• Title/Summary/Keyword: State-Dependence

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Photoisomerization of Symmetric Carbocyanines

  • 민형식;강유남;박정희
    • Bulletin of the Korean Chemical Society
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    • v.19 no.7
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    • pp.747-753
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    • 1998
  • The phoisomerization process of symmetric carbocyanine dyes such as 3,3'-diethyloxadicarbocyanine iodide (DODCI), 3,3'-diethylthiadicarbocyanine iodide (DfDCI), 1,1'-diethyl-2,2'-dicarbocyanine iodide (DDI), 1,1'-diethyl-2,2'-carbocyanine iodide (DCI), and cryptocyanine (1,1'-diethyl-4,4'-carbocyanine) iodide (CCI) have been studied by measuring the steady state and time resolved fluorescence spectra and the ground-state recovery profiles. The steady-state fluorescence spectrum of photoisomer as a function of concentration and excitation wavelength provides the evidence that the fluorescence of photoisomer is formed by the radiative energy transfer from the normal form and the quantum yield for the formation of photoisomer is increased by decreasing the excitation wavelength. The fluorescence decay profiles have been measured by using the time correlated single photon counting (TCSPC) technique, showing a strong dependence on the concentration and the detection wavelength, which is due to the formation of excited photoisomers produced either by the radiative energy transfer from the non-nal form or by absorbing the 590 nm laser pulse. We first report the fluorescence decay time of photoisomers for these cyanine dyes. The experimental results are explained by introducing the semiempirical calculations. The ground state recovery profiles of DTDCI, DDI, and CCI normal forms have been measured, showing that the recovery time from the singlet excited state is similar with the fluorescence decay time.

Kinetic Study on the Low-lying Excited States of Ga Atoms in Ar

  • Kuntack Lee;Ju Seon Goo;Ja Kang Ku
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.663-669
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    • 1994
  • Decay kinetics of Ga(5s), Ga(5p) and Ga(4d) atoms in Ar were studied by laser induced fluorescence technique. Theground state gallium atoms in the gas phase were generated by pulsed dc discharge of trimethyl gallium and argon mixtures. Both pulsed discharge and YAG-DYE laser system were controlled by a dual channel pulse generator and the delay time between the end of discharge and laser pulses was set 3.0-6.0 ms. The Ga(5s) and Ga(4d) atoms were generated by single photon excitation from the ground state Ga atoms and radiative lifetimes as well as the total quenching rate constants in Ar were obtained from the pressure dependence of the fluorescence decay rates. The Ga(5p) atoms were populated by a two-photon excitation method and the cascade fluorescence from Ga(5s) atoms were analyzed to extract quenching rate constant of Ga(5p) atoms by Ar in addition to radiative lifetimes of Ga(5p) state. The magnitudes of the quenching rate constants by Ar for the low-lying excited states of Ga atoms are 1.6-3$ {\times}10^{-11}cm^3$ molecul$e^{-1}s^{-1}$, which are much larger than those for alkali, alkaline earth and Group 12 metals. Based on the measured rate constants, kinetic simulations were done to assign state-to-state rate constants.

Design of a Rotary Electromagnetic Actuator with Linear Torque Output for Fast Steering Mirror

  • Long, Yongjun;Mo, Jinqiu;Chen, Xinshu;Liang, Qinghua;Shang, Yaguang;Wang, Shigang
    • Journal of Magnetics
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    • v.20 no.1
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    • pp.69-78
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    • 2015
  • This paper focuses on the design of a flux-biased rotary electromagnetic actuator with compact structure for fast steering mirror (FSM). The actuator has high force density and its torque output shows linear dependence on both excitation current and rotation angle. Benefiting from a new electromagnetic topology, no additional axial force is generated and an armature with small moment of inertia is achieved. To improve modeling accuracy, the actuator is modeled with flux leakage taken into account. In order to achieve an FSM with good performance, a design methodology is presented. The methodology aims to achieve a balance between torque output, torque density and required coil magnetomotive force. By using the design methodology, the actuator which will be used to drive our FSM is achieved. The finite element simulation results validate the design results, along with the concept design, magnetic analysis and torque output model.

Dynamic Model Considering the Biases in SP Panel data (SP 패널데이터의 Bias를 고려한 동적모델)

  • 남궁문;성수련;최기주;이백진
    • Journal of Korean Society of Transportation
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    • v.18 no.6
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    • pp.63-75
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    • 2000
  • Stated Preference (SP) data has been regarded as more useful than Revealed Preference (RP) data, because researchers can investigate the respondents\` Preference and attitude for a traffic condition or a new traffic system by using the SP data. However, the SP data has two bias: the first one is the bias inherent in SP data and the latter one is the attrition bias in SP panel data. If the biases do not corrected, the choice model using SP data may predict a erroneous future demand. In this Paper, six route choice models are constructed to deal with the SP biases, and. these six models are classified into cross-sectional models (model I∼IH) and dynamic models (model IV∼VI) From the six models. some remarkable results are obtained. The cross-sectional model that incorporate RP choice results of responders with SP cross-sectional model can correct the biases inherent in SP data, and also the dynamic models can consider the temporal variations of the effectiveness of state dependence in SP responses by assuming a simple exponential function of the state dependence. WESML method that use the estimated attrition probability is also adopted to correct the attrition bias in SP Panel data. The results can be contributed to the dynamic modeling of SP Panel data and also useful to predict more exact demand.

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Temporal Epidemiological Assessment of Colorectal Cancer Incidence and Mortality in East Kazakhstan, 2004-2013

  • Zhabagin, Kuantkan;Igissinov, Nurbek;Manambayeva, Zukhra;Adylkhanov, Tasbolat;Sandybayev, Marat;Nurgazin, Murat;Massadykov, Adilzhan;Tanatarov, Sayat;Aldyngurov, Daniyar;Urazalina, Nailya;Abiltayeva, Aizhan;Baissalbayeva, Ainoor;Zhabagina, Almagul;Sabitova, Dinara;Zhumykbayeva, Nurgul;Kenbayeva, Dinara;Rakhimbekov, Alexander
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.15
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    • pp.6413-6416
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    • 2015
  • Colorectal cancer incidence and mortality in Kazakhstan are relatively high but exact statistics have hitherto been lacking and trends over time are unclear. The present study was therefore undertaken to retrospectively assess data for East Kazakhstan, accessed from the central registration office, for the period 2004-2013. Approximate age standardized data for incidence and mortality were generated and compared across age groups, gender and year. It was determined that during the studied period 3,417 new cases of colorectal cancer were registered and 2,259 died of this pathology. Average cancer cancer incidence and mortality over the ten years were $24.1/10^5$ and $15.9/10^5$ respectively, and the overall ratio of mortality/incidence (M/I) was 0.69:1 (range 0.58-0.73). Both incidence and mortality tended to remain constant in both males and females. The male to female ratios also did not significantly vary over time but a trend for improvement of the mortality to incidence ratio was observed, especially for rectum. Whether this might be related to screening remains unclear. These preliminary data indicate that whereas colorectal cancer continues to be important, change in environmental factors are not having a great impact on incidence in East Kazakhstan.

From a Developmentalist Welfare State to a Social Investment State: A Case Study of Japan (발전주의 복지국가에서 사회투자국가로: 일본 사례를 중심으로)

  • Kwon, Soon-mee
    • 한국사회정책
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    • v.25 no.1
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    • pp.231-257
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    • 2018
  • Japan has generally been considered as the developmentalist welfare state. However, Japan has recently been transformed into a social investment state. Although it still has a developmentalist characteristics with its institutional path dependence, the new social and economic challenges derived from the new social risks such as low birth rates and aging population forced Japan to adopt a new welfare state strategy. The paradigm shift in terms of welfare state strategy was launched by the Third Way positioning of the Democratic party government and succeed to the Second Stage of Abenomics under the Third Abe Cabinet. This paper argues that the welfare state paradigm shift towards a social investment state in Japan is not limited to the Japan's Plan for Dynamic Engagement of All Citizens for a virtuous cycle of growth and distribution, but expands its scope to include the work-family balance policies such as labor market activation for women and public caring for children.

The Topology of Galaxy Clustering in the Sloan Digital Sky Survey Main Galaxy Sample: a Test for Galaxy Formation Models

  • Choi, Yun-Young;Park, Chang-Bom;Kim, Ju-Han;Weinberg, David H.;Kim, Sung-Soo S.;Gott III, J. Richard;Vogeley, Michael S.
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.82-82
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    • 2010
  • We measure the topology of the galaxy distribution using the Seventh Data Release of the Sloan Digital Sky Survey (SDSS DR7), examining the dependence of galaxy clustering topology on galaxy properties. The observational results are used to test galaxy formation models. A volume-limited sample defined by Mr<-20.19 enables us to measure the genus curve with amplitude of G=378 at 6h-1Mpc smoothing scale, with 4.8% uncertainty including all systematics and cosmic variance. The clustering topology over the smoothing length interval from 6 to 10h-1Mpc reveals a mild scale-dependence for the shift and void abundance (A_V) parameters of the genus curve. We find strong bias in the topology of galaxy clustering with respect to the predicted topology of the matter distribution, which is also scale-dependent. The luminosity dependence of galaxy clustering topology discovered by Park et al. (2005) is confirmed: the distribution of relatively brighter galaxies shows a greater prevalence of isolated clusters and more percolated voids. We find that galaxy clustering topology depends also on morphology and color. Even though early (late)-type galaxies show topology similar to that of red (blue) galaxies, the morphology dependence of topology is not identical to the color dependence. In particular, the void abundance parameter A_V depends on morphology more strongly than on color. We test five galaxy assignment schemes applied to cosmological N-body simulations to generate mock galaxies: the Halo-Galaxy one-to-one Correspondence (HGC) model, the Halo Occupation Distribution (HOD) model, and three implementations of Semi-Analytic Models (SAMs). None of the models reproduces all aspects of the observed clustering topology; the deviations vary from one model to another but include statistically significant discrepancies in the abundance of isolated voids or isolated clusters and the amplitude and overall shift of the genus curve. SAM predictions of the topology color-dependence are usually correct in sign but incorrect in magnitude.

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Comparisons of Magnetic and Magneto-Optic Properties between Fe-rich and Nd-rich Amorphous $Nd_xFe_{1-x} $Alloys

  • Kim, Jae-Young;Kim, Jeoung-Hoon;Oh, Hyun-Woo
    • Journal of Magnetics
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    • v.3 no.2
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    • pp.49-54
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    • 1998
  • Dependence of magnetic and magneto-optic properties on composition of amorphous NdFe alloys has been studied to identify a promising magneto-optic recording material in the wavelength of a blue laser beam. From the view point of crystallographic state, perpendicular magnetic anisotropy energy and polar Kerr rotation angle, the Nd-rich region was found to be suitable for the research purpose.

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Synthesis and characterization of orange-yellow phosphor for inorganic EL device

  • Chang, Mi-Youn;Lee, You-Hui;Han, Sang-Do;Khatkar, S.P.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1334-1337
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    • 2005
  • Orange-yellow phosphor has been synthesized by solid-state method for inorganic EL devices. Zinc sulfide is used as host material for the phosphor and the phosphor consists of copper and manganese as activators. The dependence of the photoluminescence (PL) and electroluminescence(EL) properties on the copper and manganese concentrations has been investigated.

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