• Electrical & Electronic Materials
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• v.3 no.4
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• pp.306-314
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• 1990

SrO-5.7Fe$_{2}$O$_{3}$의 Magnetoplumbite형 Sr페라이트에 첨가제 SiO$_{2}$, H$_{3}$BO$_{3}$CaCO$_{3}$, SrCO$_{3}$을 0.1-0.1wt%로 변화시켜 만든 등방성과 이방성의 자기이력곡선, 밀도, 감자곡선, 고유보자력 및 미세구조특성에 미치는 영향을 조사하였다. 위 첨가제는 페라이트 생성 및 특성개선에 효과적이었도 특히 등방성에서의 입도크기를 3.5.mu.m에서 1.7.mu.m로 하였을때 소결온도가 40.deg.C 낮은 1220.deg.C에서 잔류자속밀도가 2300G, 보자력이 1950Oe, 밀도가 4.51g/Cm$^{3}$, 교유보자력이 3500Oe로 각각 증가하였다. 이방성은 등방성 보다 원등히 우수하였고 최대에너지적 (BH)$_{max}$이 소결온도가 10.deg.C 낮은 1210.deg.C에서 1.13으로 부터 3.3MGOe로 증가하였다. 이값은 이론치의 61%에 도달하고 있다.

• Resources Recycling
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• v.13 no.6
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• pp.31-36
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• 2004

This experiment was carried out to examine the effects of morphology on properties of La-Co substituted SrM ferrite. The magnetic properties of calcined and sintered materials were varried with the substitutional amount of La and Co elements in Sr-ferrite. In the substituted SrM ferrite, the atomic fraction x of La is directly related to the mole ratio n of iron oxide and the atomic fraction y of Co by equation x=2ny. The Hcj values of the calcined powder were about 270 kA/m and 240 kA/m with x=0.3 and x=0.2, respectively at stoichiometry, n=6.0. Crystallites of the sintered material were grown with a plate shape, and their size decreased with increasing mole ratios. Such a shape was caused by the initial state of crystallite formed after calcination. In case of x=0.3 and n=6.0, Br was 415 mT and Hcj was 355 kA/m, and in x=0.2 and n=6.0, Br was 410 mT and Hcj was 370 kA/m. The squareness in 2nd quarter of BH curve with x=0.2 was smoothly improved to compared with x=0.3.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2004.12a
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• pp.27-34
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• 2004

This experiment was carried out to examine the effects of morphology on properties of La-Co substituted SrM ferrite. The magnetic properties of calcined and sintered materials varied with the substitutional amount of La and Co elements in Sr-ferrite. In the substituted SrM ferrite, the atomic fraction x of La is directly related to the mole ratio n of iron oxide and the atomic fraction y of Co by equation x=2ny. The HcJ values of the calcined powder were about 270 kA/m and 240 kA/m with x=0.3 and K=0.2, respectively at stoichiometriy, n=6.0. Crystallites of the sintered material were grown with a plate shape, and their size decreased with increasing mole ratios. Such a shape was caused by the initial state of crystallite formed after calcination. In case of x=0.3 and n=6.0, Br was 415 mT and HcJ was 355 kA/m, and in x=0.2 and n=6.0, Br was 410 mT and HcJ was 370kA/m. The squareness in 2nd quarter of BH curve with x=0.2 was smoothly improved compared with x=0.3

• Journal of the Korean Magnetics Society
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• v.9 no.1
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• pp.35-40
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• 1999

Sr substituted materials for some barium in M-type barium ferrite powder and Co-Ti substituted Sr-Ba hexagonal ferrite powder were prepared by citrate sol-gel method and 2 MOE sol-gel method these hexaferrite particles were reduced for 1hr in the hydrogen gas. The reduction temperatures were varied in the range of 250 $^{\circ}C$ to 500 $^{\circ}C$. X-ray diffraction patterns were measured using diffractometer with Cu $K_{\Alhpa}$ radiation. Mossbauer absorption spectra were measured with a constant acceleration spectrometer. We have focused on studying the origin of increasing $M_s$ by M$\"{o}$ssbauer spectroscopy. Ferrite particles which were sintered at 105$0^{\circ}C$ were found to be typical magnetoplumbite structure and single phase. XRD patterns with varying the reduction temperatures in $Sr_{0.5}Ba_{0.5}Fe_{10}O_{19}$ indicates ferrites particles become composite hexaferrites containing $\alpha$-Fe at T_{red}=350 \;$^{\circ}C$$. On the otherhand, it was found that $Co^{2+}$ ions and $Ti^{4+}$ ions in $Sr_{0.7}Ba_{0.3}Fe_{10}CoTiO_{19}$ prevent from changing $Fe^{3+}$ ions to $\alpha$-Fe during the $H_2$ reduction. Comparing Mossbauer results with XRD results, we have determined most of $\alpha$-Fe are reduced from $4f_{vi}$ sites and 12k sites of $Fe^{3+}$ ions. These $\alpha$-Fe phase bring the induced anisotropy and increase saturation magnetization $M_s$.TEX>.

• Korean Journal of Materials Research
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• v.11 no.8
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• pp.685-689
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• 2001

We carried out these experiments to examine the effects of element substitution of Co and La-Co for Sr-ferrite. The calcined properties of Co and La-Co element substitution were examined, and also the sintered magnetic properties were measured with the stoichiometric condition. The magnetic properties of $(La-Co)_{0.3}-SrM$ composition are as follows; $(M_s)$: 71.08 emu/g, $iH_c$: 4.38 kOe and $B_r$ : 4.18 kG, $iH_ c$ :4.35 kOe, $BH_{max}$: 4.3 MGOe. The $BH_{max}$ value was increased up to 10 % compared with conventional values. Our results imply that the magnetic properties of Sr-ferrite can be improved by the substitution of those elements.

• Proceedings of the Materials Research Society of Korea Conference
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• 1992.05a
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• pp.84-86
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• 1992

• Proceedings of the Materials Research Society of Korea Conference
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• 1994.05a
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• pp.31-32
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• 1994

• Electrical & Electronic Materials
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• v.5 no.3
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• pp.329-336
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• 1992

본 논문은 이방성 Sr.페라이트의 자기특성의 개선에 관하여 연구한 것이다. 시편은 SrO.nFe$_{2}$O$_{3}$의 기본조성으로서 비화학양론적 영역인 n=5.9를 택하였다. 그리고 보자력을 증가시키기 위하여 기본첨가제로서 0.7wt% CaCO$_{3}$와 0.3% wt% SiO$_{2}$를 첨가하여 하소시킨 다음 $Na_{2}$SiO$_{3}$의 량을 변화시키면서 복합첨가하였다. 한편, 위의 시료(기본첨가제와 0.5wt% $Na_{2}$SiO$_{3}$)에 Cr$_{2}$O$_{3}$ 및 $Al_{2}$O$_{3}$를 단독 및 복합첨가한 결과, 0.5wt% $Al_{2}$O$_{3}$가 단독첨가되었을 경우, 좋은 자기특성을 나타내었다. 본 연구에서 시행한 복합첨가방식에 의한 Sr.페라이트의 자기특성의 조사를 통하여 등방성의 경우, 기본조성과 기본첨가제와 0.5wt% $Na_{2}$SiO$_{3}$와 0.5wt% $Al_{2}$O$_{3}$조성에서 (BH)$_{max}$=1.15MGOe, 그리고 이방성의 경우, (BH)$_{max}$=3.23MGOe를 얻었으며 시료를 이방성화하므로서 자기특성면에서 등방성인 경우의 2~3배의 개선효과를 얻었다. 그리고 소결온도는 1210.deg.C에서 가장 좋은 특성을 나타내었으며 큐리온도는 등방성의 경우 T$_{c}$=410~420.deg.C에서 이방성의 경우 T$_{c}$=439~445.deg.C로서 약 30.deg.C가 향상되었다.

• Journal of the Korean Magnetics Society
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• v.6 no.5
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• pp.310-316
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• 1996

In this study magnetic properties of anisotropic ferrite bonded magnets produced by extrusion molding with a variety of magnetic field, extrusion mold temperature and extrusion rate were investigated. X-ray diffraction study showed the alignment of magnetic powder was decreased by molten flow in extrusion mold. When the temperature of extrusion mold was $20^{\circ}C$, the degree of alignment as much as 82% could be achieved under the applied magnetic field of 4 kOe. The bonded magnets having the remanence of 2.2 kG was able to fabricated by extrusion molding when the packing density of Sr-ferrite powder was 50 vol%.

• Journal of the Korean Society for Precision Engineering
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• v.14 no.3
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• pp.21-27
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• 1997

This paper aims to clarify the effects of grinding conditions in form grinding of Sr-ferrite with the electro-plated diamond wheel. The main conclusions obtained were as follows. (1) The flexural strength and surface roughness of ferrite became the best at the peripheral wheel speed of 1700 m/min. (2) In the case of the depth of cut larger than 0.4mm, crack layers is induced in the ground surface, and the fracture type of chips exhibits slight ductile mode in the depth of cut smaller than 0.2mm. (3) Whe the depth of cut exceeds 0.6mm, the wheel life becomes extremely severe due to the large chipping and brack- age in the diamond grains. However, at the depth of cut .leq. 0.05mm, the diamond grain shows abrasive wear. (4) The decrease of flexural strength and the increase of surface roughness is in proportion to the increase of the feed rate. (5) Most effective nozzle setting angles with various delivery conditions of the grinding fluid, such as nozzle position .PHI. , flow rate Q, etc., were made clear.