• Title/Summary/Keyword: Spectroscopic characteristics

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A study on the HPHT-processed NOUV diamonds by means of their gemological and spectroscopic properties

  • Kim, Young-Chool;Choi, Hyun-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.3
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    • pp.114-119
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    • 2005
  • This study has been carried out with the eight HPHT processed NOUV diamonds - two yellow, two yellowish green, two green and two orangy yellow color stones. The gemological properties of these diamonds included a highly saturated body color, graphitized fractures around the girdles, tension cracks around crystalline inclusions, long-wave UV with medium yellowish green to a very strong yellowish green luminescence, and short-wave UV with faint yellowish green to a strong yellowish green luminescence. Distinctive features of spectroscopic properties include absorption peaks at 415 nm and 503 nm a strong absorption band at $460{\sim}480nm$ and a H2 center at 986nm. Infrared spectra showed an absorption peak at $1344cm^{-1}$ (C center), which is the characteristics related to single substitutional nitrogen.

Investigation of Arc Quenching Material for Low Voltage Circuit Breaker using Spectroscopic Method (분광기법을 이용한 저압 차단기용 소호재료 특성연구)

  • Lee, Sang-Youb;Jung, Young-Woo;Park, Hong-Tae;Oh, Il-Sung
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1665-1667
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    • 2003
  • Recently, a breaking capacity increases with breaking method using gas pressure from ablation materials in low voltage circuit breakers. In this paper, we investigated arc quenching materials with spectroscopic method. Especially, Hydrogen spectrum was investigated because its dielectric characteristics are better than other gases. We selected two arc quenching materials, UP and PA6, that use in circuit breakers. They had hydrogen spectrums, but PA6 was better than UP in the qualitative aspect.

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MEASUREMENTS OF ALBEDO AND SPECTRAL PATTERNS OF MAN-MADE SATELLITE MATERIALS (인공위성 재질별 반사율 및 분광유형 측정)

  • 이동규;김상준;이준호;한원용;민상웅
    • Journal of Astronomy and Space Sciences
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    • v.19 no.4
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    • pp.319-326
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    • 2002
  • Laboratory tests have been carried out for investigation of the spectroscopic characteristics at visible wavelength of 12 common satellite materials used in satellite bus and payload. The obtained spectral data show that the materials can be classified and identified since their spectral features and albedos distinctly differ among them. It is suggested that the result of the laboratory tests for the satellite materials can be used for the predictions of material types, material composition ratios, sizes, and masses in comparison with the spectral data obtained from observations of new satellites or space debris.

Spectroscopic Analysis of Gain Bandwidth in Raman Amplifier with Multiwavelength Pumping Scheme Using Actual Band Model

  • Felinskyi, Georgii;Han, Young-Geun;Lee, Sang-Bae
    • Journal of the Optical Society of Korea
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    • v.8 no.4
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    • pp.156-162
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    • 2004
  • The spectroscopic model is proposed to analyze the gain bandwidth of a fiber Raman amplifier (FRA) with a multiple wavelength pumping scheme based on Raman gain theory. The oscillatory lineshape, which is the analytic function to analyze Raman gain spectra, allows us to estimate the gain bandwidth of the FRA. Based on the proposed theoretical modeling, we design and analyze the characteristics of the FRA using the combined multiwavelength pumping sources. We achieved the extended gain bandwidth of the FRA over 80 nm with the small gain ripple less than 0.5 dB. Threshold pumping power and effective noise figure for the FRA can be also analyzed by using the proposed model, which is also applicable for versatile fibers with other doping materials. The proposed analysis method can be useful for the design of FRA with the multiwavelength pumping scheme.

Fabrication of micro carbon structures using laser-induced chemical vapor deposition and Raman spectroscopic analysis (레이저 국소증착에 의한 탄소 미세 구조물 제조 및 분광분석)

  • ;;J. Senthil Selvan
    • Laser Solutions
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    • v.5 no.2
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    • pp.17-22
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    • 2002
  • Characteristics of micro carbon structures fabricated with laser-induced chemical vapor deposition (LCVD) are investigated. An argon ion laser (λ=514.5nm) and ethylene gas were utilized as the energy source and precursor, respectively. The laser beam was focused onto a graphite substrate to produce carbon deposit through thermal decomposition of the precursor. Average growth rate of a carbon rod increased for increasing laser power and pressure. Micro carbon rods with good surface quality were obtained at near the threshold condition. Micro carbon rods with aspect ratio of about 100 and micro tubular structures were fabricated to demonstrate the possible application of this method to the fabrication of three-dimensional microstructures. Laser Raman spectroscopic analysis of the micro carbon structures revealed that the carbon rods are consisting of amorphous carbon.

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The Application of Time-Resolved Laser Induced Fluorescence Spectroscopy in the Complexation Studies of Eu(III) and Cm(III) with Humic Substances

  • Joong Gill Choi;Oum Ka Won;Chang Yeoul Choi;Hichung Moon;Hyun Sang Shin;Park, Seung Min;Paul Joe Chong
    • Bulletin of the Korean Chemical Society
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    • v.14 no.1
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    • pp.72-78
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    • 1993
  • The application of time-resolved laser induced fluorescence spectroscopy (TRLIF) to the complexation studies of Eu(III) and Cm(III) with humic substances is described. Using this method, three different spectroscopic characteristics(excitation spectra, emission spectra, and lifetimes) of these aquo ions and their complexes can be directly measured. By observing shifts in the wavelength and changes in the lifetime and intensities of the fluorescence emission, the information on the complexation behavior of humic substances with these trivalent metal cations in an aqueous solution, as well as energy transfer mechanisms, can be obtained. In addition, this method allows precise spectroscopic quantification of the complexation processes at very low concentrations of both components.

Spectral Line Identification and Emission Characteristics of the Laser-Induced Plasma in Pulsed Nd:YAG Laser Welding (펄스 YAG 레이저 용접시 유기하는 플라즈마의 스펙트럼선 동정과 발광특성)

  • 김종도
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.3
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    • pp.360-368
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    • 1999
  • The paper describes spectroscopic characteristics of plasma induced in the pulsed YAG laser welding of alloys containing a large amount of volatile elements. The authors have conducted the spectroscopic analyses of laser induced Al-Mg alloys plasma in the air and argon atmosphere. In the air environment the identified spectra were atomic lines of Al, Mg, Cr, Mn, Cu, Fe and Zn and singly ionized Mg lines as well as the intense molecular spectra of ALO and MgO formed by chemi-cal reactions of evaporated Al and Mg atoms from the pool surface with oxygen in the air. In argon atmosphere MgO and AlO spectra vanished but AlH spectrum was detected. the hydrogen source was presumable hydrogen dissolved in the base metals water absorbed on the surface oxide layer or $H_2$ and $H_2O$ in the shielding gas. The resonant lines of Al and Mg were strongly self-absorbed in particular self-absorption of the Mg line was predominant. These results show that the laser induced plasma was made of metallic vapor with relatively low temperature and high density.

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Introduction of a New Method for Total Organic Carbon and Total Nitrogen Stable Isotope Analysis of Dissolved Organic Matter in Aquatic Environments (수환경 내 용존성 유기물질의 총 유기탄소 및 총 질소 안정동위원소 신규 분석법 소개)

  • Si-yeong Park;Heeju Choi;Seoyeon Hong;Bo Ra Lim;Seoyeong Choi;Eun-Mi Kim;Yujeong Huh;Soohyung Lee;Min-Seob Kim
    • Korean Journal of Ecology and Environment
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    • v.56 no.4
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    • pp.339-347
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    • 2023
  • Dissolved organic matter (DOM) is a key component in the biogeochemical cycling in freshwater ecosystem. However, it has been rarely explored, particularly complex river watershed dominated by natural and anthropogenic sources, such as various effluent facility and livestock. The current research developed a new analytical method for TOC/TN (Total Organic Carbon/Total Nitrogen) stable isotope ratio, and distinguish DOM source using stable isotope value (δ13C-DOC) and spectroscopic indices (fluorescence index [FI] and biological index [BIX]). The TOC/TN-IR/MS analytical system was optimized and precision and accuracy were secured using two international standards (IAEA-600 Caffein, IAEA-CH-6 Sucrose). As a result of controlling the instrumental conditions to enable TOC stable isotope analysis even in low-concentration environmental samples (<1 mgC L-1), the minimum detection limit was improved. The 12 potential DOM source were collected from watershed, which includes top-soils, groundwater, plant group (fallen leaves, riparian plants, suspended algae) and effluent group (pig and cow livestock, agricultural land, urban, industry facility, swine facility and wastewater treatment facilities). As a result of comparing characteristics between 12 sources using spectroscopic indices and δ13C-DOC values, it were divided into four groups according to their characteristics as a respective DOM sources. The current study established the TOC/TN stable isotope analyses system for the first time in Korea, and found that spectroscopic indices and δ13C-DOC are very useful tool to trace the origin of organic matter in the aquatic environments through library database.

SPECTROSCOPIC OBSERVATION OF THE SOLAR ACTIVE REGIONS IN HeI 10830 ${\AA}$ LINE

  • TOHMURA ICHIROH;KITAI REIZABURO;SUEMATSU YOSHINORI;SOLTAU DIRK
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.333-335
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    • 1996
  • Here we report the results from spectroscopic observations of soloar active regions in the HeI 10830 ${\AA}$ line at the German Vacuum Tower Telescope(VTT) in Tenerife during the August 199:3 International EFR(Emerging Flux Region) Campaign. Four active regions in various stages of their evolution, i.e., NOAA7558, 7560, 7561, and 7562, were ovserved on 10 August 1993. From the observed HeI 10830 ${\AA}$ spectra in these active regions, spectroscopic quantities such as equivalent width(EW), doppler shift, doppler width, etc., were derived(see Figure l(a)) and the correlation between them were studied(see Figure l(b)). Our main results are as follows: (I)In NOAA7562, which is a young and evolving EFR, the EW is large, while it is small around a simple and roundish spot of NOAA7558. (2)In these active regions, redshift in the 10830 line is dominant when the EW is larger. (3)As the doppler width increases, the line tends to shift redward. (4)When the EW is smaller, it seems to exist another component which have dynamic characteristics different from the redshifting component. In NOAA7560 and NOAA7561, regions which have several small spots, the values of the EW are intermediate. Results (2) and (3) may suggest the possible existence of downflow above active regions, if the HeI 10830 ${\AA}$line is formed in the upper chromopshere, and it is consistent with the earlyer result from the SMM extreme-ultraviolet observation by Klimchuk(1987, Astrophys. J., 323, 368) (to be submitted. to Astronomy and Astrophysics; an extended abstract)

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Optical Structures of Multilayer Coatings of Antireflection Lenses and their Transmission Characteristics (무반사 렌즈용 다층박막의 광학적 구조 및 광투과 특성)

  • 김상열;최성숙
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.259-265
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    • 1995
  • Antireflection coatings on optical lenses commertially available in domestic market are optically analyzed. Transmission spectra and reflection spectra are collected using spectrophotometers. The apparent absorption spectra around the absorption band edge are dominated by the substrate absorption. The reflection spectra and the apparent absorption spectra at visible region between 400nm and 700nm show very strong correlation to each other except a couple samples. The discrepency observed in the latters are due to an increased absorption in visible region by the substrate, which is negative effect of these samples. An antireflection coating consisted of $SiO_2/TiO_2/SiO_2/ZrO_2/Cr$ is made on c-Si substrate for spectroscopic ellispometry analysis. A film-by-film coating is accomplished and between each film deposition, ex-situ spectroscopic ellipsometry measurements are made. The analysis of the spectroscopic ellipsometry data reveals that the average film densities of $ZrO_2$ and $TiO_2$ reach only 80% of their respective packing densities and thick films are inhomogeneous along film growth direction. Discussions are made toward in-situ, real-time monitoring of the film growth so that a real-time feedback is possible to achieve a post-correction to minor deviations occured in the previous step. step.

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