• 제목/요약/키워드: Stainless-steel

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PEMFC용 분리판 표면코팅 및 부식성 평가 (Surface Coating and Corrosion Characteristics of Bipolar Plates of PEMFC Application)

  • 강경민;김동묵;최정식;차인수;윤영훈
    • 한국수소및신에너지학회논문집
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    • 제22권2호
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    • pp.199-205
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    • 2011
  • Stainless steel 304 and 316 plates were deposited with the multi-layered coatings of titanium film (0.1 um) and gold film (1-2 um) by an electron beam evaporation method. The XRD patterns of the stainless steel plates modified with the multi-layered coatings showed the crystalline phases of the external gold film and the stainless steel substrate. Surface microstructural morphologies of the stainless steel bipolar plates modified with multi-layered coatings were observed by AFM and FE-SEM images. The external gold films formed on the stainless steel plates showed micro structure of grains of about 100 nm diameter. The grain size of the external surface of the stainless steel plates increased with the gold film thickness. The electrical resistance and water contact angle of the stainless steel bipolar plates covered with multi-layered coatings were examined with the thickness of the external gold film.

소형선박용 스테인리스강 축의 음극방식 응용 (Optimum Cathodic Protection for Stainless Steel Shaft of Small-Size Boat)

  • 배일용;박정대;강대선;이명훈;김기준
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 후기학술대회논문집
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    • pp.232-233
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    • 2005
  • Stainless steel has been stably used closed by passivity oxidation films($Cr_2O_3$) is made by neutral atmospheric environment. However, passivity oxidation films of the surface of stainless steel occasionally comes to be destroyed in seawater which is influenced by an environment having halogen ion like $Cl^-$, then, localization corrosion comes to occur. Stainless steel 304 for shaft system material of the small-size FRP fishing boat on seawater environments made an experiment on simulation of sacrifical anode(Al, Zn). Through these experiment and study, following results have been obtained ; According to the field inspection and corrosion simulation, the corrosion on the 2nd class stainless steel shaft(STS 304) in FRP fishing boat has been verified to occur by crevice corrosion and galvanic corrosion etc.. According to the comparison and analysis of Stainless steel 304 shaft materials after simulation leaving unprotected and applying cathodic protection, unprotected shaft specimen of stainless steel 304 was severely corroded, but, protected shaft specimen was not totally corroded. This result is assumed to be made by the facts that anodic reaction, $Fe{\rightarrow}Fe^{2+}$ + $2e^-$, has been restricted by the cathodic protection current of sacrificial anode material.

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TIG 용접된 스테인리스강의 수소영향에 대한 연구 (Study on Hydrogen Effect in TIG Welded Stainless Steel)

  • 이진경;이상필;배동수;이준현
    • 동력기계공학회지
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    • 제20권6호
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    • pp.58-63
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    • 2016
  • A stainless steel has high corrosion resistance because of nickel in material, so it is used as materials for transportation and storage of hydrogen. In this study, TIG(tungsten ingot gas) welding was carried out on the stainless steel using the storage vessel of hydrogen. The microscopic structures at each region of TIG welded material such as HAZ, weld and base metals using optical microscope were observed. And the damage behavior of stainless steel that underwent the hydrogen charging using nondestructive evaluation was also studied. Ultrasonic test, which is the most generalized nondestructive technique, was applied to evaluate the relationship between the ultrasonic wave and mechanical properties at each zone of TIG welded stainless steel. The velocity and attenuation coefficients of ultrasonic wave didn't show a remarkable difference at each region of welded stainless steel. However, the attenuation coefficient was the highest at the weld zone when hydrogen charged stainless steel. In addition, acoustic emission test was also used to study the dynamic behavior of stainless steel experienced both hydrogen charging and weld. Lots of AE event at elastic region of stress-strain curve were occurred both the hydrogen charged specimen and the free specimen.

Type 316N 스테인리스강의 OPR1000 및 APR1400 가압기 밀림관 적용성에 대한 연구 (A Study on Applicability of Stainless Steel Type 316N to the PZR Surge-line of OPR1000 and APR1400)

  • 유완;정성훈;박성호;손갑헌;이봉상;김민철
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.287-292
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    • 2008
  • The applicability of stainless steel type 316N to the PZR surge-lines of OPR1000 and APR1400 is investigated. So far, strainless steel type 347 has been used for the OPR1000 surge-lines. The degree of improvement in the leak-before-break(LBB) and component design margin is evaluated when stainless steel type 347 is substituted by type 316N. For the study, the tensile and J-R tests on type 316N and type 347 stainless steels were performed at 316 and the microstructure of both types was examined. Stainless steel type 316N shows the higher values on the stress-strain curves, J-R curves and stress intensity, Sm, compared to those of type 347. Therefore, stainless steel type 316N ensures the higher LBB and component design margins. As a result, this study shows that stainless steel type 316N could substitute type 347 for the surge-lines of OPR1000 and APR1400.

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알루미늄 용융 도금된 304 스테인리스강의 해수 내 전기화학적 부식 특성 평가 (Evaluation of Electrochemical Corrosion Characteristics for Hot-Dip Aluminized 304 Stainless Steel in Seawater)

  • 정상옥;박일초;한민수;김성종
    • 한국표면공학회지
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    • 제48권6호
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    • pp.354-359
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    • 2015
  • Stainless steel has poor corrosion resistance in marine environment due to the breakdown of a passive film caused by chloride. It suffers electrochemical corrosion like pitting corrosion, crevice corrosion, and stress corrosion crack (SCC) in marine environment. In general, it indicates that the passive film of $Al_2O_3$ has better corrosion resistance than that of $Cr_2O_3$ in seawater. This paper investigated the damage behavior 304 stainless steel and hot-dip aluminized 304 stainless steel in seawater solution. Various electrochemical experiments were carried out including potential measurement, potentiodynaimic experiment, Tafel analysis and galvanostatic experiment. As a result of anodic polarization experiment, higher pitting damage depth was indicated at 304 stainless steel than hot-dip aluminized 304 stainless steel. In addition, relatively higher corrosion current density was shown at hot-dip aluminized stainless steel as a result of Tafel analysis.

스테인리스강관과 일반구조용강관 단주내력 비교에 관한 연구 (A Comparison Study on Strength of Stainless Steel Tube and Steel Tube Stub-columns)

  • 장호주;유재희;양영성
    • 한국강구조학회 논문집
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    • 제15권5호통권66호
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    • pp.561-570
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    • 2003
  • 본 논문은 스테인리스강관과 일반구조용강관의 비교를 통한 스테인리스 강관의 건축구조용 강재로서 적용성 검토를 위해, 폭(지름)-두께비, 단면형상을 주요 변수로 한 소재의 인장강도실험과 단주의 압축강도실험을 실시하여 소재의 기계적 성질과 단주의 강도 및 거동을 파악한다. 실험결과, 스테인리스강관은일반구조용 강관에 비해 인장내력, 항복비, 연신율, 에너지흡수능력 등이 월등히 우수한 것으로 나타났다. 항복내력 또한 KS규격 항복강도 $2.1tf/cm^2$ 나 일본 스테인리스설계기준강도 $2.4tf/cm^2$ 을 충분히 만족한 값으로 일반구조용 강판보다 더 높은 값을 보였다. 스테인리스 각형강관은 일반구조용 각형강관에 비해 폭-두께비의 제한값을 초과하는 경우에도 국부좌굴에 의한 급격한 내력저하 없이 연성적인 거동을 보이나 소성가공에 의한 영향은 폭-두께비가 증가하면서 더 많이 받는 것으로 나타났으며, 스테인리스 원형강관은 일반구조용 원형강관보다 지름-두께비가 증가함에 따라 국부좌굴과 소성가공의 영향을 더 적게 받는 것으로 나타났다. 소성변형능력 또한 일반구조용 강관에 비해 스테인리스 강관이 우수하게 나타났다.

Development and Application of High-Cr Ferritic Stainless Steels as Building Exterior Materials

  • Kim, Yeong H.;Lee, Yong H.;Lee, Yong D.
    • Corrosion Science and Technology
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    • 제7권6호
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    • pp.324-327
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    • 2008
  • Stainless steels have been widely used as a building exterior materials in Asian countries for the last decade. It is required for the materials in this field to have an aesthetic appearance, a relatively high strength, and an excellent corrosion resistance. Other metallic materials such as copper, aluminum, and carbon steels have been also used as the exterior materials. Considering the cost of maintenance, stainless steel, having the outstanding corrosion resistance, is replacing other materials in the several parts in the building exteriors. Ferritic stainless steel has been applied as the roofing materials because its thermal expansion is much smaller than that of austenitic stainless steel. Therefore, it is suitable for the large-scale construction such as airport terminal, convention center, and football stadium. To improve the corrosion resistance of the ferritic stainless steels, the modification of alloy composition has been studied to develop new grade materials and the progress in the surface technology has been introduced. Corrosion properties of these materials were evaluated in the laboratory and in the field for longer than two years. High-Cr ferritic stainless steel showed excellent corrosion resistance to the atmospheric environments. In the region close to the sea, the corrosion resistance of high-Cr ferritic stainless steel was much superior to that of other materials, which may prove this steel to be the appropriate materials for the construction around seashore. In some of the large constructions around seashore in South Korea, high-Cr ferritic stainless steels have been used as the building exterior materials for six years.

열간압연으로 제조된 STS 304L/A516-70N과 STS 316L/A516-70N 클래드재들의 미세조직에 대한 비교 연구 (Comparative Study on Microstructures of Hot-rolled STS 304L/A516-70N and STS 316L/A516-70N Clad Plates)

  • 진주찬;조수철;심호섭;이영국
    • 열처리공학회지
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    • 제34권4호
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    • pp.171-178
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    • 2021
  • In the present study, we comparatively investigated the microstructures of two hot-rolled stainless steel clad plates; STS 304L - low carbon steel A516-70N and STS 316L - A516-70N. The STS 304L/A516-70N clad plate (Clad_304L_Ni) had a Ni-interlayer between stainless steel and carbon steel and a 90 ㎛ thick deformation band of unrecrystallized austenite grains on the stainless steel. The STS 316L/A516-70N clad plate (Clad_316L) had no interlayer and almost fully recrystallized austenite grains. Clad_304L_Ni exhibited the thinner a decarburized layer in carbon steel and a total carburized layer in stainless steel than Clad_316L. However, a severely carburized layer in stainless steel was thicker for Clad_304L_Ni than Clad_316L. Hardness profiles near the interface of clad plates matched well with microstructures at locations where the hardness values were measured.

Crevice Corrosion Resistance of Stainless Steels in Natural Sea Water with different Post Welding Treatment

  • Lee, Y.H.;Kim, Y.H.;Kim, H.
    • Corrosion Science and Technology
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    • 제2권5호
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    • pp.219-224
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    • 2003
  • Crevice corrosion of stainless steels in natural seawater was investigated for several post weld treatments; as-annealed, as-welded, pickled, and ground. The results confirmed the effect of the biofilm on the cathodic reaction leading to an ennoblement of the rest potential. The degree of ennoblement of corrosion potential depends on the surface finish. As-annealed and pickled samples show stable corrosion potential approaching to 200 ~ 300 mV (SCE) while as-welded and ground samples show the fluctuating corrosion potential. This points to a situation where there are conflicting effects determining the trend in free corrosion potential. Crevice corrosion initiation will tend to pull the free corrosion potential in the active direction, whereas the presence of biofilm will tend to ennoble corrosion potential. There was no visible attack on UNS S31803, S32550, and 2205W. Therefore, those stainless steel grades appeared to be resistant to crevice corrosion in natural seawater on condition of weld metal.

Nb 첨가 오스테나이트계 스테인레스강의 연속주조시 표면크랙 형성기구 및 제어 (Formation Mechanism of Surface Crack and Its Control on Continuously Cast Slabs of Nb-containing Austenitic Stainless Steel)

  • 심상대;김선구
    • 한국주조공학회지
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    • 제21권5호
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    • pp.280-285
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    • 2001
  • Nb-containing austenitic stainless steel is widely used as exhaust frame and diffuser assembly in power plant. However, this steel is known to be difficult to produce by the continuous casting process due to the surface cracks. Therefore, the continuous casting technology was developed for the prevention of the surface cracks on CC slabs. Precipitates and the analysis of heat trasfer in a slab were investigated in order to find out the formation mechanism of surface cracks on cc slabs It was found that surface cracks are occurred due to the NbC precipitates, which are formed along the grain boundaries around $800^{\circ}C$. The secondary cooling pattern has been developed to produce the defect free CC slabs of Nb-containing austenitic stainless steel.

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