• Title/Summary/Keyword: State of Mixing

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Recycling Natural Rubber Vulcanizates through Mechanochemical Devulcanization

  • Jang G. K.;Das C. K.
    • Macromolecular Research
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    • v.13 no.1
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    • pp.30-38
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    • 2005
  • Sulfur-cured gum natural rubber vulcanizates were devulcanized using two different concentrations of diallyl disulfide. The devulcanization process was performed at $110^{\circ}C$ min in an open two-roll cracker-cum-mixing mill. Natural rubber vulcanizates having various sulfur/accelerator ratios were used to study the cleavage of monosulfide, disulfide, and polysulfide bonds. The properties of devulcanized natural rubber increased upon increasing the disulfide concentration and the mechanical properties of the revulcanized natural rubber increased upon decreasing the sulfur content in the original rubber vulcanizates. The scorch time and the maximum state of cure both increased when the ground vulcanizates were treated with higher amounts of disulfide. TGA and DMA were conducted to study the effects of the devulcanization on the thermal stability and the $T_g$ behavior of the vulcanizates. SEM analysis was conducted to study how the failure mechanism was affected by the devulcanization process. It was possible to recover $70-80\%$ of the original gum rubber properties by using this process. From IR spectroscopic analysis, we observed that the oxidation of the main chains did not occur during high-temperature milling.

Research on Liquefaction Characteristics of SF6 Substitute Gases

  • Yuan, Zhikang;Tu, Youping;Wang, Cong;Qin, Sichen;Chen, Geng
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2545-2552
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    • 2018
  • $SF_6$ has been widely used in high voltage power equipment, such as gas insulated switchgear (GIS) and gas insulated transmission line (GIL), because of its excellent insulation and arc extinguishing performance. However, $SF_6$ faces two environmental problems: greenhouse effect and high liquefaction temperature. Therefore, to find the $SF_6$ substitute gases has become a research hotspot in recent years. In this paper, the liquefaction characteristics of $SF_6$ substitute gases were studied. Peng-Robinson equation of state with the van der Waals mixing rule (PR-vdW model) was used to calculate the dew point temperature of the binary gas mixtures, with $SF_6$, $C_3F_8$, $c-C_4F_8$, $CF_3I$ or $C_4F_7N$ as the insulating gas and $N_2$ or $CO_2$ as the buffer gas. The sequence of the dew point temperatures of the binary gas mixtures under the same pressure and composition ratio was obtained. $SF_6/N_2$ < $SF_6/CO_2$ < $C_3F_8/N_2$ < $C_3F_8/CO_2$ < $CF_3I/N_2$ < $CF_3I/CO_2$ < $c-C_4F_8/N_2$ < $C_4F_7N/N_2$ < $c-C_4F_8/CO_2$ < $C_4F_7N/CO_2$. $SF_6/N_2$ gas mixture showed the best temperature adaptability and $C_4F_7N/CO_2$ gas mixture showed the worst temperature adaptability. Furthermore, the dew point temperatures of the $SF_6$ substitute gases at different pressures and the upper limits of the insulating gas mole fraction at $-30^{\circ}C$, $-20^{\circ}C$ and $-10^{\circ}C$ were obtained. The results would supply sufficient data support for GIS/GIL operators and researchers.

A Study of Thermal Effects for a Half-Circumferential Grooved Journal Bearing (半圓周形 윤활홈을 갖는 저어널 베어링의 熱效果에 관한 연구)

  • Chun, Sang-Myung;Lalas, Demetrius P.
    • Tribology and Lubricants
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    • v.6 no.1
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    • pp.36-51
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    • 1990
  • A parametric study of the thermal effects of a half-circumferential grooved journal bearings under aligned and misaligned conditions has been carried out by solving numerically the coupled Reynolds and energy equation system. Five different sets of boundary conditions for the energy equation have been used which include mixing between recirculating oil and inlet oil and a contraction ratio for the cavitation region. The effects of changes of the inlet oil temperature and pressure, the wall temperature and the L/D ratio have also been examined. For the range of parameters found in internal combustion engines, the mixing effectiveness at the groove and the resulting final mixture temperature have been found to be as important as the wall temperature and the heat transfer rate. The variability of the temperature, though, has been shown to smooth out the peaks of both pressure and friction during misaligned condition Distributions of friction and pressure in the oil are also examined which may be useful in attempts to reduce friction without reducing load. Results for an axial grooved bearing are also presentsed for comparision purpose.

Consideration on Usability of Modified Sulfur of Low-Slump Concrete (저슬럼프 콘크리트의 개질유황 사용성에 대한 검토)

  • Shin, Hyo-Chul;Kim, Gyu-Yong;Kim, Jung-Hyun;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.109-110
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    • 2015
  • In this study, fresh state properties and mechanical properties of low slump concrete which is applied to road pavement have been evaluated by mixing modified sulfur. As results, influence of mixing modified sulfur on the workability was low. Also, compressive strength, and flexural strength tend to decrese with increasing addition rate of modified sulfur. However compressive strength, and flexural strength of modified sulfur concrete were equivalent with that of plain concrete.

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Phase Equilibrium of Binary Mixture for the (propylene oxide + 1-pentanol) System at Several Temperatures

  • Kim, Jeong-lae;Kim, Hakmin;Park, Su In;An, Gyu Min;Kim, Min Gi;Shin, Moon Sam
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.73-77
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    • 2019
  • Isothermal (vapor + liquid) equilibrium data measurements were undertaken for the binary mixtures of (propylene oxide + 1-pentanol) system at three different temperatures (303.15, 318.15, and 333.15) K. The Peng-Robinson-Stryjek-Vera equation of state (PRSV EOS) was used to correlate the experimental data. The van der Waals one-fluid mixing rule was used for the vapor phase and the Wong-Sandler mixing rule, which incorporates the non-random two liquid (NRTL) model, the universal quasi-chemical (UNIQUAC) model and the Wilson model, was used for the liquid phase. The experimental data were in good agreement with the correlation results.

A Study on the Fertilizer Applicability of Sludge from Nightsoil Treatment Plant (위생(衛生) 처리장(處理場) 슬러지의 비료화(肥料化)에 관(關)한 연구(硏究))

  • Lee, Chan-Ki;Han, Chun-Ho
    • Journal of Industrial Technology
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    • v.3
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    • pp.75-85
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    • 1983
  • This study is conducted to provide useful fertilizer or soil conditioner of sludge from nightsoil treatment plant. Several possibilities present themselves. The major sink for disposal of waste sludge is the land, and in this case values will be measured primarily in terms of agricultural benefits. According to the result of sludge drying experiment, the drying rate with mixing once a day was more increased by three times than the state without mixing. And in sludge, N was 7-9%, P was 0.85-4.14%, and coliform groups in dried sludge were 75 MPN/gr.

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Architecture of SIP-based Effective Hybrid-type Multimedia Conference (SIP 기반의 효율적인 혼성형 멀티미디어 컨퍼런스 구조)

  • Lee, Ki-Soo;Jang, Choon-Seo;Jo, Hyun-Gyu
    • The Journal of the Korea Contents Association
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    • v.7 no.3
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    • pp.17-24
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    • 2007
  • SIP-based tightly coupled conference, which has a centrally located conference server for controlling and management, can be classified several models according to location of focus and mixer. These are centralized server model, endpoint server model, media server component model and distributed mixing model. However each model has its strength and weakness. In this paper, we propose and implement a SIP-based effective hybrid-type conference model which decreases amount of SIP signaling messages, lowers load of server media mixer, and can be easily expandable to large scale conference. In this model, when the number of participants exceeds a pre-defined limit, the conference server selects some participants which posses specific functions and let them share functions of notifications of conference state event package and media mixing. When each participant subscribes conference state event package to the server, it can indicates its possession of such functions by a specific header message. The server stores the indication to the conference information database, and later uses it to select participants for load sharing. The performance of our proposed model is evaluated by experiments.

Modeling and analysis of an LDPE autoclave reactor with axial dispersion

  • Park, Seung-Koo;Wi, Jeong-Ho;Rhee, Hyun-Ku
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10b
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    • pp.1693-1698
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    • 1991
  • An axial dispersion model is developed for the slim reactor employed in the LDPE autoclave process so that imperfect mixing caused by large L/D ratio (10-20) may be quantified by Peclet number. The model is then used to investigate the effect of mixing on the reactor performance represented by the monomer conversion, the reactor temperature, the molecular weight, and the polydispersity. In addition, the existence of steady state multiplicity is identified with the initiator feed concentration or the feed temperature as the bifurcation parameter. The effects of the initiator feed concentration and the feed temperature are also examined.

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Roughness effect on performance of a multistage axial compressor (다단 축류압축기의 표면조도가 성능에 미치는 영향)

  • Han, Kyung-ho;Kang, Young-seok;Kang, Shin-hyoung
    • 유체기계공업학회:학술대회논문집
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    • 2002.12a
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    • pp.264-270
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    • 2002
  • This paper presents roughness effects on flow characteristics and efficiency of multi-stage axial compressor using numerical simulation. which is carried out with a commercially available software, CFX-TASCflow. In this paper, the third of four stages of GE low pressure compressor is considered including me stator and rue rotor. Mixing-plane approach is adopted to model the interface between the stator and the rotor: it is appropriate for steady state simulation. First, a flat plate simulation was performed to validate how exact the numerical simulation predicts the roughness effect for smooth and rough walls. Then GE compressor model was calculated about at each roughness height. Concluding, very small roughness height largely affects the performance of compressor and the increasing rate of loss decrease as roughness height increase.

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Mixed Structure Effect of Fuel and Air on Rotary Kiln Burner Flame (연료 및 공기의 혼합구조가 로타리 킬른 용 버너 화염에 미치는 영향)

  • Kim, Youngho;Lee, Cheolwoo;Kim, Insu;Lim, Youngbin
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.339-342
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    • 2014
  • Rotary kiln produces lime from limestone through thermal decomposition. Ring formation in kiln internal wall is known issue that decreases productivity. The cause of ring formation is temperature imbalance as flame leans toward upper wall. Therefore, burner nozzle geometry was changed to improve air-fuel mixing state which leads to prevention of ring formation. CFD simulation and experimental test were performed in this study to investigate the effect of air-fuel mixing on flame structure, temperature and $NO_X$ concentration. It is shown that combustion efficiency has been enhanced and $NO_X$ concentration has been decreased by using swirl flow for secondary combustion air. It's also shown that flame has been straightened by using straight flow for secondary combustion air.

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