• 제목/요약/키워드: SrS:Ce

검색결과 41건 처리시간 0.026초

Cathodoluminescent properties of rare-earthe-doped $SrGa_2S_4$ thin film phosphors excited with low energy electrons

  • Nakanishi, Yoichiro
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.1015-1019
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    • 2002
  • The deposition of $SrGa_2S_4$ thin film phosphors doped with Ce or Eu aiming at application for FEDs has been carried out by a multi-source deposition technique. A $SrGa_2S_4$ phase was formed by annealing process and $SrGa_2S_4$ thin films which were deposited using a $Ga_2S_3/Sr$ flux ratio larger than 50 and annealed in $H_2$S showed luminance and luminous efficiency of about 1700 cd/$m^2$ and 2.95 lm/W, respectively, with (0.13, 0.10) chromaticity in the activation with Ce, and about 4000 cd/$m^2$ and 7.05 lm/W, respectively, with (0.36, 0.60) under excitation with 3 kV and 60A/$cm^2$. The results obtained this experiment demonstrate the potential of $SrGa_2S_4$ thin film phosphors for FED screens.

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$(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ 계의 합성 및 초전도 특성 (Synthesis and Superconductivity in $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ System)

  • 이호근;배수민
    • Progress in Superconductivity
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    • 제10권2호
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    • pp.128-132
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    • 2009
  • Polycrystalline samples of $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$($ 0{\leq}x{\leq}1.25$) have been synthesized by a solid-state reaction route. The X-ray diffraction data revealed that the Nd solubility limit can be placed between x=0.5 and x=0.75. The superconducting transition temperature decreased with increasing Nd content, confirming that Nd entered the lattice. Room-temperature thermoelectric power measurements showed that all the samples are in the underdoped state and the partial substitution of Nd for Gd resulted in a decrease in the carrier density on the superconducting layers.

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Chemical Treatment of Low-level Radioactive Liquid Waste (I)

  • Lee, Sang-Hoon;Choe, Jong-In;Kim, Yong-Eak
    • Nuclear Engineering and Technology
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    • 제8권2호
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    • pp.69-76
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    • 1976
  • 핵연료 재처리 과정이나 원자력발전소에서 대량으로 발생되는 비교적 반감기가 긴 핵종들(Sr-90, Ru-106, Cb-137, Ce-144)의 화학응집제와 국산점토 광물(montmorillonite)에 의한 제거 효율을 결정하기 위해 본 실험이 수행되었다. Phosphate process는 Ce-144의 제거에 있어서 99.5% 이상의 극히 좋은 효율을 나타냈고, lime-soda process는 Sr-90에 대하여 93%의 높은 제거율을 보였으며, Cs-187에 대해서는 copper-ferrocyanide가 제거율 99%의 매우 적절한 화학 응집제임을 나타냈다. Phosphate나 lime-soda process에서 가장 좋은 제거효율은 PH 11 이상에서 얻어졌다. 그리고 NaCl로 처리된 montmorillonite가 방사성 핵종들은 제거하는데 있어서 natural montmorillonite 보다 향상된 제거 효율을 보여주었다.

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Tb이 치환된 $RuSr_2(Eu_{1.34}Ce_{0.66})Cu_2O_z$ 계의 초전도 및 자기적 특성 (Superconductivty and Magnetic Properties of Tb-substituted $RuSr_2(Eu_{1.34}Ce_{0.66})Cu_2O_z$)

  • 이호근;이만석
    • Progress in Superconductivity
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    • 제14권2호
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    • pp.110-115
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    • 2012
  • Samples with nominal compositions of $RuSr_2(Eu_{1.34-x}Tb_xCe_{0.66})Cu_2O_z$ (x = 0, 0.67) were prepared and their superconductivity and magnetic properties were compared to shed light on the effect of Tb substitution for Eu. X-ray diffraction measurements indicate that the Tb substitution resulted in a decrease in both a and c lattice parameters in consistent with ionic size difference between Eu and Tb. Contrary to the Tb-free sample, no superconducting transition behavior is observed in the Tb-sustituted sample. It is also found that the Tb substitution for Eu significantly increases the weak-ferromagnetic component of the field-cooled magnetic susceptibility as well as an increase in the magnetic ordering temperature. These results suggest that the magnetic state of the Ru sublattice is significantly affected by the Tb substitution for Eu.

Glycine-Nitrate Process를 이용한 $La_{0.5}$$Sr_{0.5}$$MnO_3$-${Ce_{0.8}}{Gd_{0.2}}{O_{1.9}}$ 환원극 제조 및 특성평가 (Synthesis and Characterization of $La_{0.5}$$Sr_{0.5}$$MnO_3$-${Ce_{0.8}}{Gd_{0.2}}{O_{1.9}}$ Cathode for Solid Oxide Fuel Cell by Glycine-Nitrate Process)

  • 구본석;윤희성;김병호
    • 한국세라믹학회지
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    • 제38권1호
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    • pp.45-51
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    • 2001
  • 고체산화물 연료전지의 삼상 계면의 길이를 증가시키기 위해 Glycine-Nitrate Process(GNP)를 이용하여 환원극 재료인 L $a_{0.5}$S $r_{0.5}$Mn $O_3$(LSM)과 전해질 재료인 C $e_{0.8}$G $d_{0.2}$ $O_{1.9}$(CGO)를 합성하였다. 적당한 합성조건을 찾기 위하여 글리신의 양을 달리하여 분말을 합성한 결과 LSM의 경우 글리신이 양이온 몰수의 2배일 때 perovskite상이 얻어졌으며 비표면적은 34$m^2$/g 이었다. 합성된 LSM과 CGO 분말을 50:50 wt%로 혼합하여 제작된 환원극을 screen-printing법으로 코팅한 후 각각 1200, 1300, 1350 및 140$0^{\circ}C$에서 4시간 동안 소결한 후 80$0^{\circ}C$에서 power density와 양극과전압 등을 측정한 결과 130$0^{\circ}C$에서 소결한 단위전지에서 최대 309 mW/$ extrm{cm}^2$의 power density를 얻을 수 있었다.다.

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Superconductivty and magnetic properties of $(Ru_{1-x}Nb_x)Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$

  • Lee, H.K.;Bae, S.M.;Lee, J.M.
    • 한국초전도ㆍ저온공학회논문지
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    • 제15권3호
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    • pp.1-4
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    • 2013
  • We investigated the effect of Nb substitution for Ru on the structural and magnetic properties of $(Ru_{1-x}Nb_x)\;Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$ Samples. X-ray diffraction measurements indicated that nearly single-phase samples are formed in the range from x = 0 to 1.0. The superconducting transition temperature determined from the inflection in the field-cooled magnetic susceptibility decreased only slightly from $T_c$ = 25 K for x = 0 to $T_c$ = 22 K for x = 1.0, in consistent with the change in room temperature thermopower of the samples. However, the Nb substitution for Ru above x = 0.25 significantly suppressed the weak ferromagnetic component of the field-cooled magnetic susceptibility. It was also found that the Nb substitution for Ru results in an enhanced diamagnetic susceptibility with Nb content above x = 0.5 in both zero field-cooled and field-cooled magnetization measurements, in contrast to the behavior of the samples with $x{\leq}0.5$ in which the diamagnetic susceptibility decreases as the Nb content increases.

시트르산의 양과 소결온도에 따른 (La,Sr)$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ 계면특성 (Characterization of (La,Sr))$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ Interface with Citric Acid Contents and Sintering Temperature)

  • 윤일영;윤희성;김병호
    • 한국전기전자재료학회논문지
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    • 제11권1호
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    • pp.18-25
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    • 1998
  • G $d_{0.2}$C $e_{0.8}$ $O_{1.9}$(CGO) for electrolyte and L $a_{0.5}$S $r_{0.5}$Mn $O_3$(LSM50) for cathode in Solid Oxide Fuel Cells(SOFC) were synthesized by citrate process. Specimens were prepared with sintering temperatures at 110$0^{\circ}C$, 120$0^{\circ}C$ and 130$0^{\circ}C$, which were fabricated by slurry coating with citric acid contents. Interfacial resistance was measured between cathode and electrolyte using AC-impedance analyzer. With various citric acid content, the degree of agglomeration for the initial particles changed. Also sintering temperature changed the particle size and the degree of densification of cathode. Factors affecting the interfacial resistance were adherent degree of the electrolyte and cathode, distribution of TPB(three phase boundaries, TPB i.e., electrolyte/electrode/gas phase area) and porosity of cathode. By increasing the sintering temperature, particle size and densification of the cathode were increased. And then, TPB area which occurs catalytic reaction was reduced and so interfacial resistance was increased.sed.sed.d.

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A study on the characteristics of SrS:Cu TFEL devices prepared by hot wall deposition

  • Lee Sang-Tae
    • Journal of Advanced Marine Engineering and Technology
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    • 제30권4호
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    • pp.514-519
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    • 2006
  • SrS:Cu, Cl thin films have been grown by the hot wall technique with S furnace placed on the outside of the growth chamber in order to investigate the crystallographic and optical characteristics. The films have a good crystallinity independent of CuCl wall temperature and PL characteristics showed a peak assigned by the transition form $3d^94s^1\;(^3Eg)$ to $3d^{10}\;(^1A_{1g})$ of $Cu^+$ center. It has also been found that. from the PLE spectra, $Cu^+$ luminescent centers are doped in the host materials. The EL emission from SrS:Cu-based device showed a greenish-blue but shifted to short wavelength compared to SrS:Ce-based EL. The device was obtained the maximum luminance of $110cd/m^2$ and the maximum luminous efficiency of $0.1\;lm/W$ at $V_{40}$.