• Journal of the Korean Society of Safety
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• v.30 no.6
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• pp.148-155
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• 2015

Using dispersants is known to be an effective solution to accelerate the natural dispersion and being an appropriate oil spill response strategy. By breaking up large oil chunks into small droplets, dispersants are generally intended to help reducing further oil exposures and slicks. Collecting property data of circulating crude oil in South Korea and understanding the interaction between crude oils and dispersions need to be preceded for the effective dispersant use. This paper provides an property analysis of three selected oils which have the same composition of spilt oils from the Herbei Spirit Incident and conducts an emulsification and toxicity experiment with selected domestic and foreign dispersants. Results will present a direction of future domestic dispersants' development which aimed at eco-friendly and safety.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1116-1123
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• 2021

Oil spilled in seawater undergoes physical and chemical changes as well as biological degradation through various weathering processes, such as evaporation, diffusion, dispersion, emulsification, dissolution, oxidation, and sedimentation. Evaporation is one of the most immediate and prompt weathering processes, and it has the greatest influence on majority of pollutants. In this study, the evaporation characteristics of different oil samples were studied; the volatilization characteristics of gasoline, kerosene, and diesel were compared at average seawater (25 ℃) and near-equator (35 ℃) temperatures. The oil samples were pre-treated and then collected at regular intervals. Gas chromatography-mass spectrometry analysis was performed, and the changes in the amount of the hydrocarbons were calculated.

• Journal of the Korean Association of Geographic Information Studies
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• v.15 no.4
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• pp.90-103
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• 2012

Mallipo is a representative beach contaminated by Hebei Spirit oil spill accident in December 2007. This study aims to compare the differences of two seasons (winter and summer) for the spatio-temporal variation patterns of oiling status in the whole area and divided five regions of Mallipo beach. In the whole area, the decreasing rate of average TPH (total petroleum hydrocarbon) in winter was twice greater than summer during four years. According to the spatial variation pattern analysis of oiling status using weighted mean center and weighted standard distance, the oil concentration was clustered on southwestern region in winter, however, the TPH was dispersed in the whole area in summer. Temporal variation pattern of TPH in each of Mallipo's five regions showed that TPH had been consistently decreased in winter, but oil concentration had not been changed in summer since 2009 except the southwestern region. Therefore, in order to evaluate and predict the progress of oiling status, it is needed to analyze the spatio-temporal variation pattern of TPH using spatial analysis after separating data into seasons (e.g., winter and summer). In addition, time series analysis is useful in the regional scales through spatial partitioning rather than the whole beach area for the understanding of temporal variation pattern.

• Journal of Microbiology and Biotechnology
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• v.13 no.3
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• pp.437-443
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• 2003

Bioremediation technologies were applied to experimental microcosms, simulating an oil spill in a lower intertidal area. Three treatments (oil only, oil plus nutrients, and oil plus nutrients and microbial inocula) were applied, and each microcosm was repeatedly filled and eluted with seawater every 12 h to simulate tidal cycles. To minimize washing-out of the inoculum by the tidal cycles, microbial cells were primarily immobilized on diatomaceous earth before they were applied to the oiled sand. Oil degradation was monitored by gravimetric measurements, thin layer chromatography/flame ionization detector (TLC/FID) analysis, and gas chromatography (GC) analysis, and the loss of oil content was normalized to sand mass or nor-hopane. When the data were normalized to sand mass, no consistent differences were detected between nutrient-amended and nutrient/inoculum-amended microcosms, although both differed from the oil-only microcosm in respect of oil removal rate by a factor of 4 to 14. However, the data relative to nor-hopane showed a significant treatment difference between the nutrient-amended and nutrient/inoculum-treated microcosms, especially in the early phase of the treatment. The accelerating effect of inoculum treatment has hardly been reported in studies of oil bioremediation in the Tower intertidal area. The inoculum immobilized on diatomaceous earth seemed to be a very effective formulation for retaining microbial cells in association with the sand. Results of this study also suggest that interpretation of the effectiveness of bioremediation could be dependent on the selection of monitoring methods, and consequently the application of various analytical methods in combination could be a solution to overcome the limitations of oil bioremediation monitoring.

• Journal of the Korean Society of Marine Environment & Safety
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• v.6 no.1
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• pp.69-76
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• 2000

Bubble boom may be a good alternative for the prevention of oil spill pollution due to its easy deployment and clean post-process tasks. The present work is focused on the experimental investigation of air bubble movement for the bubble boom by visualization and quantitative PIV measurements. Bubble plume was generated by adjusting the pressure of pressure vessel ranging 6.7 kpa to 14.7 kpa. The results showed at lower inlet velocity and higher supply air flow rate that bubble boom maintained its containing capability reasonably well up to the maximum containing limit.

• Journal of the Korean GEO-environmental Society
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• v.11 no.10
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• pp.49-55
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• 2010

The oil spill occurred frequently due to probably the increased consumption of oil as the energy source and the raw materials of various chemicals. For the treatment of oil contaminated groundwater, DAF(Dissolved Air Flotation) is being used but the removal efficiency is low. Therefore it is necessary to reduce the free phase oil, oil-in water type or water-in oil type emulsified oil, and soluble oil which are the main sources of contaminated groundwater. In this study, treatment of contaminated groundwater was performed using the Fenton oxidation process. The optimum conditions for the removal of THP(Total Petroleum Hydrocarbon) were 3 of pH, 25mM of $H_2O_2$ concentration and 25mM of $Fe^{2+}$ concentration. THP and COD(Chemical Oxygen Demand) concentrations decreased less than 1.5mg/L and 40.0mg/L in 7 minutes using DAF and Fenton oxidation process. However it is necessary to install the settling basin as the sludge concentration increased approximately 5 times.

• Korean Journal of Microbiology
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• v.33 no.2
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• pp.157-162
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• 1997

Recently the bioremediation technology has been widely used to recover the oil contaminated environments The application of bioremediation agents to oil polluted environments became common and thus many kinds of commercial products were imported into domestic market. In Korea, howcver. the standardization of bioremediation products quality is not yet established and results of efficacy test .ire scarce. In this study five oil spill bioremediation commercial products including microbial inoculants and en'cyme agents are tested for the oil degradation rate. From the results most products shows the strong oil emulsifying phenomena due to the contained chemical oil dispersant and the low oil degradation rate. Product D inhibited the oil degradability of microorganisms even in the natural sea water. From these results it could be concluded that in the near future the laboratory protocol and standardization of products quality for bioremediarion agents should be prepared to activate the effective application of bioremediation technology in Korea.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.772-776
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• 2001

The flow structures of turbulent shear layer behind oil fences with different tip configurations were investigated experimentally using flow visualization and PIV velocity field measurement. An oil fence was installed in a circulating water channel and the flow structure around the fence tip was mainly analyzed in this experiment. The four tip configurations tested in this experiment are knife edge; semi-circle edge, circular edge and rectangular edge. The 300 instantaneous velocity fields were measured using the single-frame PIV system and they were ensemble averaged to give the mean velocity field and spatial distribution of turbulent statistics. Free stream velocity was fixed at 10ms/sec and the corresponding Reynolds number based on the fence height was Re=4000. As a result, for the oil fence with rectangular edge, the streamwise velocity component was decreased. On the other hand it was increased for the oil fence with circular edge. For all four fences tested in this study, general flow pattern of the lower shear layer is analogous but the upper layer shows difference depending on the tip configurations. The oil fence with circular edge has more diffusive upper shear layer than that of the others. The shear layer of the oil fence with rectangular edge has relatively thin thickness. The oil fence with circular edge was found to be proper shape for tandem fence.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.36 no.6
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• pp.743-748
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• 2003

An oil boom was set up in order to contain diffused oil from spills and for the retrenchment of damage caused by oil Pollution. Therefore, the oil boom anchor needed proper holding power to endure high resistance from flowing streams and to secure the oil boom around the spill, and must dredge directly into the seabed when it is dropped and block oil outflow immediately. This study investigated the holding power of the danforth anchor and the coastal fishing vessel anchor used for oil booms in the KMPRC (Korea Marine Pollution Response Corporation). For each type, a 30 kg and 20 kg anchor were used. The holding power of the danforth anchors were measured by dropping both weights 10 times. However the coastal fishing vessel anchors were dropped only 5 times each, because no substantial differences were found between drops. In the results of the danforth anchors, an anchor awoke occurred in 2 drops of the 30 kg anchor and in 4 drops of the 20 kg anchor, wherein there was no holding power to be measured. With exception to the anchor awoke cases, the maximum holding power of the danforth 30 kg and 20 kg anchors was 250-520 kg and 123-233 kg, respectively. In the case of the coastal fishing vessel anchors of 30 kg and 20 kg, throughout the experiment, there was no occurrence of an anchor awoke. For the 30 kg and 20 kg anchors, the maximum holding power was measured to be 209-230 kg and 155-170 kg, respectively. Therefore, the holding power of the coastal fishing vessel anchor was shown to be much poorer than that of the danforth anchor. However, the holding power of the danforth anchor was very unstable. Due to the occurrences of anchor awoke, there was no holding power and the measurement value of maximum holding power showed too much variation among the drop tests. Also, after the maximum holding power was achieved, anchor awoke occurred easily. In the case of the coastal fishing vessel anchor was much more stabile, because there was no anchor awoke and no instance where holding power failed. Also the maximum holding power was reached quickly and almost no variation occurred among the drop tests.

• Journal of Environmental Science International
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• v.6 no.5
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• pp.473-480
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• 1997

Microorganisms producing bioemulslfiler were isolated from the sea water In Pusan coastal area. The isolated strain which had the highest emulsification activity and stability was identified as the genus Achetobacter from the results of morphological. cultural and biochemical tests and named Achetobacter sp. EL-C6 for convenience. The compositions of optimum medium for emulsification of crude oil by Acinetobacter sp. EL-C6 were crude oil 2.0%, NH4NO3 0.2%, $K_2HPO_4$ 0.01%, $MgSO_4$.$7H_2O$ 1.o%, $CaCl_2$.$2H_2O$ 0.1% and NaCl 3.0% at initial pH 7.5 and 3$0^{\circ}C$, respectively. The cultivation for emulsification of crude ell was carried out in 500m1 shaking flask containing 100m1 of the optimum medium at 3$0^{\circ}C$. The highest emulsification was observed after 5 days. The utilization on the various hydrocarbon of the Achetobacter sp. EL-C6 showed that utilization of n-alkane compounds were better than that of aromatic compounds. Among the petroleum compounds, crude ell was best utilized by the Achetobacter sp. EL-C6.