• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.10
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• pp.1471-1476
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• 2012

A study on the dielectric characteristics of the Glass Fiber Reinforced Plastic (GFRP) is important for designing a reliable high voltage superconducting machines such as transmission superconducting fault current limiters, superconducting cables, and superconducting transformers. In this paper, dielectric experiments of the GFRP under lightning impulse voltage are conducted in liquid nitrogen($LN_2$) according to various experimental conditions such as the thicknesses of the GFRP, the diameters of electrode systems and the pressures. The dielectric characteristics of the GFRP are analyzed by using a Finite Elements Method(FEM) according to various field utilization factors. It has been reported that the electrical insulation design of the GFRP would be conducted by considering the mean electric field intensity($E_{mean}$) distributed inside the GFRP. In this study, it is found that the dielectric performance of the GFRP could be explained by not only $E_{mean}$ but also the maximum electric field intensity ($E_{max}$). Finally, the empirical formulae of the GFRP to estimate an electrical breakdown voltage at sparkover under the lightning impulse condition are deduced. It is expected that the presented experimental results in this paper are helpful to design electrically reliable high voltage superconducting machines using the GFRP as an insulation material.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1599-1601
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• 1999

The characteristics of ultrasonic signal in insulation oil were investigated by optical fiber sensor(OFS) utilizing Mach-Zehnder interferometer. For checking the response properties of OFS ultrasonic signal was generated by function generator in various kinds of insulation oil. The attenuation of ultrasonic signal linearly increased with the increase of viscosity of insulation oil in log scale. Discharging signal was produced by neele-sphere electrode system. Intensity of discharging signal was plotted in terms of cumulative $y^2$ and the intensity of discharging signal in new oil was little bigger than that in serviced one.

• Proceedings of the KIEE Conference
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• 1999.07e
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• pp.2066-2068
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• 1999

In this paper, an optical fiber sensor(OF sensor) utilizing the principal of Sagnac interferometer was proposed to detect the discharge signals which generated from needle-sphere electrode system in insulating oil. The performance of OF sensor was checked by sinusoidal calibration signal generated by PZT acuator at 198kHz. The detected discharge signals consisted of acoustic signal and the electrical noise. The noise signal could be removed by digital low pass filter. It was demonstrated that the OF sensor in this research had a possibility to detect the discharge signals in power apparatus.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2008.10a
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• pp.253-255
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• 2008

This paper gives a basic data of the surface discharge characteristics for epoxy resin in Dry-Air. Used electrodes are needle to plane, sphere to plane and KS M3015 electrodes. With the changing electrodes in same condition, we can obtain different creeping lengthes, breakdown voltages and dielectric strengths, respectively. Dielectric strengths of Needle to plane electrodes are more higher than the others. Breakdown voltage and dielectric strength increase as the thickness of epoxy resin and creeping strength increase.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.49 no.11
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• pp.622-626
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• 2000

In this paper, an optical fiber sensor(OF sensor) utilizing the principal of Sagnac interferometer was proposed to detect the discharge signals. The needle-sphere electrode system in insulating oil generated the signals. The performance of OF sensor was checked by sinusoidal calibration signal generated by PZT actuator at 198KHz. The detected discharge signals consisted of acoustic signal and the electrical noise. The noise signal could be removed by digital low pass filter. It was demonstrated that the OF sensor in this research had a possibility to detect the discharge signals in power apparatus.

• Journal of Hydrogen and New Energy
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• v.12 no.1
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• pp.39-50
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• 2001

Vanadium based solid solution alloys have been studied as a potential negative electrode of Ni/MH battery due to their high hydrogen storage capacity. In order to improve the kinetic property of V-Ti alloy in KOH electrolyte, the ball-milling process with Ni, which has a catalytic effect of hydrogen absorption/desorption, was carried out to modify the surface properties of V-Ti-Cr alloys with high hydrogen storage capacity. Moreover, to overcome the problem of poor cycle life, V-Ti alloy substituted by Cr, V0.68 Ti0.20 Cr0.12, has been developed showing a good cycle performance (keeping about 80 % of initial discharge capacity after 200 cycles). The cycle life of surface-modified V0.68 Ti0.20 Cr0.12 alloy was improved by suppressing the formation of TiO2 layer on the alloy surface while decreasing the amount of dissolved vanadium in the KOH electrolyte. In order to promote the effect of Ni coating on the surface property of V0.68 Ti 0.20 Cr 0.12 alloy by ball-milling, filamentary-typed Ni, which has higher surface coverage area than sphere-typed Ni was used as a surface modifier. Consequently, the surface-modified V0.68 Ti0.20 Cr0.12 alloy electrode showed a improved discharge capacity of 460 mAh/g.

• Proceedings of the KIEE Conference
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• 2004.07c
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• pp.1808-1810
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• 2004

This paper describes the discharge characteristics of liquid $SF_6$ (-41$[^{\circ}]$, 1.7[atm]) and $LN_2$ for plane to plane, needle to plane, plane to needle and sphere to plane electrode with gap variations from 1[mm] to 12[mm]. From this result, the breakdown voltage was increased with increasing gap length. Especially, the formation of bubbles by evaporation was observed in spite of non-applying voltage source. A corona is created of the applying voltage from the bubbles on the electrodes applied voltage. We consider it equal mechanism of corona as void exists in solid insulator. The results of liquid $SF_6$ and $LN_2$ discharge characteristics were caused by bubble formed evaporation and applied electric field voltage. Corona was happened to weak bubble and was proceed to new bubble breakdown.

• Journal of the Korean Ceramic Society
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• v.49 no.5
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• pp.427-431
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• 2012

The $TiO_2$ foam synthesized using freeze-casting is a promising photocatalyst and photovoltaic electrode for a variety of energy applications, because the freeze-casting technique is easy to use, cheap, and suitable for mass-production. Despite its several advantages, little scientific information is available on the processing and morphology of the $TiO_2$ foams processed by freeze-casting. In particular, no systematic study has been performed on the microstructural evolution and morphological change of the rutile-phase $TiO_2$ foams during sintering. Therefore, in the present study, several $TiO_2$ foam samples were produced using the freeze-casting technique, which were then sintered at a relatively high temperature of $1200^{\circ}C$ for 1, 2, and 4 h to compare the morphological changes in the microstructure and to understand the effects of processing parameters of the rutile-phase $TiO_2$ foams. The foam ligament size increased near linearly with increasing sintering time whereas the average pore size decreased only slightly with increasing sintering time, with changes in particle morphology from sphere to rod and complete phase transformation from anatase to rutile.

• Current Photovoltaic Research
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• v.2 no.1
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• pp.18-27
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• 2014

Dye-sensitized solar cells (DSSCs), developed two decades ago, are considered to be an attractive technology among various photovoltaic devices because of their low cost, accessible dye chemistry, ease of fabrication, high power conversion efficiency, and environmentally friendly nature. A typical DSSCs consists of a dye-coated $TiO_2$ photoanode, a redox electrolyte, and a platinum (Pt)-coated fluorine-doped tin oxide (FTO) counter electrode. Among them, redox electrolytes have proven to be extremely important in improving the performance of DSSCs. Due to many drawbacks of iodide electrolytes, many research groups have paid more attention to seeking other alternative electrolyte systems. With regard to this, one-electron outer sphere redox shuttles based on cobalt complexes have shown promising results: In 2014, porphyrin dye (SM315) with the cobalt (II/III) redox couple exhibited a power conversion efficiency of 13% in DSSCs. In this review, we will provide an overview and perspectives of cobalt redox electrolytes in DSSCs.

• Progress in Superconductivity and Cryogenics
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• v.13 no.1
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• pp.27-30
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• 2011

A sub-cooled liquid nitrogen cooling system is known as a most promising method to develop large scale superconducting apparatuses such as superconducting fault current limiters and superconducting cables [1]. Gaseous helium (GHe), gaseous nitrogen ($GN_2$) and sulfur hexafluoride ($SF_6$) are commonly used for designing an high voltage applied superconducting device as an injection gaseous medium [2, 3]. In this paper, the analysis on the dielectric characteristics of GHe, $GN_2$ and $SF_6$ are conducted by designing and manufacturing sphere-to-plane electrode systems. The AC withstand voltage experiments on the various gaseous insulation media are carried out and the results are analyzed by using finite element method (FEM) considering field utilization factors (${\xi}$). It is found that the electric field intensity at sparkover ($E_{MAX}$) of insulation media exponentially decreases according to ${\xi}$ increases. Also, the empirical expressions of the functional relations between $E_{MAX}$ and ${\xi}$ of insulation media are deduced by dielectric experiments and computational analyses. It is expected that the electrical insulation design of applied superconducting devices could be performed by using the deduced empirical formulae without dielectric experiments.