• Title/Summary/Keyword: Splitting ratio

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Improvement of the Thermochemical water-splitting IS Process Using the Membrane Technology (분리막 기술을 이용한 열화학적 수소제조 IS[요오드-황] 프로세스의 개선)

  • Hwang, Gab-Jin;Kim, Jong-Won;Sim, Kyu-Sung
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.3
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    • pp.249-258
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    • 2002
  • Thermochemical water-splitting IS(Iodine-Sulfur) process has been investigating for large-scale hydrogen production. For the construction of an efficient process scheme, two kinds of membrane technologies are under investigating to improve the hydrogen producing HI decomposition step. One is a concentration of HI in quasi-azeotropic HIx ($HI-H_2O-I_2$) solution by elecro-electrodialysis. It was confirmed that HI concentrated from the $HI-H_2O-I_2$ solution with a molar ratio of 1:5:1 at $80^{\circ}C$. The other is a membrane reactor to enhance the one-pass conversion of thermal decomposition reaction of gaseous hydrogen iodide (HI). It was found from the simulation study that the conversion of over 0.9 would be attainable using the membrane reactor using the gas permeation properties of the prepared silica hydrogen permselective membrane by chemical vapor deposition (CVD). Design criterion of the membrane reactor was also discussed.

The photocatalytic water splitting into $H_2$ and $O_2$ mimicking a Z-scheme mechanism (광합성을 모사한 광촉매 물분해 수소 제조)

  • Jeon, Myung-Seok;Hong, Joon-Gi;Chun, Young-Gab;Choi, Ho-Suk
    • Journal of the Korean Solar Energy Society
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    • v.23 no.4
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    • pp.29-35
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    • 2003
  • We studied the water splitting into $H_2$ and $O_2$ using two different semiconductor photo catalysts and redox mediator, mimicking the Z-scheme mechanism of the photosynthesis, $H_2$ evolution took place on a Pt-$SrTiO_2$ (Cr-Ta doped) photocatalyst using $I^-$ electron donor under the visible light irradiation. The Pt-$WO_3$ photocatalyst showed an excellent activity of the $O_2$ evolution using $IO_3^-$ electron acceptor under visible light. $H_2$ and $O_2$ gases evolved in the stoichiometric ratio($H_2/O_2$=2) under visible light using a mixture of the Pt-$WO_3$ and Pt-$SrTiO_3$ (Cr-Ta doped) suspended in NaI aqueous solution. We proposed a two-step photo-excitation mechanism using redox mediator under the visible irradiation.

Study on the hydrogen production using the metal oxide (Cu-ferrite) (금속산화물(Cu-ferrite)를 이용한 수소제조 연구)

  • Park, Chu-Sik;Seo, In-Tai;Kim, Jung-Min;Lee, Sang-Ho;Hwang, Gap-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.3
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    • pp.201-207
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    • 2004
  • Redox characteristics of metal oxide for hydrogen production by thermochemical water-splitting were investigated. $CuFe_2O_4$ as a redox pair that had a different molar ratio of Cu and Fe were prepared by co-precipitation method. Hydrogen production consisted of water-splitting step and thermal reduction step was performed below 1200K. Redox characteristics of Cu-ferrites were studied using the thermal gravimetric analysis technique. Also, structure change of Cu-ferrite during thermal reduction was investigated using the high temperature controlled XRD. In results, oxygen release of Cu-ferrite during the thermal reduction was initiated at oxygen site combined with Cu. Consequently, oxygen release amount of Cu-ferrite was increased with increase of Cu molar ratio of Cu-ferrite. It was found that thermal reduction of Cu-ferrite was begun at $875^\circ{C}$. It was confirmed that structure of Cu-ferrite was changed to metal and cation excess metal oxide during the thermal reduction step.

Influence of Steel Fiber Volume Ratios on Workability and Strength Characteristics of Steel Fiber Reinforced High-Strength Concrete (강섬유 혼입율이 강섬유보강 고강도 콘크리트의 작업성과 강도특성에 미치는 영향)

  • Kim, Yoon-Il;Lee, Yang-Keun;Kim, Myung-Sung
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.3
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    • pp.75-83
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    • 2008
  • In this paper, concrete material tests were carried out to investigate influence of steel fiber volumn ratios on variations of workability and strength characteristics of steel fiber reinforced high-strength concrete, $50MPa{\sim}90MPa$ of compressive strength, according to increase of fiber volume. Test specimens were arranged with six levels of concrete compressive strength and fiber volumn ratios, 0.0%, 0.5%, 1.0%, 1.5%, 2.0%. The test results showed that steel fiber reinforced high-strength concrete($70MPa{\sim}90MPa$, 1.5% fiber volumn ratio) with good workability of slump 20cm could be used practically and effects of steel fiber reinforcement in improvement of concrete strength and toughness characteristics such as splitting tensile strength, flexural strength, and diagonal tensioned shear strength, were more distinguished in high-strength concrete than general strength concrete. And the test results indicated that splitting tensile strength of fiber reinforced concrete was proportioned to the product of steel fiber volumn ratios, $V_f(%)$ and sqare root of compressive strength, $\sqrt{f_{ck}}$, and the increasing rate was in contrast with that of flexural strength, and increase of diagonal tensioned shear strength was remarkable at steel fiber volumn ratio, 0.5%.

The Properties of Lightweight Concrete Using the Expanded Clay (경량골재 콘크리트의 역학적 특성)

  • 김태형;하상진;최영화;김동인
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.249-252
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    • 1999
  • Recently, the use of lightweight concrete in architectural structures are increasing. It is considered important to control the quality of lightweight concrete. The purpose of this study is to find mechanical properties of lightweight concrete using the expanded clay. Thus, slump, air content, compressive strength, splitting tensile strength, length change ratio, unitweight change ratio and absorption of lightweight concrete have been investigated. As a result, it was shown that proper expanded clay replaced by coarse aggregate in concrete was considered as a good replacement of lightweight concrete.

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Highly Utilized Fiber Plant with Extended Reach and High Splitting Ratio Based on AWG and EDFA Characteristics

  • Syuhaimi, Mohammad;Mohamed, Ibrahim
    • ETRI Journal
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    • v.35 no.5
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    • pp.786-796
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    • 2013
  • In this paper, we propose a hybrid time-division multiplexing and dense wavelength-division multiplexing scheme to implement a cost-effective and scalable long-reach optical access network (LR-OAN). Our main objectives are to increase fiber plant utilization, handle upstream and downstream flow through the same input/output port, extend the reach, and increase the splitting ratio. To this end, we propose the use of an arrayed waveguide grating (AWG) and an erbium-doped fiber amplifier (EDFA) in one configuration. AWG is employed to achieve the first and second objectives, while EDFA is used to achieve the third and fourth objectives. The performance of the proposed LR-OAN is verified using the Optisystem and Matlab software packages under bit error rate constraints and two different approaches (multifiber and single-fiber). Although the single-fiber approach offers a more cost-effective solution because service is provided to each zone via a common fiber, it imposes additional losses, which leads to a reduction in the length of the feeder fiber from 20 km to 10 km.

Modal Characteristics of Plasmonic Multimode Interference Couplers with Stepped Structure (플라즈마 계단형 다중모드 간섭 결합기의 모드 특성)

  • Ho, Kwang-Chun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.13 no.2
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    • pp.47-52
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    • 2013
  • A novel architecture to reduce dramatically the coupling length of multimode interference-based couplers (MMICs) is proposed by replacing conventionally designed MMICs by cascaded two-section plasmonic stepped MMICs (PS-MMIC). For the 60% cross power splitting ratio in a stepped-width MMIC, the coupling length of device results in around 42% length reduction. Furthermore, the power splitting ratio and coupling length of plasmonic MMIC just vary around 1~2% along the variation of refractive index. On the contrast, those factors for the variation of MMIC's width strongly vary around 30~40%.

Optimal Bit Split Methods and Performance Analysis for Applying to Multilevel Modulation of Iterative Codes (반복 부호의 다치 변조방식 적용을 위한 최적의 비트 분리 방법 및 성능평가)

  • Bae, Jong-Tae;Jung, Ji-Won;Choi, Seok-Soon;Kim, Min-Hyuk;Chang, Dae-Ig
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.3C
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    • pp.216-225
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    • 2007
  • This paper presents bit splitting methods to apply multilevel modulation to iterative codes such as turbo code, low density parity check code and turbo product code. Log-likelihood ratio method splits multilevel symbols to bits using the received in-phase and quadrature component based on Gaussian approximation. However it is too complicate to calculate and implement hardware due to exponential and log calculation. therefore this paper presents Euclidean, MAX and Sector method to reduce the high complexity of LLR method. We propose optimal bit splitting method for three iterative codes.

RECONSTRUCTION OF SEVERE BUCCO-LINGUAL BONE RESORPTION AREA USING "RIDGE SPLITTING TECHNIQUE" (심한 협-설골 위축에서 치조골 수평 확장술을 이용한 골 재건)

  • Yeo, Duck-Sung;Lim, So-Yeon;Lee, Hyun-Jin;Ahn, Mi-Ra;Sohn, Dong-Seok
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.28 no.6
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    • pp.590-594
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    • 2006
  • Dental implant has become one of the important option for completely or partially edentulous patients, But it is challenging to reconstruct the severely atrophic ridge. Insufficient bone volume could restrict to place the wide and long implant and because of excessive interocclusal clearance, improper prosthetics could be produced. In this case bone augmentation for implant dentistry is necessary procedure to improve the insufficient bone volume. Therefore, bone augmentation or GBR is the most important procedure for successful implant placement and for ideal crown- root ratio. There are various bone augmentation techniques have been introduced recently; like block bone graft, distraction osteogenesis, inlay graft, onlay graft, etc.... In severe bucco-lingual resorption area, ridge splitting is the first choice of the treatment, because it provides a place for implantation and also has compaction effect. This technique may be indicated for sharp mandible and maxillary ridges in patients whose bone quantity is inadequate for primary stabilization. We report that the clinical experience of bone augmentation using ridge splitting technique in bucco-lingual bone resorption area.

Mechanical Properties of Energy Efficient Concretes Made with Binary, Ternary, and Quaternary Cementitious Blends of Fly Ash, Blast Furnace Slag, and Silica Fume

  • Kim, Jeong-Eun;Park, Wan-Shin;Jang, Young-Il;Kim, Sun-Woo;Kim, Sun-Woong;Nam, Yi-Hyun;Kim, Do-Gyeum;Rokugo, Keitetsu
    • International Journal of Concrete Structures and Materials
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    • v.10 no.sup3
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    • pp.97-108
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    • 2016
  • When the energy performance of concrete is substantially higher than that of normal type concrete, such concrete is regarded as energy efficient concrete (WBSCSD 2009). An experimental study was conducted to investigate mechanical properties of energy efficient concrete with binary, ternary and quaternary admixture at different curing ages. Slump test for workability and air content test were performed on fresh concretes. Compressive strength, splitting tensile strength were made on hardened concrete specimens. The mechanical properties of concrete were compared with predicted values by ACI 363R-84 Code, NZS 3101-95 Code, CSA A23.3-94 Code, CEB-FIP Model, EN 1991, EC 2-02, AIJ Code, JSCE Code, and KCI Code. The use of silica fume increased the compressive strengths, splitting tensile strengths, modulus of elasticities and Poisson's ratios. On the other hand, the compressive strength and splitting tensile strength decreased with increasing fly ash.