• Corrosion Science and Technology
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• v.5 no.4
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• pp.129-136
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• 2006

High temperature corrosion behavior of AISI-type 316L stainless steel for the MCFC(molten carbonate fuel cell) bipolar application was studied by immersion test and penetration attack method in anode environment ($650^{\circ}C$, $Li_2CO_3/K_2CO_3=62/38$ mol%, $H_2/CO_2=80/20$ vol%) without or with different $CaCO_3$ content. Not only immersion test method but also morphological observation of samples in the carbonate melts are adopted as experimental methods. With aid of the morphological observation of cross section of samples immersed in a carbonate melt was possible to obtain penetration attack. The concentration effect of $CaCO_3$ inhibitor was investigated in order to verify the optimum concentration for practical application in MCFC stack operation. The corrosion rate in the presence of $CaCO_3$ was proven to be decreased as a function of $CaCO_3$ concentration. The corrosion rate in the presence of $CaCO_3$ was measured with a value of 6.9 mpy which is 2.4 times lower than that of inhibitor-free electrolyte. The cross section microscopy revealed that the internal penetration by oxidation in molten carbonate is very severe. In this case, the attack was occurred not only dissolution loss in the electrolyte by corrosion reaction but also weight gain through oxide layer by internal penetration.

• Journal of Pharmaceutical Investigation
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• v.37 no.1
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• pp.7-13
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• 2007

To produce stable polymer coating layer using the interaction between metal stent and polymer layer, Ahx-HSAB was synthesized by coupling 6-aminoheanoic acid (Ahx) with N-Hydroxy succinimidyl 4-azidobenzonate (HSAB) containing photo reactive group. Then, Ahx-HSAB was applied to self·assembled monolayer (SAM) on $TiO_2$-coated surface, since one end of Ahx-HSAB was carboxyl acid which was known to be able to interact with $TiO_2$ surface. That SAM layer was incubated in 1% polycaprolacton (PCL) solution and photoreacted by ultraviolet light (254 nm) to produce the chemical bond between SAM and polymer layer, followed by PCL polymer coating ({\sim}5\;{\mu}m$) by the method of spray coating. The surface change was investigated by measuring of contact angle of the surface. The contact angle values of stainless steel (SS) surface, $TiO_2$-coated surface, SAM layer by Ahx-HSAB, photoreacted surface with PCL and PCL layer by spray coating were 70.48${\pm}$1.89, 38.57${\pm}$3.31, 60.14${\pm}$2.21, 54.91${\pm}$2.70 and 56.47${\pm}$2.12, respectively. The stability of polymer layers was tested by incubation of PCL-coated plates in 0.1M PBS buffer (pH 7.4, 0.05%, Tween 80) with vigorous shaking (200 rpm). While the poiymer layer prepared by these processes showed the intact surface morphology over 3 days, the polymer layers prepared by spray coating of PCL onto SS plate (control 1) and $TiO_2$-coated SS plate (control 2) were Peeled off in 3 days. Thus, the polymer coating method using SAM and photoreaction seems to be a effective method to obtain the stable polymer layer onto SS surface.

• Nuclear Engineering and Technology
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• v.17 no.1
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• pp.25-33
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• 1985

The main purpose of this work is to investigate the effects of the wall thickness, the ultrasonic frequency, and the acoustic impedance of wall material on the liquid-film thickness measurement by an ultrasonic pulse echo method. A series of liquid-film thickness measurements in a horizontal air-water stratified system was performed employing a plate-type and a tube-type test sections. Measurements were repeated changing (1) the wall thickness of the test section and (2) the transducer frequency. Also, in an effort to improve the accuracy of the measurement and to exam me the effect of acoustic impedance of wall material on the measurement by an ultrasonic technique, two different stand-off rods, one made of stainless steel and the other polyacrylate, were used in the liquid-film thickness measurement. These experimental results are discussed and compared with the actual film thicknesses.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.20 no.1
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• pp.25-31
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• 2024

The core shroud of rector vessel internals (RVI) of OPR1000 and ARP1400 is made of Type 304 stainless steel (SS) by bending and welding process that may induce high deformation and residual stress in manufacturing. This work aims to evaluate the susceptibility of stress corrosion crack (SCC) initiation of bent parts of RVI in high temperature primary water environment. For SCC initiation test, tensile specimens were fabricated from the 90 degree bent plate of Type 304 SS (DT specimen), that is an archived part of a Korean APR1400. After the SCC initiation test, the specimen surface was thoroughly examined by optical and scanning electron microscopy, and compared to the specimen fabricated from the as-received plate of Type 304 SS (AR specimen). The surface observation revealed that SCC initiated on the AR specimen surface in typical intergranular (IG) mode, while SCC on the DT specimen occurred in transgrannular mode as well as IG mode. It was also found that the size and number of SCC on the DT specimen were larger than that on the AR specimen. This was attributable to a strain-hardening during the bending process. To compare the susceptibility of SCC initiation, total crack density (TCD) was calculated from the total crack length divided by the measured area of AR and DT specimens. TCD of DT specimen was 4.6 times higher than AR specimen in average, indicating that higher possibility of degradation of bent parts of RVI for a long-term operation.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.757-762
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• 2002

Many reports have been shown that the buoyancy, electromagnetic force, surface tension, and gas shear stress are the driving forces of weld pool circulation in arc welding. Among them, the surface tension of molten metal plays an important role in the flow in weld pool, which are clarified by the specially designed experiments with small particles as well as the numerical simulations. The surface tension is also related to the penetration in arc welding. Therefore, a quantitative evaluation of surface tension is demanded for the development of materials and arc process control. However, there are few available data published on the surface tension of molten metals, since it depends on the temperature and the composition of materials. In this study, a new method was proposed for the evaluation of surface tension and its temperature dependence, in which it is evaluated by the equilibrium condition of acting forces under a given surface geometry, especially back surface. When this method was applied to the water pool and to the back surface of molten pool in the stationary gas tungsten arc welding of thin plate, following results were obtained. In the evaluation of surface tension of water, it was shown that the back surface geometry was very sensitive to the evaluation of surface tension and the evaluated value coincided with the surface tension of water. In the measurement of molten pool in the stationary gas tungsten arc welding, it was also shown that the comparison between the surface tension and temperature distribution across the back surface gave the temperature dependent surface tension. Applying this method to the mild steel and stainless steel plates, the surface tension with negative gradient for temperature is obtained. The evaluated values are well matched with ones in the published papers.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.2
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• pp.106-113
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• 2011

This paper was conducted on experimental analysis in the free vibration analysis of rectangular plates under uniform thermal loading. Materials of three rectangular plates were aluminum, steel and stainless-steel respectively. The dimension of rectangular plates was 0.1 $\times$ 0.1 $\times$ 0.002 m. Infrared quartz lamps were used for thermal loading. The PCS(Power Control System) electric control system was applied for control and scanning vibrometer (Poly Tech) was used for acquisition of frequency response function. Applied temperature was increased from room temperature to $300^{\circ}C$ by $50^{\circ}C$. Boundary condition was free-free condition using bungee cord. Front face of rectangular plate was heated uniformly.

• Journal of Yeungnam Medical Science
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• v.7 no.1
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• pp.81-93
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• 1990

The author fractographically analyized the cause of metal failure(the first time this procedure has been used for this metal failure)and also analyized it clinically. In this study, I selected eight cases which have been analyized fractographically. In all these cases, the analysis was done after treatment of metal failure of implants internally fixed to femur shaft fractures at the Department of Orthopedic Surgery, Yeung-Nam University Hospital during the six year period from May 1983 to September 1989. 1. Metal failure occured in five dynamic-compression plates, one Jewett nail, one screw in Rowe plate, and one interlocking nail. 2. The clinical cause of metal failure was deficiency of medial butress in five cases, incorrect position of implant in one case, and incorrect selection of implant in two cases. 3. The time interval between internal fixation and metal failure was four months in one case, between five months to twelve months in six cases, three years in one case. 4. The fractographically analytical cause of metal failure was ; first, impact failure, one case, second, fatigue failure, six cases, machining mark(stress liser), four cases type : low consistent cyclic fatigue failure irregular cyclic fatigue failure third, stress corrosion crack, one case. 5. 316L Stainless Steel has good resistance to corrosion. However, when its peculiar surface film is destroyed by fretting, it shows pitting corrosion. This is, perhaps, the main cause of metal failure. 6. It is possible that mechanical injury occured in implants during the manufacturing of implants or that making a screw hole is the main cause of metal failure.

• Journal of the Korean Society for Nondestructive Testing
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• v.26 no.5
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• pp.297-305
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• 2006

The thermal ratcheting deformation at the reactor baffle and upper internal structure of the liquid metal reactor (LMR) can occur due to movement of the hot sodium free surface. In in-service inspection of reactor internals of LMR, a new inspection technique should be developed for the detection of the thermal ratcheting damage. In this study, an inspection technique using ultrasonic guided wave is proposed for the detection of the thermal ratcheting damage of cylindrical vessels. A 316L stainless steel cylindrical shell specimen has been prepared. The thermal ratchet structural tests were cyclically performed by heat-up up to $550^{\circ}C$ with steep temperature gradients along the axial direction after cool-down by cooling water. Ultrasonic guided wave propagation has been characterized by analysis of dispersion curve of the stainless steel plate. The zero-order antisymmetric $A_0$ guided wave has been selected as the optimal mode for detection of the ratcheting deformation. It is confirmed that the thermal ratcheting deformation can be detected by the measurement of transit time difference of circumferentially propagated $A_0$ guided waves.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.2
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• pp.251-264
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• 2000

Organic removal from synthetic wastewater by electrochemical methods was investigated with various operating parameters, such as current density, retention time, electrode gap and $Cl^-/COD_{Cr}$ ratio. In electrolysis, dioxide iridium coated titanium ($IrO_2/Ti$) and stainless steel plate were used for anode and cathode respectively. The $COD_{Cr}$ removal efficiencies between plate type anode and net type anode were about same effect, but electrolytic power using net type anode is low than plate type anode. The $Cl^-/COD_{Cr}$ ratio was about $1.3kgCl^-/kgCOD_{Cr}$ when organic removal obtained 70 %, $Cl^-/COD_{Cr}$ ratio needs $2.2kgCl^-/kgCOD_{Cr}$ so as to organic completely remove. The removal efficiency of organics increased with current density, retention time and $Cl^-/COD_{Cr}$ ratio, but decreased with increasing electrode gap. The relationship of operating conditions and $COD_{Cr}$ removal efficiencies are as follows. $$COD_{Cr}(%)=80.0360(Current\;density)^{0.4451}{\times}(HRT)^{0.8102}{\times}(Gap)^{-0.4915}{\times}(Cl^-/COD_{Cr})^{0.5805}$$ There existed a competition between the removals for $COD_{Cr}$ and ammonium during electrolysis, the removal of ammonium was shown to be dominant and $COD_{Cr}$ removal was low. But $COD_{Cr}$ removal was raised as addition of alkalinity.

• The korean journal of orthodontics
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• v.40 no.4
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• pp.276-287
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• 2010

This case report describes the treatment of a 23-year, 8-month-old female patient with a Class II malocclusion who showed severe bidentoalveolar protrusion and anterior crowding. The treatment plan consisted of extracting all the first premolars, decrowding and en masse retraction of the upper six anterior teeth and lower anteriors. The upper C-plate placed in the midpalatal area combined with lingual sheath fixtures were used as substitutes for posterior anchorage teeth during upper anterior retraction. Preadjusted brackets (0.022-inch) were used for upper anterior decrowding. A 0.9 mm diameter stainless steel lever-arm soldered to the main arch wire facilitated controlled retraction of upper anteriors. The upper and lower dentition was detailed using a tooth positioner during the finishing stage. Correct overbite and overjet were obtained by decrowding and retraction of the upper six anterior teeth into their proper positions. Use of the C-plate and lingual appliances provided ideal anchorage to enhance the improvement in facial balance. The active treatment period was 19 months. The treatment result was stable 13 months after debonding.