• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.159-165
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• 2003

Self-excited noise generation from laminar flames in thin annular jets of methane/air premixture has been investigated experimentally. Various flames were observed in this flow configuration, including conical shape flames, ring shape flames, steady crown shape flames, and oscillating crown shape flames. Self-excited noise with the total sound pressure level of about 70dB was generated from the oscillating crown shape flames for the equivalence ratio larger than 0.95. Sound pressure and $CH^{\ast}$ chemiluminescence were measured by using a microphone and a photomultiplier tube. The frequency of generated noise was measured as functions of equivalence ratio and premixture velocity. A frequency doubling phenomena have also been observed. The measured $CH^{\ast}$ chemiluminescence data were analyzed from which the corresponding sound pressure has been calculated. By comparing the data with those of measured ones, the noise source can be attributed to the flame front fluctuation near the edge of the oscillating crown-shape flames. The flame stability regime was influenced sensitively to the supplying air through the inner tube.

• Journal of the Korean Chemical Society
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• v.31 no.6
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• pp.503-508
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• 1987

The protonation constants of 3,4 : 9,10-dibenzo-1,12-diaza-5,8-dioxacyclotetradecane $(NenOenH_4)$ and stability constants of its transition metal complexes have been determined by the potentiometric titration in 1 : 1 dioxane-water mixture with 0.1 ionic strength at $25^{\circ}C.$ For a given anion system, the stabilitv constants of the complexes are in the order of $Mn^{2+}<\;Co^{2+}\;< Ni^{2+}\;<\;Cu^{2+}\;>\;Zn^{2+}$, which accords with the Williams-Irving series.