• Title/Summary/Keyword: Stable isotopes

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Stable Carbon and Nitrogen Isotopes of Sinking Particles in the Eastern Bransfield Strait (Antarctica)

  • Khim, Boo-Keun;Kim, Dong-Seon;Shin, Hyoung-Chul;Kim, Dong-Yup
    • Ocean Science Journal
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    • v.40 no.3
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    • pp.167-176
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    • 2005
  • A time-series sediment trap was deployed at 1,034 m water depth in the eastern Bransfield Strait for a complete year from December 25, 1998 to December 24, 1999. About 99% of total mass flux was trapped during an austral summer, showing distinct seasonal variation. Biogenic particles (biogenic opal, particulate organic carbon, and calcium carbonate) account for about two thirds of annual total mass flux $(49.2\;g\;m^{-2})$, among which biogenic opal flux is the most dominant (42% of the total flux). A positive relationship (except January) between biogenic opal and total organic carbon fluxes suggests that these two variables were coupled, due to the surface-water production (mainly diatoms). The relatively low $\delta^{13}C$ values of settling particles result from effects on C-fixation processes at low temperature and the high $CO_2$ availability to phytoplankton. The correspondingly low $\delta^{l5}N$ values are due to intense and steady input of nitrates into surface waters, reflecting an unlikely nitrate isotope fractionation by degree of surface-water production. The $\delta^{l5}N$ and $\delta^{l3}C$ values of sinking particles increased from the beginning to the end of a presumed phytoplankton bloom, except for anomalous $\delta^{l5}N$ values. Krill and the zooplankton fecal pellets, the most important carriers of sinking particles, may have contributed gradually to the increasing $\delta^{l3}C$ values towards the unproductive period through the biomodification of the $\delta^{l3}C$ values in the food web, respiring preferentially and selectively $^{12}C$ atoms. Correspondingly, the increasing $\delta^{l5}N$ values in the intermediate-water trap are likely associated with a switch in source from diatom aggregates to some remains of zooplankton, because organic matter dominated by diatom may be more liable and prone to remineralization, leading to greater isotopic alteration. In particular, the tendency for abnormally high $\delta^{l5}N$ values in February seems to be enigmatic. A specific species dominancy during the production may be suggested as a possible and speculative reason.

Correlation of Growth Performance with Total Nitrogen, Carbon and Nitrogen Isotope Compositions in the Xylem of Pinus koraiensis (잣나무 생장과 목질부내의 전질소, 탄소 및 질소 동위원소 조성과의 상관관계)

  • Lee, Wi-Young;Park, Eung-Jun;Han, Sang-Urk
    • Journal of Korean Society of Forest Science
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    • v.99 no.3
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    • pp.353-358
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    • 2010
  • In this study, we investigated the relationship of tree-ring growth with total nitrogen content, and stable carbon and nitrogen isotopes from the core samples of Pinus koraiensis (35-year-old). Annual ring width showed significant positive correlations with the ${\delta}^{13}C$ (P=0.003). The total nitrogen content (P=0.024), and the ${\delta}^{13}C$ content was also correlated with total nitrogen content (P=0.038), indicating that the growth of P. koraiensis was stimulated as the contents of both ${\delta}^{13}C$ and total nitrogen were increased. On the other hand, the less the ${\delta}^{15}N$ content and the C/N ratio were, the larger the annual ring width was. Moreover the families with relatively better growth performance contained the higher levels of ${\delta}^{13}C$ in the xylem compared to other families. These results suggest that the ${\delta}^{13}C$ and total nitrogen contents are the important determinants in the growth performance of P. koraiensis.

Geochemistry and Stable Isotopes of Carbonated Waters in South Korea (남한 탄산수의 지구화학적 특성과 안정동위원소 조성)

  • 윤정아;김규한
    • Journal of the Korean Society of Groundwater Environment
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    • v.7 no.3
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    • pp.116-124
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    • 2000
  • Geochemical and isotopic analyses were carried out to investigate hydrochemical characteristics, source of carbon species in the carbonated waters in South Korea. Most Korean carbonated waters from different geologic settings are characterized by a Ca-HCO$_3$type with a relatively low pH range from 5.3 to 6.3 (avg. 6.0). The concentrations of cations and anions in the carbonate waters are in the order of Ca$^{2+}$>Na$^{+}$>Mg$^{2+}$>Si$^{4+}$>Fe$^{2+}$>K$^{+}$ and HCO$_3$$^{-}$>SO$_4$$^{2-}$>Cl$^{-}$, respectively. The HCO$_3$$^{-}$ ion is more enriched in the carbonated water from the sedimentary rock and granitic rock of Mesozoic age in the Gyungsang basin(GII) and the Precambrian metamorphic rock and Jurassic granitic rocks of the Gyunggj massif in the Gangwon province(GⅠ) than those of the meta-sedimentary rock and granite in the Ogcheon zone(GⅢ). Based on the oxygen and hydrogen isotopic data, the carbonated waters are derived from the meteoric water, showing apparent latitude and altitude effects. The $delta$$^{13}$C values of carbon species in the carbonated water are in between -6.23 and 0.0 $textperthousand$, suggesting inorganic source of carbon originated from the carbonate mineral and carbonate rock in the aquifer.

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Hydrogeological Characterization of Groundwater and Surface Water Interactions in Fresh-Saline Water Mixed Zone of the East Coast Lagoon Area, Korea (동해안 석호 담염수 혼합대에서 지하수와 지표수 상호작용의 수리지질학적 특성 평가)

  • Jeon, Woo-Hyun;Kim, Dong-Hun;Lee, Soo-Hyoung;Hwang, Seho;Moon, Hee Sun;Kim, Yongcheol
    • Journal of Soil and Groundwater Environment
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    • v.26 no.6
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    • pp.144-156
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    • 2021
  • This study examined hydrogeological characteristics of groundwater and surface water interaction in the fresh-saline water mixed zone of East Coast lagoon area, Korea, using several technical approaches including hydrological, lithological, and isotopic methods. In addition, the fresh-saline water interface was evaluated using vertical electrical conductivity (EC) data. For this purpose, three monitoring wells (SJ-P1, SJ-P2, and SJ-P3) were installed across the Songji lagoon at depths of 7.4 to 9.0 m, and water level, EC, and temperature at the wells and in the lagoon (SJ-L1) were monitored using automatic transducers from August 1 to October 21, 2021. Isotopic composition of the groundwater, lagoon water, and sea water were also monitored in the mid-September, 2013. The mixing ratios calculated from oxygen and hydrogen isotopic composition decreased with increasing depth in the monitoring wells, indicating saline water intrusion. In the study area, the interaction of groundwater-surface water-sea water was evident, and residual salinity in the sedimentary layers created in the past marine environment showed disorderly characteristics. Moreover, the horizontal flow at the lagoon's edge was more dominant than the vertical flow.

Surface Dose Evaluation According to the Environment Around the Patient after Nuclear Medicine Examination (핵의학 검사 후 환자의 주위 환경에 따른 표면 선량 평가)

  • Lee, Young-Hee;Park, Jae-Yoon
    • Journal of the Korean Society of Radiology
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    • v.15 no.7
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    • pp.943-948
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    • 2021
  • The purpose of this study was to investigate changes in surface dose due to increased scattering of gamma rays from patients injected with 99mTc and 18F, which are radioactive isotopes, in close contact with materials with high atomic number such as the walls of the stable room. Prepare 99mTc and 18F by injecting 20 and 10 mCi respectively into the NEMA phantom, and then measuring the surface dose for 60 minutes by positioning the phantom at a height of 1 m above the surface, at a distance of 0, 5 and 10 cm from the wall, and at the same location as the phantom facing the wall. Each experiment was repeated five times for reproducibility of the experiment and one way analysis of variability (ANOVA) was performed for significance testing and Tukey was used as a post-test. The study found that surface doses of 220.268, 287.121, 243.957, and 226.272 mGy were measured at 99mTc, respectively, in the case of empty space and in the case of 0, 5 and 10 cm, while those of 18F were measured at 637.111, 724.469, 657.107, and 640.365 mGy, respectively. In order to reduce changes in surface dose depending on the patient's location while waiting, it is necessary to keep the distance from the ground or the wall where the patient is closely adhered to, or install an air mattress, etc., to prevent the scattered lines as much as possible, considering the scattered lines due to the wall etc. in future setup of the patient waiting room and safety room, and in addition to the examination, the external skin width may be reduced.

Assessment of CH4 oxidation in macroinvertebrate burrows of tidal flats (갯벌의 무척추 동물 서식굴 내 메탄산화 평가)

  • Kang, J.;Kwon, K.;Woo, H.J.;Choi, J.U.
    • Journal of Wetlands Research
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    • v.21 no.2
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    • pp.95-101
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    • 2019
  • In tidal flats that lack plants, methane ($CH_4$) fluxes are both positive (gas emission) and negative (gas "sinking") in nature. The levels of methanotroph populations significantly affect the extent of $CH_4$ sinking. This preliminary study examined $CH_4$ flux in tidal flats using a circular closed-chamber method to understand the effects of macroinvertebrate burrowing activity. The chamber was deployed over decapods (mud shrimp, Laomedia astacina and crab, Macrophthalmus japonicus) burrows for ~ 2 h, and the $CH_4$ and $CO_2$ concentrations were continuously monitored using a closed, diffuse $CH_4/CO_2$ flux meter. We found that Laomedia astacina burrow (which is relatively long) site afforded higher-level $CH_4$ production, likely due to diffusive emission of $CH_4$ in deep-layer sediments. In addition, the large methanotrophic bacteria population found in the burrow wall sediments has $CH_4$ oxidation (consumption) potential. Especially, nitrite-driven anaerobic oxidation of methane (AOM) may occur within burrows. The proposed $CH_4$-oxidation process was supported by the decrease in the ${\delta}^{13}C$ of headspace $CO_2$ during the chamber experiment. Therefore, macroinvertebrate burrows appear to be an important ecosystem environment for controlling atmospheric $CH_4$ over tidal flats.

Groundwater and Stream Water Acidification and Mixing with Seawater, and Origin of Liquefaction-Expelled Water in a Tertiary Formation in the Pohang Area (포항지역 제3기층내 지하수와 지표수의 산성화 및 해수혼합, 그리고 액상화 유출수 기원에 관한 연구)

  • Jeong, Chan Ho;Ou, Song Min;Lee, Yu Jin;Lee, Yong Cheon;Kim, Young Seog;Kang, Tae Seob
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.559-569
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    • 2022
  • This study investigated the acidification and mixing with seawater of groundwater, stream water, and reservoir water in the Hunghae area of Pohang City, as well as the source of water expelled to the stream by liquefaction induced by the Pohang earthquake on 15 November 2017. Geologically, the area consists of Tertiary sedimentary rocks. We collected six samples of groundwater, five of reservoir water, four of stream water, two of liquefaction water, and one of seawater to analyze the chemical composition and stable isotopes (𝛿D and 𝛿18O). Gogkang Stream flows eastward through the central part of the study area into the East Sea. The groundwater and reservoir water in the lower part of the stream are acidic (pH < 4), have a Ca(Mg)-SO4 composition, and high concentrations of Al, Fe, and Mn, likely due to the oxidation of pyrite in Tertiary rocks. The groundwater in the upper part of the stream have a Ca(Na)-HCO3(Cl) composition, indicating the mixing of seawater with the stream water. The 𝛿D and 𝛿18O isotope data indicate the isotopic enrichment of reservoir water by evaporation. Based on the chemical and isotopic data, it is inferred that the two samples of liquefaction water originated from alluvium water in a transition zone with stream water, and from deep and shallow groundwaters that has been infiltrated by seawater, respectively.

Analysis of Food Sources of Pre- and Post-diet in a Bivalve Using DNA Metabarcoding (DNA metabarcoding을 이용한 이매패류 공식 전후 먹이원 분석)

  • Bong-Soon Ko;Jae-won Park;Chang Woo Ji;Ihn-Sil Kwak
    • Korean Journal of Ecology and Environment
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    • v.55 no.4
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    • pp.360-367
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    • 2022
  • Research on food sources through DNA metabarcoding is being used for various organisms based on high resolution and reproducibility. In the study, we investigated the difference in food sources between pre and post-starving in the three bivalve species (Anemina acaeformis, Anodonta woodiana, and Unio douglasiae) through DNA metabarcoding using 18S rRNA V9 primer. The food source of pre-starving appeared in 87 genera, 71 families, 51 orders, 35 classes, and 22 phyla. The primary food sources were the zoo and phytoplankton, including Chlamydomonadales, Euglenales, Ploima, Sphaeropleales, and Stephanodiscales. However, all zoo and phytoplankton were not observed after starving except Schizopyrenida and Rotifera. In Levin's niche breadth analysis, the Bi index of A. woodiana is 0.3, which was higher than A. acaeformis(0.14) and U. douglasiae (0.21), indicating that they feed on various food sources. The niche overlap of A. acaeformis was measured as 0.78 in A. woodiana, 0.7 in U. douglasiae showing a relative high value compared to other bivalves. The trophic level of A. acaeformis, A. woodiana, and U. douglasiae based on the food source information were investigated as 2.0, 2.0, and 2.5, respectively. The results of the previous study on the trophic level using stable isotopes showed 1.8 to 2.4 values were similar to the results of this study. These results suggest that DNA metabarcoding can be an effective analyzing tool for the gut content in the bivalves.

Development of an exclusive column method for 82Sr/82Rb generator using a 100 MeV proton linear accelerator of KOMAC

  • Kye-Ryung Kim;Yeong Su Ha;Sang-Pil Yoon;Yeon-ji Lee;Yong-Sub Cho;Hyeongi Kim;Sang-Jin Han;Jung Young Kim;Kyo Chul Lee;Jin Su Kim
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.7 no.2
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    • pp.119-125
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    • 2021
  • 82Sr for 82Rb generator was produced through the irradiation of the proton beam on the nat.RbCI target at the target irradiation facility installed at the end of the Rl-dedicated beamline of the 100 MeV proton linear accelerator of KOMAC (Korea Multi-purpose Accelerator Complex). The average current of the proton beam was 1.2 µA for irradiation time of 150 min. For the separation and purification of the 82Sr from nat.RbCI irradiated, Chelex-100 resin was used. The activities of 82Sr in the irradiated nat.RbCI target solution and after purification were 45.29 µCi and 43.4 µCi, respectively. The separation and purification yield was 95.8%. As an adsorbent to be filled in the generator for 82Sr adsorption hydrous tin oxide was selected. The adsorption yield of 82Sr into the generator adsorbent was > 99 %, and the total amount of 82Sr adsorbed to the generator was 21.6 µCi as of the day of the 82Rb elution experiment. When the elution amount was 22 mL, the maximum82Rb elution yield was 93.3%, and the elution yield increased as the flow rate increased. After the eluted 82Rb was filled in the correction phantom of the small PET for animals, a PET image was taken. The image scan time was set to 5 min, and the phantom PET image was successfully obtained. As results of impurity analysis on eluted 82Rb using ICP-MS, nat.Rb stable isotopes that compete in vivo of 82Rb were identified as undetected levels and were determined to be No-Carrier-Added (NCA).

An Assessment of Primary Productivity Determined by Stable Isotopes and Diving-PAM in the Pyropia Sea Farms of the Manho (Jindo-Haenam) Region on the Southwestern Coast of the Korean Peninsula (안정동위원소 및 Diving-PAM을 이용한 남서해안 만호해역 (진도-해남) 김 양식장에서의 일차 생산력)

  • Kim, Jeong Bae;Lee, Won-Chan;Kim, Hyung Chul;Hong, Sokjin
    • Korean Journal of Environmental Biology
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    • v.34 no.1
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    • pp.18-29
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    • 2016
  • The effects of water temperature, salinity, water column nutrient contents, and phytoplankton primary productivity on pigment composition and concentration, as well as primary productivity of Pyropia yezoensis Ueda purple lavers were studied at the primary cultivation areas in the Manho (Jindo-Haenam) region on the southwestern coast of Korea in March 2014. The water temperature was $9.1{\sim}9.6^{\circ}C$, salinity was 32.5~33.1, and transparency was 0.7~1.5 m. The shallow euphotic depth resulted from the high turbidity. Water column dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), and silicate concentrations were $3.59{\sim}5.73{\mu}M$, $0.16{\sim}0.41{\mu}M$, and $12.41{\sim}13.94{\mu}M$, respectively. Chlorophyll a (Chl a) concentration was $0.51{\sim}1.25{\mu}g\;L^{-1}$. Nanoplankton ($0.7{\sim}20{\mu}m$ size class) accounted for 58% of the total Chl a concentration. Fucoxanthin was the dominant photosynthetic pigment at all sites. Microplankton ($20{\sim}200{\mu}m$ size class) accounted for 64% of the total fucoxanthin concentration. The primary productivity of phytoplankton was $57.72{\pm}4.67(51.05{\sim}66.71)mg\;C\;m^{-2}d^{-1}$. The nanoplankton ($0.7{\sim}20{\mu}m$ size class) accounted for 77% of the total phytoplankton primary productivity. The calculated phytoplankton primary productivity was $11,337kg\;C\;d^{-1}$. The primary productivity of Pyropia blades was $1,926{\pm}192(1,102{\sim}2,597)mg\;C\:m^{-2}d^{-1}$, i.e., calculated as $39,295kg\;C\;d^{-1}$. The total primary productivity of phytoplankton and Pyropia blades was $50,632kg\;C\;d^{-1}$. The primary productivity of Pyropia blades was 3.5 times greater than that of phytoplankton in the Manho region on the southwestern coast of Korea.