• Title/Summary/Keyword: Spectral range

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Water-Methanol and Water-Acetonitrile Mixture Analysis using NIR Spectral Data and Iterative Target Transform Factor Analysis

  • Na, Dae-Bok;Hur, Yun-Jeong;Park, Young-Joo;Cho, Jung-Hwan
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1289-1289
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    • 2001
  • Water-methanol and water-acetonitrile mixtures are frequently used as HPLC solvent system and strong hydrogen bonding is well-known. But a detailed aspect of water-methanol and/or water-acetonitrile mixtures have not been shown with direct spectral evidence. Recently, near infrared spectroscopy and chemometric data refinery have been successfully combined in many applications. On the basis of factor analytical methods, the spectral features of water-methanol and water-acetonitrile mixtures were studied to reveal the detail of mixtures. Water-methanol and water-acetonitrile mixtures were prepared with varying concentration of each constituent and near infrared spectral data were acquired in the range of 1100-2500nm with 2-nm interval. The data matrices were analysed with ITTFA(Iterative Target Transform Factor Analysis) algorithm implemented as MATLAB codes. As a result, the concentration profiles of water, methanol and water-methanol complex were resolved and the spectra of water-methanol complexes were calculated, which cannot be acquired with pure complexes. A similar result was obtained with NIR spectral data of water-acetonitrile mixtures. Moreover, pure spectra of hydrogen-bonding complexes of water-methanol and water-acetonitrile can be computed, while any other usual physical methods cannot isolated those complexes for acquiring pure component spectra.

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Spectral Reflectance of Soils Related to the Interaction of Soil Moisture and Soil Color Using Remote Sensing Technology (RS 기법을 이용한 토양수분과 토양 색에 관련된 토양의 분광반사)

  • 박종화
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.5
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    • pp.77-84
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    • 2003
  • Recent advances in remote sensing techniques provide the potential for monitoring soil color as well as soil moisture conditions at the spatial and temporal scales required for detailed local modeling efforts. Soil moisture as well as soil color is a key feature used in the identification and classification of soils. Soil spectral reflectance has a direct relationship with soil color, as well as to other parameters such as soil moisture, soil texture. and organic matter. We evaluate the influence of seven soil properties, soil color and soil moisture, on soil spectral reflectance. This paper presents the results obtained from the ground-truth spectral reflectance measurements in the 300-1100 nm wavelength range for various land surfaces. The results suggest that the reflectance properties of soils are related to soil color, soil texture, and soil moisture. Increasing soil moisture content generally decreases soil reflectance which leads to parallel curves of soil reflectance spectra across the entire shortwave spectrum. We discuss the relationships between the soil reflectance and the Munsell Soil Color Charts which contain standard color chips with colors specified by designations for hue, value, and chroma.

Estimating Optimal-Band of NDVI and GNDVI by Vegetation Reflectance Characteristics of Crops.

  • Shin, Hyoung-Sub;Park, Jong-Hwa;Park, Jin-Ki;Kim, Seong-Joon;Lee, Mi-Seon
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.151-154
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    • 2008
  • Information on the area and spatial distribution of crop fields is needed for biomass production, arrangement of water resources, trace gas emission estimates, and food security. The present study aims to monitor crops status during the growing season by estimating its aboveground biomass and leaf area index (LAI) from field reflectance taken with a hand-held radiometer. Field reflectance values were collected over specific spectral bandwidths using a handheld radiometer(LI-1800). A methodology is described to use spectral reflectance as indicators of the vegetative status in crop cultures. Two vegetation indices were derived from these spectral measurements. In this paper, first we analyze each spectral reflectance characteristics of vegetation in the order of growth stage. Vegetation indices (NDVI, GNDVI) were calculated from crop reflectance. And assess the nature of relationships between LAI and VI, as measured by the in situ NDVI and GNDVI. Among the two VI, NDVI showed predictive ability across a wider range of LAI than did GNDVI. Specific objectives were to determine the relative accuracy of these two vegetation indices for predicting LAI. The results of this study indicated that the NDVI and GNDVI could potentially be applied to monitor crop agriculture on a timely and frequent basis.

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Optimal Dispersion Condition to Distinguish OPD Directions of Spectrally-Resolved Interferometry (방향 판별 분산간섭계의 최적 분산 조건 연구)

  • Yun, Young Ho;Kim, Dae Hee;Joo, Ki-Nam
    • Journal of the Korean Society for Precision Engineering
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    • v.34 no.4
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    • pp.259-264
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    • 2017
  • Spectrally resolved interferometry (SRI) is an attractive technique to measure absolute distances without any moving components. In the spectral interferogram obtained by a spectrometer, the optical path difference (OPD) can simply be extracted from the linear slope of the spectral phase. However, SRI has a fundamental measuring range limitation due to maximum and minimum measurable distances. In addition, SRI cannot distinguish the OPD direction because the spectral interferogram is in the form of a natural sinusoidal function. In this investigation, we describe a direction determining SRI and propose the optimal conditions for determining OPD direction. Spectral phase nonlinearity, caused by a dispersive material, effects OPD direction but deteriorates spectral interferogram visibility. In the experiment, various phase nonlinearities were measured by adjusting the dispersive material (BK7) thickness. We observed the interferogram visibility and the possibility of direction determination. Based on the experimental results, the optimal dispersion conditions are provided to distinguish OPD directions of SRI.

DEEP-South: Taxonomic Classification of Asteroids Based on Johnson-Cousins Photometric System

  • Roh, Dong-Goo;Moon, Hong-Kyu;Kim, Myung-Jin;Park, Jintae;Choi, Young-Jun;Yim, Hong-Suh;Lee, Hee-Jae;Oh, Young-Suk
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.56.1-56.1
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    • 2016
  • Surface mineralogy of asteroids are inferred from photometric and spectroscopic observations with the wide range of wavelengths spanning from far-ultraviolet to mid-infrared. We classify mineralogy of those objects based on their spectral absorption features and spectral slopes. Based on overall spectral shapes, mineralogical classes are divided into three broad complexes; silicates (S), carbonaceous (C) and Vestoids (V), and the end-members that do not fit within the S, C and V broad-complexes. Each of them is subdivided into individual classes. Spectral classification of asteroidal objects has been simply represented by a combination of photometric colors. For a decade, photometric data of asteroids have been grouped and classified according to their SDSS colors converted from the spectral taxonomy. However, systematic studies for asteroid taxonomy based on Johnson-Cousins filters is few, and were conducted only with a small number of objects. In this paper, we present our preliminary results for taxonomic classification of Main Belt asteroids based on KMTNet Johnson-Cousins photometric color system.

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Evaluating the effective spectral seismic amplification factor on a probabilistic basis

  • Makarios, Triantafyllos K.
    • Structural Engineering and Mechanics
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    • v.42 no.1
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    • pp.121-129
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    • 2012
  • All contemporary seismic Codes have adopted smooth design acceleration response spectra, which have derived by statistical analysis of many elastic response spectra of natural accelerograms. The above smooth design spectra are characterized by two main branches, an horizontal branch that is 2.5 times higher than the peak ground acceleration, and a declining parabolic branch. According to Eurocode EN/1998, the period range of the horizontal, flat branch is extended from 0.1 s, for rock soils, up to 0.8 s for softer ones. However, from many natural recorded accelerograms of important earthquakes, the real spectral amplification factor appears to be much higher than 2.5 and this means that the spectrum leads to an unsafe seismic design of the structures. This point is an issue open to question and it is the object of the present study. In the present paper, the spectral amplification factor of the smooth design acceleration spectra is re-calculated on the grounds of a known "reliability index" for a desired probability of exceedance. As a pilot scheme, the seismic area of Greece is chosen, as it is the most seismically hazardous area in Europe. The accelerograms of the 82 most important earthquakes, which have occurred in Greece during the last 38 years, are used. The soil categories are taken into account according to EN/1998. The results that have been concluded from these data are compared with the results obtained from other strong earthquakes reported in the World literature.

Classifying Forest Species Using Hyperspectral Data in Balah Forest Reserve, Kelantan, Peninsular Malaysia

  • Zain, Ruhasmizan Mat;Ismail, Mohd Hasmadi;Zaki, Pakhriazad Hassan
    • Journal of Forest and Environmental Science
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    • v.29 no.2
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    • pp.131-137
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    • 2013
  • This study attempts to classify forest species using hyperspectral data for supporting resources management. The primary dataset used was AISA sensor. The sensor was mounted onboard the NOMAD GAF-27 aircraft at 2,000 m altitude creating a 2 m spatial resolution on the ground. Pre-processing was carried out with CALIGEO software, which automatically corrects for both geometric and radiometric distortions of the raw image data. The radiance data set was then converted to at-sensor reflectance derived from the FODIS sensor. Spectral Angle Mapper (SAM) technique was used for image classification. The spectra libraries for tree species were established after confirming the appropriate match between field spectra and pixel spectra. Results showed that the highest spectral signature in NIR range were Kembang Semangkok (Scaphium macropodum), followed by Meranti Sarang Punai (Shorea parvifolia) and Chengal (Neobalanocarpus hemii). Meanwhile, the lowest spectral response were Kasai (Pometia pinnata), Kelat (Eugenia spp.) and Merawan (Hopea beccariana), respectively. The overall accuracy obtained was 79%. Although the accuracy of SAM techniques is below the expectation level, SAM classifier was able to classify tropical tree species. In future it is believe that the most effective way of ground data collection is to use the ground object that has the strongest response to sensor for more significant tree signatures.

Acoustic analysis of fricatives in dysarthric speakers with cerebral palsy

  • Hernandez, Abner;Lee, Ho-young;Chung, Minhwa
    • Phonetics and Speech Sciences
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    • v.11 no.3
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    • pp.23-29
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    • 2019
  • This study acoustically examines the quality of fricatives produced by ten dysarthric speakers with cerebral palsy. Previous similar studies tend to focus only on sibilants, but to obtain a better understanding of how dysarthria affects fricatives we selected a range of samples with different places of articulation and voicing. The Universal Access (UA) Speech database was used to select thirteen words beginning with one of the English fricatives (/f/, /v/, /s/, /z/, /ʃ/, /ð/). The following four measurements were taken for both dysarthric and healthy speakers: phoneme duration, mean spectral peak, variance and skewness. Results show that even speakers with mild dysarthria have significantly longer fricatives and a lower mean spectral peak than healthy speakers. Furthermore, mean spectral peak and variance showed significant group effects for both healthy and dysarthric speakers. Mean spectral peak and variance was also useful for discriminating several places of articulation for both groups. Lastly, spectral measurements displayed important group differences when taking severity into account. These findings show that in general there is a degradation in the production of fricatives for dysarthric speakers, but difference will depend on the severity of dysarthria along with the type of measurement taken.

Structural Stability of High-Temperature State of Bacteriorhodopsin: A Model of Multi-state Membrane Proteins

  • Mitaku, Shigeki;Yokoyama, Yasunori;Sonoyama, Masashi
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.118-121
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    • 2002
  • A state of bacteriorhodopsin at high temperature was studied by various spectral measurements. The stability measurements indicated that the onset temperature of the denaturation was 70$^{\circ}C$ in the dark and 60$^{\circ}C$ under illumination. The reactivity of hydroxylamine with the Schiff's base also significantly increased in the temperature range between 60 and 70$^{\circ}C$. A spectral band at about 470 nm appeared in the temperature range higher than 60$^{\circ}C$. The circular dichroism spectra in the visible region started to change from a bilobed exiton type to a positive band at about 60$^{\circ}C$, suggesting that the two-dimensional configuration of bacteriorhodopsin molecules changed from crystalline to amorphous. All the measurements suggested a new state between 60 and 70$^{\circ}C$ in which bacteriorhodopsin is stable only in the dark.

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Spectral Reflectance of Rice Grain and its Application to Develop a Whiteness-meter of Milled Rice (벼의 분광(分光) 반사(反射) 특성(特性)과 이를 이용한 정백미(精白米)의 백도(百度) 측정기(測定器) 개발(開發))

  • Noh, S.H.;Ikeda, Y.;Yamashita, R.
    • Journal of Biosystems Engineering
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    • v.15 no.1
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    • pp.33-43
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    • 1990
  • Spectral reflectance of paddy, brown rice, milled rice, greenish grain, yellow grain and denatured grain were measured over the range of 340 to 820 nm with "Double Beam Spectrophotometer(Model UV-180)". Variation in the reflectance depending on milling degree of milled rice appeared greatest over the range of 420 to 500 nm, and that between white rice and other rice samples appeared greatest near 500 nm. On the basis of the above results, a whiteness meter to measure milling degree of rice was manufactured using tungsten lamp, photodiodes and amplifier, and its performance was compared with the existing whiteness meters (KETT and Z-II optical sensor). There were very high correlations among those whiteness meters.

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