure on the viscosity (viscosity vs. concentration or shear rate) of magnetic particle suspensions. In this characterization, measurement of suspension viscosity is used to obtain the dependence of viscous energy dissipation on microstructural state of dispersions. Microstructural shape effects which are related to particle orientation are then indirectly obtained. Empirical formulas from mean field theory and the Mooney equation, which are applicable at high concentration of magnetic particles, are used to relate viscosity to particle concentration. The validity and physical meaning of these equations are discussed.

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Quantum Mechanical Study of the O(1D) + HCl → OH + Cl Reaction

  • Lin, Shi-Ying;Park, Seung-C.
    • Bulletin of the Korean Chemical Society
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    • v.23 no.2
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    • pp.229-240
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    • 2002
  • Quantum mechanical calculation is performed for the $O(^1D)$ + HCl ${\rightarrow}$OH + Cl reaction using Reactive Infinite Order Sudden Approximation. Shifting approximation is also employed for the l ${\neq}$ 0 partial wave contributions. Various dynamical quantities are calculated and compared with available experimental results and quasiclassical trajectory results. Vibrational distributions agree well with experimental results i.e. product states mostly populated at $v_f$ = 3, 4. Our results also show small peak at $v_f$ = 0, which indicates bimodal vibrational distribution. The results show two significant broad peaks in ${\gamma}_i$ dependence of the cross section, one is at ${\gamma}_i$ = $15^{\circ}-35^{\circ}$ and the another is at ${\gamma}_i$= $55^{\circ}-75^{\circ}$ which can be explained as steric effects. At smaller gi, the distribution is peaked only at higher state ($v_f$ = 3, 4) while at the larger gi, both lower state ($v_f$ = 0) and higher state ($v_f$ = 3, 4) are significantly populated. Such two competing contributions (smaller and larger ${\gamma}_i$) result in the bimodal distribution. From these points we suggest two mechanisms underlying in current reaction system: one is that reaction occurs in a direct way, while the another is that reaction occurs in a indirect way.

SWR as Tool for Determination of the Surface Magnetic Anisotropy Energy Constant

  • Maksymowicz, L.J.;Lubecka, M.;Jablonski, R.
    • Journal of Magnetics
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    • v.3 no.4
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    • pp.105-111
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    • 1998
  • The low energy excitations of spin waves (SWR) in thin films can be used for determination of the surface anisotropy constant and the nonhomogeneities of magnetization in the close-to-surface layer. The dispersion relation in SWR is sensitive on the geometry of experiment. We report on temperature dependence of surface magnetic anisotropy energy constant in magnetic semiconductor thin films of$ CdCr_{2-2x}In_{2x}Se_4$ at spin glass state. Samples were deposited by rf sputtering technique on Corning glass substrate in controlled temperature conditions. Coexistence of the infinite ferromagnetic network (IFN) and finite spin slusters (FSC) in spin glass state (SG) is know phenomena. Some behavior typical for long range magnetic ordering is expected in samples at SG state. The spin wave resonance experiment (microwave spectrometer at X-band) with excited surface modes was applied to describe the energy state of surface spins. We determined the surface magnetic anisotropy energy constant versus temperature using the surface inhomogeneities model of magnetic thin films. It was found that two components contribute to the surface magnetic anisotropy energy. One originates from the exchange interaction term due to the lack of translation symmetry for surface spin as well as from the originates from the exchange interaction term due to the lack of translation symmetry for surface spin as well as from the stray field of the surface roughness. The second one comes from the demagnetizing field of close-to surface layer with grad M. Both term linearly decrease when temperature is increased from 5 to 123 K, but dominant contribution is from the first component.

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Novel Approach for Modeling Wireless Fading Channels Using a Finite State Markov Chain

  • Salam, Ahmed Abdul;Sheriff, Ray;Al-Araji, Saleh;Mezher, Kahtan;Nasir, Qassim
    • ETRI Journal
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    • v.39 no.5
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    • pp.718-728
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    • 2017
  • Empirical modeling of wireless fading channels using common schemes such as autoregression and the finite state Markov chain (FSMC) is investigated. The conceptual background of both channel structures and the establishment of their mutual dependence in a confined manner are presented. The novel contribution lies in the proposal of a new approach for deriving the state transition probabilities borrowed from economic disciplines, which has not been studied so far with respect to the modeling of FSMC wireless fading channels. The proposed approach is based on equal portioning of the received signal-to-noise ratio, realized by using an alternative probability construction that was initially highlighted by Tauchen. The associated statistical procedure shows that a first-order FSMC with a limited number of channel states can satisfactorily approximate fading. The computational overheads of the proposed technique are analyzed and proven to be less demanding compared to the conventional FSMC approach based on the level crossing rate. Simulations confirm the analytical results and promising performance of the new channel model based on the Tauchen approach without extra complexity costs.