• 공업화학
• /
• 제25권2호
• /
• pp.198-203
• /
• 2014

본 연구에서는 Ni metal foam 플레이트의 수증기 개질반응 및 표면 특성을 조사하였다. 전처리를 통하여 Ni의 산화상태를 변화시킬 수 있었으며, 활성 site로서 표면에 노출된 metallic Ni 종은 수증기 개질 반응활성에 중요한 역할을 한다. 또한 Ni metal foam 플레이트의 기공제어 및 촉매 기능을 부여하기 위하여 Ni metal foam 플레이트와 Ni-YSZ 촉매를 혼합하여 다공성 촉매 분리막을 제조하였다. SEM 분석 결과 metal foam 플레이트의 기공을 제어할 수 있었으며, 표면에 Ni-YSZ 촉매는 고르게 잘 분포되어 있었다. Ni 기반 다공성 촉매 분리막은 공간속도에 상관없이 상용촉매와 유사한 수증기 개질 활성을 가진다.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2010년도 제34회 춘계학술대회논문집
• /
• pp.190-193
• /
• 2010

고성능 액체로켓의 핵심 요소인 고압 연소기에 사용되는 분사기에 대한 혼합 및 연소 특성을 도출하기 위하여 초임계 상태에 적용되는 혼합 및 연소모델을 수치적으로 연구하였다. 난류모델은 LES(Large Eddy Simulation)를 기반으로 하였고, 난류연소모델은 혼합분율(Z)을 이용한 Laminar Flamelet Model을 사용하였다. 그리고 초임계 영역의 상태량을 계산하기위해 Soave Redlich-Kwong 상태 방정식, 점성계수와 열전도도에 대하여 Chung이 제안한 고압상태 혼합물에 대한 방정식, 확산계수에 대하여 Fuller 이론에 Takahashi가 제안한 고압상태의 특징을 고려한 식을 적용하였다. 계산결과는 선행연구자의 결과와 비교하였고, LOx post 후방에 발생되는 와류에 따른 보염영역에 대하여 연구하였다.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2011년도 제36회 춘계학술대회논문집
• /
• pp.430-432
• /
• 2011

희박 예혼합 가스터빈에서 발생되는 연소 불안정 현상의 메커니즘을 규명하기 위하여 입구 속도 변동에 대한 열발생 변동을 정량화한 화염 전달 함수가 실험적으로 규현되었다. 이를 위하여 실제 가스 터빈과 유사한 형태를 갖는 모형 연소기가 제작되었으며, 열발생율의 측정을 위한 가시화 연소기가 장착되었다. 또한 흡기 속도의 변조를 위하여 가변 속도 모터 및 유량 제어 장치가 설계되었고, 이러한 장치들을 통하여 입구 속도 변동이 열발생율의 진폭에 미치는 영향 및 화염 구조의 변화를 실험적으로 계측하였다.

• Steel and Composite Structures
• /
• 제43권3호
• /
• pp.389-401
• /
• 2022

This study investigated the flowability and mechanical properties of cost-effective steel fiber reinforced ultra-high performance concrete (UHPC) by using locally available materials for field-cast application. To examine the effect of mixture constituents, five mixtures with different fractions of silica fume, silica powder, ground granulated blast furnace slag (GGBS), silica sand, and crushed natural sand were proportionally prepared. Comprehensive experiments for different mixture designs were conducted to evaluate the fresh- and hardened-state properties of self-consolidating UHPC. The results showed that the proposed UHPC had similar mechanical properties compared with conventional UHPC while the flow retention over time was enhanced so that the field-cast application seemed appropriately cost-effective. The self-consolidating UHPC with high flowability and low viscosity takes less total mixing time than conventional UHPC up to 6.7 times. The X-ray computed tomographic imaging was performed to investigate the steel fiber distribution inside the UHPC by visualizing the spatial distribution of steel fibers well. Finally, the tensile stress-strain curve for the proposed UHPC was proposed for the implementation to the structural analysis and design.

• 한국분무공학회지
• /
• 제22권3호
• /
• pp.137-145
• /
• 2017

This paper describes numerical modeling of transcritical and supercritical fluid flows within a liquid propellant rocket engine. In the present paper, turbulence is modeled by standard $k-{\varepsilon}$ model. A conserved scalar approach in conjunction with multi-environment probability density function model is used to account for the turbulent mixing of real-fluids in the transcritical and supercritical region. The two real-fluid equations of state and dense-fluid correction schemes for mixtures are used to construct thermodynamic data library based on the conserved scalar. In this study, calculations are made on two cryogenic nitrogen jets under different chamber pressures. Sensitivity analysis for two different real-fluid equations of sate is particularly emphasized. Based on numerical results, precise structures of cryogenic nitrogen jets are discussed in detail. Numerical results show that the current real-fluid model can predict the essential features of the cryogenic liquid nitrogen jets.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2007년도 추계학술대회 논문집
• /
• pp.394-395
• /
• 2007

In order to make full color cholesteric displays, color filter-less R, G, B sub-pixel structured cholesteric LC cells have been studied. To make R, G, B colors, UV induced pitch variant chiral dopant was added to cholesteric LC mixtures. The concentration of the photo-sensitive chiral dopant was adjusted so that the initial state showed blue color and the color was changed from blue to green and red with increase of UV irradiation to the cholesteric cells. To prevent the mixing of R, G, B reflective sub-pixel liquid crystals, separation walls were formed using negative photo resister in boundary area between sub-pixels. Through the optimization of the material concentrations and UV irradiation condition, vivid R, G, B colors were achieved.

• 한국소음진동공학회논문집
• /
• 제20권3호
• /
• pp.215-222
• /
• 2010

Long and slender body, like a fuel rod, oscillating in axial flow can be unstabilized even by the small cross flow which can be activated by the flow mixer or turbulent generator. It is important to include these effects of flow disturbance in dynamic stability analysis of nuclear fuel rod. This work shows how eigen frequency of a multi-span fuel rod can be changed by the swirl flow, which is discretely generated by a flow mixer. By solving a state-space form of the eigenvalue equation for a multi-span fuel rod system, the critical velocity at which a fuel rod becomes unstable was calculated. Based on the simulation results, we evaluated how stability of a multi-spanned nuclear fuel rod with mixing vanes can be affected by the coolant flow in an operating reactor core.

• 한국터널지하공간학회 논문집
• /
• 제4권3호
• /
• pp.195-205
• /
• 2002

터널에서의 배면공동은 설계 시공 유지관리중 다양한 원인들이 복합적으로 작용하여 발생하게 된다. 특히, 터널 천단부 라이닝 부분에는 콘크리트 타설후 재료분리 등으로 인해 터널 천단부에 배면공동이 발생이 되는데, 이러한 터널 배면공동은 라이닝 균열, 누수 등과 밀접한 연관이 있는 것으로 밝혀지고 있다. 본 연구는 석산에서 발생되는 석분을 이용하여 터널 배면공동 및 지하공동의 충전용 모르타르를 개발하고 이를 노후터널에 적용함으로서 개발재료의 현장적용성 등에 대한 시험을 수행하였다.

• 한국세라믹학회지
• /
• 제33권12호
• /
• pp.1301-1310
• /
• 1996

Generally it requires high sintering temperatures more than 135$0^{\circ}C$ to make semiconductive BaTiO3 ceramics. Also it is very difficult to achieve a homogeneous mixing in solid-state reaction method. Therefore the liquid phase distributed to non-uniform dilute the characteristics of PTCR. In order to improve the uniformity this study is used the sol-gel coating method. Using this method we studied the new manufacturing process that had a high reproducibility and mass production capability. Tetraethyl orthosilicate (TEOS) was used as a source of Si. The semiconductive BaTiO3 ceramics which was produced by sol-gel method for the SiO2 addition and sintered between 124$0^{\circ}C$ and 130$0^{\circ}C$ showed almost same resistivity at room temperature among 125$0^{\circ}C$ and 130$0^{\circ}C$. As the results We could be sintered the semiconducting BaTiO3 ceramics at lower temperature even at 125$0^{\circ}C$ maintaining the same specific resistivity ratio ($\rho$max/$\rho$min) at 130$0^{\circ}C$. The specific resistivity both below and above the Curie temperature were increased by slow cooling and the steepness of the plots in the reasion of transition from low to high resistance increased as the cooling rate decreased.

• Journal of Korean Society for Atmospheric Environment
• /
• 제22권E1호
• /
• pp.9-18
• /
• 2006

Aerosol hygroscopic properties were measured by a tandem differential mobility analyzer (TDMA) system during the Aerosol Characterization Experiment (ACE)-Asia campaign from 31 March to 1 May 2001. Two high flow differential mobility analyzers (DMAs) were used to maximize the count rate on board the Center for Interdisciplinary Remotely Piloted Aircraft (CIRPAS) Twin Otter aircraft. Hygroscopic growth factor distributions of particles having initial dry nanoparticle diameters of 0.040, 0.059, 0.086, 0.126, 0.186, 0.273, 0.400, and $0.586{\mu}m$ were measured during 19 research flights. Data collected during 12 of those flights were used to investigate aerosol mixing state and the influence of aerosol source region on size-resolved hygroscopicity. The uniformity in size-resolved hygroscopicity was quantified to facilitate comparison between measurements made in different air masses. Hygroscopic growth factors are strongly dependent on source region and sizes. Mean hygroscopic growth factors were observed to be greatest when the air mass origin was from the south. The mean growth factors for continental sources decreased with initial size from 1.47 to 1.27 for $0.040{\mu}m\;and\;0.586{\mu}m$, but increased with initial size from 1.44 to 1.8 for $0.040{\mu}m\;and\;0.400{\mu}m$ dry diameters for marine sources.