• Clean Technology
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• v.30 no.3
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• pp.220-227
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• 2024

As the demand for lithium-ion batteries with high capacity and high energy density has rapidly increased, silicon anodes (theoretical capacity = 3,570 mA h g^-1) have garnered attention as potential replacements for conventional graphite anodes (theoretical capacity = 372 mA h g^-1). However, silicon anodes suffer from severe volume expansion (~360%) during lithiation, low ionic conductivity (10^-14 ~ 10^-13 cm² S^-1), and low electrical conductivity (10^-2 S cm^-1), resulting in poor cycling and rate performance. To address these issues, this study synthesized core@shell-structured silicon@carbon nanoparticles (Si@C NPs) via a one-pot spray pyrolysis process using Pluronic-F127. Pluronic-F127 in the spray solution contributes to the synthesis of nanoparticles by preventing the formation of silicon nanoparticle/dextrin agglomerates and by undergoing pyrolysis simultaneously. Additionally, dextrin derived amorphous carbon was coated on the surface of the silicon nanoparticles to act as an electron transport pathway within the anodes and enhance the electrical contact between the silicon nanoparticles. The Si@C NPs exhibited a discharge capacity of 1,912 mA h g^-1 after 50 cycles at 1.0 A g^-1 and high rate capabilities (discharge capacity of 1,493 mA h g^-1 at 3.0 Ag^-1). The silicon@carbon composite nanoparticle synthesis strategy based on the spray pyrolysis process presented in this study is expected to offer a new direction for improving the performance of silicon anode materials.

• Journal of ILASS-Korea
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• v.17 no.2
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• pp.71-76
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• 2012

The aim of this work was to investigate the combustion and nanoparticle emission characteristics of premixed charge compression ignition (PCCI) combustion at various test conditions using a single cylinder common-rail diesel engine. In order to create the homogeneity of fuel-air mixture, the premixed fuel (gasoline) was injected into premixing chamber during the intake process and then the diesel fuel was directly injected into the combustion chamber as an ignition source for the gasoline premixture. From these results, it revealed that the ignition delays and combustion durations were gradually prolonged and the peak combustion pressure were increased because diesel fuel was injected early injection timing with the increase of premixed ratio. In addition, as the increase of premixed ratio, total particle number is generally decreased and particle volume also indicated low levels at the direct injection timing from BTDC $20^{\circ}$ to TDC. At further advanced injection timing, total particle number and volume were generally increased

• Journal of ILASS-Korea
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• v.20 no.4
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• pp.261-267
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• 2015

The main purpose of this study is to provide the information of soot generation of toluene fuel droplet. To achieve this, this paper provides the experimental results on the different initial diameter of toluene droplet combustion characteristics conducted under equivalent ambient pressure ($P_{amb}$) and oxygen concentration ($O_2$) conditions. Visualization of single fuel droplet was performed with high resolution CCD camera and visualization system. At the same time, ambient pressure ($P_{amb}$) and oxygen concentration ($O_2$) were maintained by ambient condition control system. Soot volume fraction ($f_v$) was analyzed and compared on the basis of intensity ratio ($I/I_0$) of background image. The result of soot generation was almost the same regardless of initial droplet diameter since thermophoretic flux is not much changed under the same ambient conditions. Soot standoff ratio (SSR) of 2 mm diameter showed unstable variation characteristics due to the short available measuring time.

• Journal of ILASS-Korea
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• v.20 no.4
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• pp.217-222
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• 2015

In this study, Injection rate tests of a Diesel common-rail injector have been performed with injection volume measurement type injection rate test system EMI21 for construction of injector model can be used in an engine calibration mean valued model. The measuring principle of the test system is based on measurement of dispalcement of a movable measurement piston by the volume of fluid released by the injector. From these injection rate test results, the characteristics on shape of instantaneous injection rate and injection fuel amount have been investigated and injection fuel amount calculation equation based on test results has been newly constructed. This equation is very simple and calculation error is less than 5% with test results for wide range injection pressure (200~1800 bar) and injection duration ($200{\sim}1800{\mu}s$) conditions. So, it is anticipated that newly constructed simple injection fuel amount model in this study can be efficiently used on engine calibration and control model.

• Journal of ILASS-Korea
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• v.14 no.4
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• pp.171-177
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• 2009

This study proposes a new stratified charge system for low emission and ultra lean burn. In order to examine combustion characteristics of the new system, sparkplug with a hole at positive pole and a common CNG injector for injecting fuel were used in this study as injector-type spark plug. The new stratified charge system injects fuel of extremely small quantities and ignites mixture around sparkplug gap. Also, the system was fitted in a visualized constant volume chamber. Then, for analysis of the combustion characteristics, we examined combustion pressure, lean inflammable limit, and visualized combustion flame according to equivalence ratio by comparison with homogeneous charge (HC) method and the new stratified charge (SC) method. As results of this study, in the case of using this system, the propagation speed of initial flame was increased and total combustion period was reduced in the ultra lean burn in the same equivalence ratio. These phenomena occurred clearly under the conditions of lean equivalence ratio. Furthermore, the lean inflammable limit of mixture was extended by using the injector-type spark plug.

• Journal of ILASS-Korea
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• v.17 no.3
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• pp.152-157
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• 2012

This investigation decribes the effect of the combustion and emission characteristics of HCNG engine according to the high purity hydrogen contents. The HCNG fuel was made by the mixture with a high purity hydrogen ($H_2$) and a natural gas. The test vehicle was applied to the bi-fuel (Gasoline and CNG) system and this system was modified from the fuel supply and fuel tank. In addition, the three premixed HCNG fuels with mixed rate of 10, 20 and 30% of hydrogen were used to maintain the safety. In order to analyze the combustion characteristics of HCNG and CNG, the fuel was injected in the combustor with constant volume. The exhaust emission from light duty vehicle with bi-fuel system was analyzed by a chassis dynamometer and emission analyzer. From these results, the reduction rate of NOx emission increased in the HCNG fuel and emission amount of THC and CO shows a similar level with CNG fuel. This study can be utilized the basic data for the development of a new business plans related with HCNG engines.

• Journal of ILASS-Korea
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• v.22 no.2
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• pp.80-86
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• 2017

The soot formation characteristics of various alkane-based single fuel droplets were studied in this work. Also, This study was performed to provide the database of the soot behavior and formation of alkane-based single fuel droplet. The experimental conditions were set to 1.0 atm of ambient pressure ($P_{amb}$), 21% of oxygen concentration ($O_2$) and 79% of nitrogen concentration ($N_2$). Combustion and soot formation of single fuel droplet was visualized by visualization system with high speed camera. At the same time, ambient pressure, oxygen concentration and nitrogen concentration were maintained by ambient condition control system. Soot formation characteristics was analyzed and compared on the basis of intensity ratio ($I/I_0$) of background image. The results of toluene fuel droplet showed the largest soot generation. Soot volume fraction ($f_v$) was almost the same under the identical fuel types regardless of various initial droplet diameter ($d_0$) since thermophoretic flux was not much changed under the same ambient conditions.

• Journal of ILASS-Korea
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• v.10 no.2
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• pp.41-47
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• 2005

Exhaust gas emissions from internal combustion engines are one of the major sources of air pollution. And. it is extremely difficult to increase gasoline engine efficiency and to reduce NOx and PM(particulate matter) simultaneously in diesel combustion. This paper offers some basic concepts to overcome the above problems. To solve the problems, a recommended technique is CAI(controlled auto-ignition) combustion. In this paper. internal EGR(exhaust gas recirculation) effect is suggested to realize CAI combustion. An experimental study was carried out to achieve CAI combustion using homogeneous premixed gas mixture in the constant volume combustion chamber(CVCC). A flame trap was used to simulate internal EGR effect and to increase flame propagation speed in the CVCC. Flame propagation photos and pressure signals were acquired to verify internal EGR effect. Flame trap creates high speed burned gas jet. It achieves higher flame propagation speed due to the effect of geometry and burned gas jet.

• Archives of design research
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• v.18 no.4 s.62
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• pp.119-128
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• 2005

This paper presents an intuitive 3D modeling interlace based on a field study and prototype development. The process and tools of modeling were observed in workshops of professional design model making, day modeling, wood caning and glass crafting. The Spray Modeling interlace was developed from the observational analysis of the field study. It is a 3D modeling interface which combines particle spraying and day modeling in Virtual or Augmented Reality space. Virtual volume particles are sprayed on frames in Augmented Reality space as day modeling. It adopts a real air spay gun as a tangible interface device which provides coherent sound and air-force feedback. The prototype development and a user study showed that the interface supports new patterns of form development and expression. Control interfaces and requirements of auxiliary devices were found to be improved. This study examines the potential of the new interlace for designers working in 3D virtual and augmented reality. The new spraying interface is also expected to be used as an alternative interface in 3D computer workspace, games, education software and media art.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.3
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• pp.237-243
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• 2015

In this study, the effects of the mixing ratio of emulsified fuel on the droplet evaporation and spray behavior characteristics were analyzed. A surfactant comprising span 80 and tween 80 mixed at a 9:1 ratio was used for the emulsified fuel. The fuel and surfactant were mixed at a ratio of 3:1 for the emulsified fuel. In addition, considering the mixing ratio of the surfactant, the mixing ratio of $H_2O_2$ in the emulsified fuel was set as EF (emulsified fuel)0, EF2, EF12, EF22, EF32, and EF42. To observe the evaporation characteristics, droplets of the emulsified fuel were dropped on a heating plate and observed using scattered light and a Schlieren system. In addition, to analyze the effect of the $H_2O_2$ mixing ratio, the behavior characteristics of the evaporative free spray were investigated in the mixing ratio range of EF0 to EF22 using a constant volume chamber with heaters. Consequentially, it was found that in the case of EF22, the free spray development of the emulsified fuel was faster than that of EF0 (diesel only) because of the promotion of the evaporation due to the phase change in the peroxide contained in the emulsion fuel.