• Title/Summary/Keyword: Spectral range

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Hyperspectral Imaging and Partial Least Square Discriminant Analysis for Geographical Origin Discrimination of White Rice

  • Mo, Changyeun;Lim, Jongguk;Kwon, Sung Won;Lim, Dong Kyu;Kim, Moon S.;Kim, Giyoung;Kang, Jungsook;Kwon, Kyung-Do;Cho, Byoung-Kwan
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.293-300
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    • 2017
  • Purpose: This study aims to propose a method for fast geographical origin discrimination between domestic and imported rice using a visible/near-infrared (VNIR) hyperspectral imaging technique. Methods: Hyperspectral reflectance images of South Korean and Chinese rice samples were obtained in the range of 400 nm to 1000 nm. Partial least square discriminant analysis (PLS-DA) models were developed and applied to the acquired images to determine the geographical origin of the rice samples. Results: The optimal pixel dimensions and spectral pretreatment conditions for the hyperspectral images were identified to improve the discrimination accuracy. The results revealed that the highest accuracy was achieved when the hyperspectral image's pixel dimension was $3.0mm{\times}3.0mm$. Furthermore, the geographical origin discrimination models achieved a discrimination accuracy of over 99.99% upon application of a first-order derivative, second-order derivative, maximum normalization, or baseline pretreatment. Conclusions: The results demonstrated that the VNIR hyperspectral imaging technique can be used to discriminate geographical origins of rice.

Fabrication and $^{60}Co$ Gamma Induced Damage of Plastic Scintillators (플라스틱 섬광체의 제작과 $^{60}Co$ $\gamma$-선에 의한 방사선 손상)

  • Kim, Sung-Hwan;Nam, Seung-Hee;Cheon, Jong-Kyu;Kim, Wan;Kang, Hee-Dong;Kim, Do-Sung;Lee, Woo-Gyo;Doh, Sih-Hong
    • Journal of Sensor Science and Technology
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    • v.9 no.5
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    • pp.350-356
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    • 2000
  • The optimum composition ratios of primary solute(p-terphenyl) and secondary solute(popop) have been investigated in order to fabricate plastic scintillator with higher light output and less radiation damage. The radiation damage induced by $^{60}Co$ $\gamma$-irradiation depends on mainly the concentration of secondary solute. The spectral range of the luminescence was $400{\sim}450\;nm$, its peak emission appeared at 415 nm. The transmittance and the light output were not changed by radiation damage up to $1{\times}10^4\;Gy$ irradiation with $^{60}Co$ $\gamma$-rays.

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KVN Observation on Radio-selected AGNs hosted by Elliptical Galaxies

  • Park, Song-Youn;Yi, Suk-Young K.;Sohn, Bong-Won
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.61.1-61.1
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    • 2011
  • We have performed simultaneous observations at 22GHz and 43GHz on AGNs hosted by elliptical galaxies using KVN radio telescope. We have constructed the sample, based on two major surveys in radio and optical band, i.e. Faint Images of the Radio Sky at Twenty-Centimeters (FIRST) and Sloan Digital Sky Survey (SDSS) DR7, respectively. We restricted the redshift range 0.01 < z < 0.06 and the absolute magnitude Mr < -19.4 in order to satisfy volume limited sample. We also checked clear detection of four distinctive emission lines ([NII], [OIII], $H{\alpha}$, $H{\beta}$) so as to utilize on BPT diagram, distinguishing AGNs from star-forming galaxies. Elliptical galaxies have been selected by visual inspection making use of SDSS optical images. Then, we cross-matched the elliptical galaxies with FIRST detections. About 35% of the galaxies have been detected throughout KVN observations. We derive spectral index, applying the flux of different radio frequencies from FIRST (1.4GHz) and KVN (22GHz) and classify into steep, flat or inverted spectrum. We have found that most of the detected galaxies have flat spectrum while the rest of them have steep spectrum. This implies that a number of detected galaxies might have compact structure associated with the central region of the galaxies. The relation between black hole mass and radio luminosity has shown relatively tighter correlation in high frequency than in low frequency, which confirms that high frequency in radio band is appropriate to study the center of the galaxies.

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Detecting Incipient Caries Using Front-illuminated Infrared Light Scattering Imaging

  • Kim, Ji-Young;Ro, Jung-Hoon;Jeon, Gye-Rok;Kim, Jin-Bom;Ye, Soo-Young
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.6
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    • pp.310-316
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    • 2012
  • A new method for early caries diagnosis was proposed and tested through a home-made optical examination system that used quantitative light fluorescence (QLF) and digital imaging fiber optic transillumination (FOTI) (DIFOTI), with light sources across a wide spectral range, from 350 nm to 1,000 nm. The front-illuminated infrared light scattering image (FIR) showed similar diagnostic abilities to that of DIFOTI. The FIR method was invented based on the observation that caries lesions lose the high transmittance and low scattering properties of benign enamel tissue. There are various methods for the early diagnosis of caries, such as visual examination, exploration, X-ray radiography, QLF, FOTI, and infrared fluorescence (diagnodent). Among them, methods based on optical properties are regarded as having the most potential. A comparative study was performed between the FOTI, QLF, diagnodent, optical coherence tomography, and FIR scattering image methods, using 20 extracted teeth samples with early caries. A scale of lesion measurement based on optical image contrast was proposed. The statistical analysis showed a significant correlation between the DIFOTI and FIR methods (r = 0.35, p < 0.05). However, the QLF and diagnodent methods showed little association with FIR images, as they have different detection principles as compared with FIR. Tomographic images obtained by OCT, using 1,330 nm super luminescent LED as a gold standard of tooth structure, verified that the FOTI and FIR results correctly represented the lack of homogeneity in dental tissue. The newly proposed FIR method attained similar diagnostic results to those of FOTI, but with an easier approach.

Simultaneous Determination of Tryptophan and Tyrosine by Spectrofluorimetry Using Multivariate Calibration Method (다변량 분석법을 이용한 Tryptophan과 Tyrosine의 형광분광법적 정량)

  • Lee, Sang-Hak;Park, Ju-Eun;Son, Beom-Mok
    • Journal of the Korean Chemical Society
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    • v.46 no.4
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    • pp.309-317
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    • 2002
  • A spectrofluorimetric method for the simultaneous determination of amino acids (tryptophan and tyrosine) based on the application of multivariate calibration method such as principal component regression and partial least squares (PLS) to luminescence measurements has been studied. Emission spectra of synthetic mixtures of two amino acids were obtained at excitation wavelength of 257 ㎚. The calibration model in PCR and PLS was obtained from the spectral data in the range of 280-500 ㎚ for each standard of a calibration set of 32 standards, each containing different amounts of two amino acids. The relative standard error of prediction ($RSEP_a$) was obtained to assess the model goodness in quantifying each analyte in a validation set. The overall relative standard error of prediction ($RSEP_m$) for the mixture obtained from the results of a validation set, formed by 6 independent mixtures was also used to validate the present method.

Align-free Micro-optic Mach-Zehnder Interferometric Filter (정렬에 무관한 마이크로옵틱 마하젠더 간섭계형 필터)

  • Lee, Jong-Hoon;Kim, Hyun-Deok;Song, Jae-Won
    • Korean Journal of Optics and Photonics
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    • v.17 no.3
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    • pp.285-289
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    • 2006
  • A novel alignment-free micro-optic MZI filter has been demonstrated. The filter is composed of two fiber-pigtailed collimators and a beam-splittingplate with a periodically etched stripe pattern. We fabricated the plate through a standard lithographic formulation process by using a pyrex substrate glass with SU-8 resist coating on its one of the surfaces. The maximum insertion loss of the implemented filter was less than 2 dB over 1000 nm to 1600 nm and the extinction ratio was larger than 33 dB. The measured PDL within the 3-dB pass band of the filter was less than 0.15dB and the maximum extinction ratio variation was less than 2 dB even when the worst alignment error occured.

Validations of Typhoon Intensity Guidance Models in the Western North Pacific (북서태평양 태풍 강도 가이던스 모델 성능평가)

  • Oh, You-Jung;Moon, Il-Ju;Kim, Sung-Hun;Lee, Woojeong;Kang, KiRyong
    • Atmosphere
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    • v.26 no.1
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    • pp.1-18
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    • 2016
  • Eleven Tropical Cyclone (TC) intensity guidance models in the western North Pacific have been validated over 2008~2014 based on various analysis methods according to the lead time of forecast, year, month, intensity, rapid intensity change, track, and geographical area with an additional focus on TCs that influenced the Korean peninsula. From the evaluation using mean absolute error and correlation coefficients for maximum wind speed forecasts up to 72 h, we found that the Hurricane Weather Research and Forecasting model (HWRF) outperforms all others overall although the Global Forecast System (GFS), the Typhoon Ensemble Prediction System of Japan Meteorological Agency (TEPS), and the Korean version of Weather and Weather Research and Forecasting model (KWRF) also shows a good performance in some lead times of forecast. In particular, HWRF shows the highest performance in predicting the intensity of strong TCs above Category 3, which may be attributed to its highest spatial resolution (~3 km). The Navy Operational Global Prediction Model (NOGAPS) and GFS were the most improved model during 2008~2014. For initial intensity error, two Japanese models, Japan Meteorological Agency Global Spectral Model (JGSM) and TEPS, had the smallest error. In track forecast, the European Centre for Medium-Range Weather Forecasts (ECMWF) and recent GFS model outperformed others. The present results has significant implications for providing basic information for operational forecasters as well as developing ensemble or consensus prediction systems.

Measurement of Atmospheric BTX in Seoul Using Differential Optical Absorption Spectroscopy (차등흡수 분광법을 이용한 서울 대기 중 BTX 측정)

  • Lee Chulkyu;Choi Yeo Jin;Lee Jeong Soon;Jung Jin Sang;Kim Young Joon;Kim Ki Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.1-14
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    • 2005
  • In this study, a Long Path Differential Optical Absorption Spectroscopy system (K-JIST LP-DOAS) has been used to simultaneously measure atmospheric monoaromatic hydrocarbons and other trace compounds. The validity of the K-JIST LP-DOAS for measuring atmospheric monoaromatic hydrocarbons was tested during a field campaign between 12 February and 14 March 2003 at an urban site in Seoul, Korea through inter-comparative measurements against a collocated on-line Gas Chromatography (GC) system. The concentrations of benzene, toluene, p-xylene, and m-xylene were measured with the K-JIST LP-DOAS system in the UV region (239~302 nm) over a 740 m beam path. For the other trace compounds, a longer spectral range (299~362 nm) was used. In order to remove the interference of atmospheric abundant species (such as oxygen, sulfur dioxide and ozone), two oxygen optical density spectra obtained at two pathlengths, 697 and 1133m, and reference spectra of sulfur dioxide and ozone were incorporated in the fitting procedure. The mean concentrations measured by our LP-DOAS during the measurement period were 0.77 ($\pm$0.38) ppbv for benzene, 3.68 ($\pm$1.90) ppbv for toluene, 0.41 ($\pm$0.19) ppbv for p-xylene, 0.54 ($\pm$0.24) ppbv for m-xylene. The concentration data of benzene, toluene, p-xylene and m-xylene obtained by our LP-DOAS were found to be in relatively good correlations with those of the online GC system. Pearson's coefficients in the observed concentrations between LP-DOAS and on-line GC were 0.84 for benzene, 0.83 for toluene and 0.65 for m,p-xylene. This study suggests that the LP-DOAS system can be used to provide reliable information on both the mixing ratios and temporal distribution characteristics of monoaromatic hydrocarbons in the urban air.

Complete $^1H$-NMR and $^{13}C$-NMR spectral analysis of the pairs of 20(S) and 20(R) ginsenosides

  • Yang, Heejung;Kim, Jeom Yong;Kim, Sun Ok;Yoo, Young Hyo;Sung, Sang Hyun
    • Journal of Ginseng Research
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    • v.38 no.3
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    • pp.194-202
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    • 2014
  • Background: Ginsenosides, the major ingredients of Panax ginseng, have been studied for many decades in Asian countries as a result of their wide range of pharmacological properties. The less polar ginsenosides, with one or two sugar residues, are not present in nature and are produced during manufacturing processes by methods such as heating, steaming, acid hydrolysis, and enzyme reactions. $^1H$-NMR and $^{13}C$-NMR spectroscopic data for the identification of the less polar ginsenosides are often unavailable or incomplete. Methods: We isolated 21 compounds, including 10 pairs of 20(S) and 20(R) less polar ginsenosides (1-20), and an oleanane-type triterpene (21) from a processed ginseng preparation and obtained complete $^1H$-NMR and $^{13}C$-NMR spectroscopic data for the following compounds, referred to as compounds 1-21 for rapid identification: 20(S)-ginsenosides Rh2 (1), 20(R)-Rh2 (2), 20(S)-Rg3 (3), 20(R)-Rg3 (4), 6'-O-acetyl-20(S)-Rh2 [20(S)-AcetylRh2] (5), 20(R)-AcetylRh2 (6), 25-hydroxy-20(S)-Rh2 (7), 25-hydroxy-20(S)-Rh2 (8), 20(S)-Rh1 (9), 20(R)-Rh1 (10), 20(S)-Rg2 (11), 20(R)-Rg2 (12), 25-hydroxy-20(S)-Rh1 (13), 25-hydroxy-20(R)-Rh1 (14), 20(S)-AcetylRg2 (15), 20(R)-AcetylRg2 (16), Rh4 (17), Rg5 (18), Rk1 (19), 25-hydroxy-Rh4 (20), and oleanolic acid 28-O-b-D-glucopyranoside (21).

Synthesis of Nucleophilic Adducts of Thiols (VIII). Addition of L-Glutathione to ${\beta},\;{\beta}$-Diethoxycarbonylstyrene Derivatives (Thiol의 친핵성 첨가물의 합성 (VIII). ${\beta},\;{\beta}$-Diethoxycarbonylstyrene에 대한 L-Glutathione의 첨가)

  • Tae-Rin Kim;Sung-Yong Choi;Joon-Seob Shin
    • Journal of the Korean Chemical Society
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    • v.29 no.6
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    • pp.651-655
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    • 1985
  • A series of S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-glutathione derivatives (11a-e) were synthesized from the reaction of ${\beta},\;{\beta}$-diethoxycarbonylstyrene with L-glutathione in 9 : 1 aqueous methanol. Thus, S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-glutathione (11a), S-2,2-diethoxycarbonyl-1-(3',4'-methylenedioxy)phenylethyl-L-glutathione (11b), S-2,2-diethoxycarbonyl-1-(3',4',5'-trimethoxy)phenylethyl-L-glutathione (11c), S-2,2-diethoxycarbonyl-1-(4'-hydroxy)phenylethyl-L-glutathione (11d), S-2,2-diethoxycarbonyl-1-(4'-methoxy)phenylethyl-L-glutathione (11e) were obtained in good yields. The structure of the adducts was characterized by analytical and spectral data. The effects of pH and solvents upon the yields were also briefly examined. In the range of pH from 4.0 to 8.0, the aqueous methanol were found to be the best solvent for the addition reaction and the antibacterial activities of the adducts to Gram(+) bacteria were found to be weak.

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